DOI: 10.1063/1.1726152. Electrically Induced Perturbations of Halogen Nuclear Quadrupole Interactions in Polycrystalline Compounds. I. Phenomenological Theory and Experimental Results

Electrically Induced Perturbations of Halogen Nuclear Quadrupole Interactions in Polycrystalline Compounds. I. Phenomenological Theory and Experimental Results

10.1063/1.1726152

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

When a nucleus in a dielectric solid occupies a lattice site which lacks inversion symmetry, the application of an external electric field causes a change in the electric field gradient at this nucleus. The magnitude of the change is proportional to the applied field. When the nucleus has spin greater than one-half and possesses a nonzero quadrupole moment, the quadrupole interaction energy is, therefore, a linear function of the applied field. This field gradient perturbation is discussed phenomenologically through the use of a third rank tensor R which relates the electric field and the electric field gradient via the equation eΔq=R·E. Changes in the quadrupole interaction energy, observed as broadenings of nuclear quadrupole resonance lines in zero magnetic field, have been obtained for 35Cl, 81Br, and 127I nuclei in halogenated polycrystalline compounds including several halogenated methanes and benzenes, the solid halogens, and iodic acid. Broadened line shapes, local electric field corrections, and restrictions imposed by nuclear site symmetries are discussed. All observations are consistent with the phenomenological theory.

Bibliography

Dixon, R. W., & Bloembergen, N. (1964). Electrically Induced Perturbations of Halogen Nuclear Quadrupole Interactions in Polycrystalline Compounds. I. Phenomenological Theory and Experimental Results. The Journal of Chemical Physics, 41(6), 1720â1738.

Authors 2

R. W. Dixon (first)
N. Bloembergen (additional)

References 51 Referenced 35

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:01 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 2:25 a.m.)
Issued	60 years, 11 months ago (Sept. 15, 1964)
Published	60 years, 11 months ago (Sept. 15, 1964)
Published Print	60 years, 11 months ago (Sept. 15, 1964)

Funders 0

None

BibTeX

@article{Dixon_1964, title={Electrically Induced Perturbations of Halogen Nuclear Quadrupole Interactions in Polycrystalline Compounds. I. Phenomenological Theory and Experimental Results}, volume={41}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1726152}, DOI={10.1063/1.1726152}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Dixon, R. W. and Bloembergen, N.}, year={1964}, month=sep, pages={1720–1738} }

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