DOI: 10.1063/1.1726340. Infrared Study of the Crystalline Monohydrates of Nitric, Perchloric, and Sulfuric Acids

Infrared Study of the Crystalline Monohydrates of Nitric, Perchloric, and Sulfuric Acids

10.1063/1.1726340

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The infrared spectra of the solid monohydrates of three strong acids nitric, perchloric, and sulfuric were measured down to 50 cm—1. The last two are completely ionic, viz., H3O+ClO4— and H3O+HSO4—, but the first one always seems to retain a trace of covalent structure, HNO3·H2O. In the three hydrogen-bonded lattices the H3O+ ions have libration frequencies of the order of 700 cm—1 and translation frequencies lying between 120 and 400 cm—1. The frequencies of these lattice modes increase with the strengths of the hydrogen bonds. The deuterated hydrate of sulfuric acid gave only vitreous spectra because of supercooling. Likewise the room-temperature phase of perchloric acid monohydrate showed broad, diffuse absorption bands due to the disordered orientation of the hydronium ions. The pyramidal configuration of the H3O+ ion is confirmed definitely.

Bibliography

Savoie, R., & GiguÃ¨re, P. A. (1964). Infrared Study of the Crystalline Monohydrates of Nitric, Perchloric, and Sulfuric Acids. The Journal of Chemical Physics, 41(9), 2698â2705.

Authors 2

Rodrigue Savoie (first)
Paul A. Giguère (additional)

References 50 Referenced 66

10.1039/tf9514701261 / Trans. Faraday Soc. (1951)
10.1063/1.1748467 / J. Chem. Phys. (1951)
{'key': '2024020823092124600_r2a', 'first-page': '102', 'volume': '7', 'year': '1951', 'journal-title': 'J. Phys. Soc. Japan'} / J. Phys. Soc. Japan (1951)
10.1039/tf9524800307 / Trans. Faraday Soc. (1952)
10.1107/S0365110X53000521 / Acta Cryst. (1953)
10.1107/S0365110X59000056 / Acta Cryst. (1959)
10.1021/j150572a035 / J. Phys. Chem. (1959)
10.1107/S0365110X62000055 / Acta Cryst. (1962)
{'key': '2024020823092124600_r8'}
{'key': '2024020823092124600_r9', 'first-page': '169', 'volume': '24', 'year': '1956', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1956)
10.1021/ja01604a012 / J. Am. Chem. Soc. (1956)
{'key': '2024020823092124600_r11', 'first-page': 'C', 'volume': '50', 'year': '1953', 'journal-title': 'J. Chim. Phys.'} / J. Chim. Phys. (1953)
{'key': '2024020823092124600_r12', 'first-page': '1421', 'volume': '21', 'year': '1953', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1953)
{'key': '2024020823092124600_r13', 'first-page': '4113', 'volume': '75', 'year': '1953', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1953)
10.1063/1.1742330 / J. Chem. Phys. (1955)
10.1139/v60-334 / Can. J. Chem. (1960)
10.1139/v54-070 / Can. J. Chem. (1954)
10.1038/189211a0 / Nature (1961)
10.1021/ja00886a008 / J. Am. Chem. Soc. (1963)
10.1039/tf9454100174 / Trans. Faraday Soc. (1945)
10.1063/1.1700760 / J. Chem. Phys. (1952)
10.1107/S0365110X51000805 / Acta Cryst. (1951)
{'key': '2024020823092124600_r22'}
10.1021/ac60068a007 / Anal. Chem. (1952)
10.1063/1.1747346 / J. Chem. Phys. (1949)
10.1039/df9500900115 / Disc. Faraday Soc. (1950)
10.1002/jlac.19244400119 / Ann. Chem. (1924)
{'key': '2024020823092124600_r27', 'first-page': '1589', 'volume': '3', 'year': '1958', 'journal-title': 'Zh. Neorgan. Khim.'} / Zh. Neorgan. Khim. (1958)
{'key': '2024020823092124600_r28', 'first-page': '2382', 'volume': '3', 'year': '1958', 'journal-title': 'Zh. Neorgan. Khim.'} / Zh. Neorgan. Khim. (1958)
{'key': '2024020823092124600_r29'}
{'key': '2024020823092124600_r30'}
10.1139/v62-077 / Can. J. Chem. (1962)
10.1139/v62-148 / Can. J. Chem. (1962)
10.1021/ic50007a066 / Inorg. Chem. (1963)
10.1021/ja01486a014 / J. Am. Chem. Soc. (1960)
10.1021/ja01160a005 / J. Am. Chem. Soc. (1950)
{'key': '2024020823092124600_r36', 'first-page': '1063', 'volume': '246', 'year': '1958', 'journal-title': 'Compt. Rend.'} / Compt. Rend. (1958)
10.1039/TF9615701286 / Trans. Faraday Soc. (1961)
10.1139/v62-100 / Can. J. Chem. (1962)
{'key': '2024020823092124600_r39', 'first-page': '328', 'volume': '4', 'year': '1960', 'journal-title': 'Soviet Phys.-Cryst.'} / Soviet Phys.-Cryst. (1960)
{'key': '2024020823092124600_r39a', 'first-page': '353', 'volume': '4', 'year': '1959', 'journal-title': 'Kristallografiya'} / Kristallografiya (1959)
10.1021/ja01253a014 / J. Am. Chem. Soc. (1942)
{'key': '2024020823092124600_r41', 'first-page': '980', 'volume': 'B70', 'year': '1957', 'journal-title': 'Proc. Phys. Soc. (London)'} / Proc. Phys. Soc. (London) (1957)
10.1107/S0365110X5700016X / Acta Cryst. (1957)
{'key': '2024020823092124600_r43'}
10.1063/1.1748298 / J. Chem. Phys. (1951)
{'key': '2024020823092124600_r45', 'first-page': '147', 'volume': '19', 'year': '1961', 'journal-title': 'Arkiv Fysik'} / Arkiv Fysik (1961)
{'key': '2024020823092124600_r45a', 'first-page': '1', 'volume': '21', 'year': '1962', 'journal-title': 'Ark. Fys.'} / Ark. Fys. (1962)
{'key': '2024020823092124600_r46', 'first-page': '1692', 'volume': '257', 'year': '1963', 'journal-title': 'Compt. Rend.'} / Compt. Rend. (1963)
10.1016/0022-3697(59)90222-7 / J. Phys. Chem. Solids (1959)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:09 p.m.)
Indexed	1 year, 3 months ago (May 22, 2024, 4:34 a.m.)
Issued	60 years, 10 months ago (Nov. 1, 1964)
Published	60 years, 10 months ago (Nov. 1, 1964)
Published Print	60 years, 10 months ago (Nov. 1, 1964)

