DOI: 10.1063/1.1726222. Dissociative Ionization of N2 and N2O by Rare-Gas Ion Impact

Dissociative Ionization of N2 and N2O by Rare-Gas Ion Impact

10.1063/1.1726222

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Cross sections for the reactionsNe++N2→N++N+Ne,Kr++N2O→O++N2+Kr,Ar++N2→N++N+Ar,Kr++N2O→N+NO++Kr,are measured as functions of primary ion kinetic energy. All of these reactions exhibit thresholds, and a semiempirical formula is fitted to the data near to the threshold energies. Despite the isoelectronic character of the products of Kr++N2O→O++N2+Kr and Kr++N2O→N+NO++Kr, their behavior differs in that the former reaction proceeds by the energetically most favorable channel while the latter does not; the reaction Kr++N2O→N+NO++Kr is energetically allowed for all primary ion kinetic energies but appears not to proceed below kinetic energies of about 2.4 eV in the center-of-mass coordinate system. The cross sections of reactions involving only atomic products do not exhibit any striking, qualitative differences from those cross sections involving molecular products.

Bibliography

Maier, W. B. (1964). Dissociative Ionization of N2 and N2O by Rare-Gas Ion Impact. The Journal of Chemical Physics, 41(7), 2174â2181.

Authors 1

William B. Maier (first)

References 34 Referenced 58

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:05 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 2:28 p.m.)
Issued	60 years, 11 months ago (Oct. 1, 1964)
Published	60 years, 11 months ago (Oct. 1, 1964)
Published Print	60 years, 11 months ago (Oct. 1, 1964)

Funders 0

None

BibTeX

@article{Maier_1964, title={Dissociative Ionization of N2 and N2O by Rare-Gas Ion Impact}, volume={41}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1726222}, DOI={10.1063/1.1726222}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Maier, William B.}, year={1964}, month=oct, pages={2174–2181} }

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