Funders 0

None

BibTeX

@article{Savoie_1964, title={Infrared Study of the Crystalline Monohydrates of Nitric, Perchloric, and Sulfuric Acids}, volume={41}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1726340}, DOI={10.1063/1.1726340}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Savoie, Rodrigue and Giguère, Paul A.}, year={1964}, month=nov, pages={2698–2705} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        5,
        22
      ]
    ],
    "date-time": "2024-05-22T08:34:28Z",
    "timestamp": 1716366868568
  },
  "reference-count": 50,
  "publisher": "AIP Publishing",
  "issue": "9",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1964,
        11,
        1
      ]
    ]
  },
  "abstract": "<jats:p>The infrared spectra of the solid monohydrates of three strong acids nitric, perchloric, and sulfuric were measured down to 50 cm\u20141. The last two are completely ionic, viz., H3O+ClO4\u2014 and H3O+HSO4\u2014, but the first one always seems to retain a trace of covalent structure, HNO3\u00b7H2O. In the three hydrogen-bonded lattices the H3O+ ions have libration frequencies of the order of 700 cm\u20141 and translation frequencies lying between 120 and 400 cm\u20141. The frequencies of these lattice modes increase with the strengths of the hydrogen bonds. The deuterated hydrate of sulfuric acid gave only vitreous spectra because of supercooling. Likewise the room-temperature phase of perchloric acid monohydrate showed broad, diffuse absorption bands due to the disordered orientation of the hydronium ions. The pyramidal configuration of the H3O+ ion is confirmed definitely.</jats:p>",
  "DOI": "10.1063/1.1726340",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        9
      ]
    ],
    "date-time": "2005-01-09T06:59:58Z",
    "timestamp": 1105253998000
  },
  "page": "2698-2705",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 66,
  "title": "Infrared Study of the Crystalline Monohydrates of Nitric, Perchloric, and Sulfuric Acids",
  "prefix": "10.1063",
  "volume": "41",
  "author": [
    {
      "given": "Rodrigue",
      "family": "Savoie",
      "sequence": "first",
      "affiliation": [
        {
          "name": "D\u00e9partement de Chimie, Universit\u00e9 Laval, Qu\u00e9bec, Canada"
        }
      ]
    },
    {
      "given": "Paul A.",
      "family": "Gigu\u00e8re",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "D\u00e9partement de Chimie, Universit\u00e9 Laval, Qu\u00e9bec, Canada"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020823092124600_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1261",
      "DOI": "10.1039/tf9514701261",
      "volume": "47",
      "year": "1951",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020823092124600_r2",
      "doi-asserted-by": "crossref",
      "first-page": "1069",
      "DOI": "10.1063/1.1748467",
      "volume": "19",
      "year": "1951",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823092124600_r2a",
      "first-page": "102",
      "volume": "7",
      "year": "1951",
      "journal-title": "J. Phys. Soc. Japan"
    },
    {
      "key": "2024020823092124600_r3",
      "doi-asserted-by": "crossref",
      "first-page": "307",
      "DOI": "10.1039/tf9524800307",
      "volume": "48",
      "year": "1952",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020823092124600_r4",
      "doi-asserted-by": "crossref",
      "first-page": "157",
      "DOI": "10.1107/S0365110X53000521",
      "volume": "6",
      "year": "1953",
      "journal-title": "Acta Cryst."
    },
    {
      "key": "2024020823092124600_r5",
      "doi-asserted-by": "crossref",
      "first-page": "17",
      "DOI": "10.1107/S0365110X59000056",
      "volume": "12",
      "year": "1959",
      "journal-title": "Acta Cryst."
    },
    {
      "key": "2024020823092124600_r6",
      "doi-asserted-by": "crossref",
      "first-page": "279",
      "DOI": "10.1021/j150572a035",
      "volume": "63",
      "year": "1959",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020823092124600_r7",
      "doi-asserted-by": "crossref",
      "first-page": "18",
      "DOI": "10.1107/S0365110X62000055",
      "volume": "15",
      "year": "1962",
      "journal-title": "Acta Cryst."
    },
    {
      "key": "2024020823092124600_r8"
    },
    {
      "key": "2024020823092124600_r9",
      "first-page": "169",
      "volume": "24",
      "year": "1956",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823092124600_r10",
      "doi-asserted-by": "crossref",
      "first-page": "5999",
      "DOI": "10.1021/ja01604a012",
      "volume": "78",
      "year": "1956",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020823092124600_r11",
      "first-page": "C",
      "volume": "50",
      "year": "1953",
      "journal-title": "J. Chim. Phys."
    },
    {
      "key": "2024020823092124600_r12",
      "first-page": "1421",
      "volume": "21",
      "year": "1953",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823092124600_r13",
      "first-page": "4113",
      "volume": "75",
      "year": "1953",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020823092124600_r14",
      "doi-asserted-by": "crossref",
      "first-page": "1464",
      "DOI": "10.1063/1.1742330",
      "volume": "23",
      "year": "1955",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823092124600_r15",
      "doi-asserted-by": "crossref",
      "first-page": "2467",
      "DOI": "10.1139/v60-334",
      "volume": "38",
      "year": "1960",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020823092124600_r16",
      "doi-asserted-by": "crossref",
      "first-page": "550",
      "DOI": "10.1139/v54-070",
      "volume": "32",
      "year": "1954",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020823092124600_r17",
      "doi-asserted-by": "crossref",
      "first-page": "211",
      "DOI": "10.1038/189211a0",
      "volume": "189",
      "year": "1961",
      "journal-title": "Nature"
    },
    {
      "key": "2024020823092124600_r18",
      "doi-asserted-by": "crossref",
      "first-page": "287",
      "DOI": "10.1021/ja00886a008",
      "volume": "85",
      "year": "1963",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020823092124600_r19",
      "doi-asserted-by": "crossref",
      "first-page": "174",
      "DOI": "10.1039/tf9454100174",
      "volume": "41",
      "year": "1945",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020823092124600_r20",
      "doi-asserted-by": "crossref",
      "first-page": "1345",
      "DOI": "10.1063/1.1700760",
      "volume": "20",
      "year": "1952",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823092124600_r21",
      "doi-asserted-by": "crossref",
      "first-page": "239",
      "DOI": "10.1107/S0365110X51000805",
      "volume": "4",
      "year": "1951",
      "journal-title": "Acta Cryst."
    },
    {
      "key": "2024020823092124600_r22"
    },
    {
      "key": "2024020823092124600_r23",
      "doi-asserted-by": "crossref",
      "first-page": "1253",
      "DOI": "10.1021/ac60068a007",
      "volume": "24",
      "year": "1952",
      "journal-title": "Anal. Chem."
    },
    {
      "key": "2024020823092124600_r24",
      "doi-asserted-by": "crossref",
      "first-page": "607",
      "DOI": "10.1063/1.1747346",
      "volume": "17",
      "year": "1949",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823092124600_r25",
      "doi-asserted-by": "crossref",
      "first-page": "115",
      "DOI": "10.1039/df9500900115",
      "volume": "9",
      "year": "1950",
      "journal-title": "Disc. Faraday Soc."
    },
    {
      "key": "2024020823092124600_r26",
      "doi-asserted-by": "crossref",
      "first-page": "200",
      "DOI": "10.1002/jlac.19244400119",
      "volume": "440",
      "year": "1924",
      "journal-title": "Ann. Chem."
    },
    {
      "key": "2024020823092124600_r27",
      "first-page": "1589",
      "volume": "3",
      "year": "1958",
      "journal-title": "Zh. Neorgan. Khim."
    },
    {
      "key": "2024020823092124600_r28",
      "first-page": "2382",
      "volume": "3",
      "year": "1958",
      "journal-title": "Zh. Neorgan. Khim."
    },
    {
      "key": "2024020823092124600_r29"
    },
    {
      "key": "2024020823092124600_r30"
    },
    {
      "key": "2024020823092124600_r31",
      "doi-asserted-by": "crossref",
      "first-page": "495",
      "DOI": "10.1139/v62-077",
      "volume": "40",
      "year": "1962",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020823092124600_r32",
      "doi-asserted-by": "crossref",
      "first-page": "991",
      "DOI": "10.1139/v62-148",
      "volume": "40",
      "year": "1962",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020823092124600_r33",
      "doi-asserted-by": "crossref",
      "first-page": "654",
      "DOI": "10.1021/ic50007a066",
      "volume": "2",
      "year": "1963",
      "journal-title": "Inorg. Chem."
    },
    {
      "key": "2024020823092124600_r34",
      "doi-asserted-by": "crossref",
      "first-page": "62",
      "DOI": "10.1021/ja01486a014",
      "volume": "82",
      "year": "1960",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020823092124600_r35",
      "doi-asserted-by": "crossref",
      "first-page": "1445",
      "DOI": "10.1021/ja01160a005",
      "volume": "72",
      "year": "1950",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020823092124600_r36",
      "first-page": "1063",
      "volume": "246",
      "year": "1958",
      "journal-title": "Compt. Rend."
    },
    {
      "key": "2024020823092124600_r37",
      "doi-asserted-by": "crossref",
      "first-page": "1286",
      "DOI": "10.1039/TF9615701286",
      "volume": "57",
      "year": "1961",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020823092124600_r38",
      "doi-asserted-by": "crossref",
      "first-page": "644",
      "DOI": "10.1139/v62-100",
      "volume": "40",
      "year": "1962",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020823092124600_r39",
      "first-page": "328",
      "volume": "4",
      "year": "1960",
      "journal-title": "Soviet Phys.-Cryst."
    },
    {
      "key": "2024020823092124600_r39a",
      "first-page": "353",
      "volume": "4",
      "year": "1959",
      "journal-title": "Kristallografiya"
    },
    {
      "key": "2024020823092124600_r40",
      "doi-asserted-by": "crossref",
      "first-page": "48",
      "DOI": "10.1021/ja01253a014",
      "volume": "64",
      "year": "1942",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020823092124600_r41",
      "first-page": "980",
      "volume": "B70",
      "year": "1957",
      "journal-title": "Proc. Phys. Soc. (London)"
    },
    {
      "key": "2024020823092124600_r42",
      "doi-asserted-by": "crossref",
      "first-page": "70",
      "DOI": "10.1107/S0365110X5700016X",
      "volume": "10",
      "year": "1957",
      "journal-title": "Acta Cryst."
    },
    {
      "key": "2024020823092124600_r43"
    },
    {
      "key": "2024020823092124600_r44",
      "doi-asserted-by": "crossref",
      "first-page": "594",
      "DOI": "10.1063/1.1748298",
      "volume": "19",
      "year": "1951",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823092124600_r45",
      "first-page": "147",
      "volume": "19",
      "year": "1961",
      "journal-title": "Arkiv Fysik"
    },
    {
      "key": "2024020823092124600_r45a",
      "first-page": "1",
      "volume": "21",
      "year": "1962",
      "journal-title": "Ark. Fys."
    },
    {
      "key": "2024020823092124600_r46",
      "first-page": "1692",
      "volume": "257",
      "year": "1963",
      "journal-title": "Compt. Rend."
    },
    {
      "key": "2024020823092124600_r47",
      "doi-asserted-by": "crossref",
      "first-page": "249",
      "DOI": "10.1016/0022-3697(59)90222-7",
      "volume": "11",
      "year": "1959",
      "journal-title": "J. Phys. Chem. Solids"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/41/9/2698/18835663/2698_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/41/9/2698/18835663/2698_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T23:09:47Z",
    "timestamp": 1707433787000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/41/9/2698/209654/Infrared-Study-of-the-Crystalline-Monohydrates-of"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1964,
        11,
        1
      ]
    ]
  },
  "references-count": 50,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          1964,
          11,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1726340",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1964,
        11,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1964,
        11,
        1
      ]
    ]
  }
}