DOI: 10.1063/1.1725512. Molecular Reorientation in Liquids. Deuteron Quadrupole Relaxation in Liquid Deuterium Oxide and Perdeuterobenzene

Molecular Reorientation in Liquids. Deuteron Quadrupole Relaxation in Liquid Deuterium Oxide and Perdeuterobenzene

10.1063/1.1725512

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Temperature-dependence measurements have been made on the deuteron spin—lattice relaxation times for liquid deuterium oxide and perdeuterobenzene. The quadrupole spin—lattice relaxation is expressed in terms of motional models previously developed for magnetic dipole—dipole relaxation. The deuterium oxide data are discussed in terms of microwave, dielectric relaxation, and hydrogen-bonding phenomena. The T1 values follow rather closely a proportionality to absolute temperature divided by viscosity. The effective quadrupole coupling constant is only ⅔ to ¾ of the value derived from microwave data. For perdeuterobenzene, the 1.86-kcal/mole activation energy rules out a dominance of the rotational-inertia effect proposed recently by Steele. The temperature dependence is much lower than that of the absolute temperature divided by viscosity. Possible reasons for this are discussed. By use of proton-relaxation data, a quadrupole coupling constant value of 138 kc/sec is estimated, assuming axial symmetry of the electric-field gradient about the C—D bond.

Bibliography

Woessner, D. E. (1964). Molecular Reorientation in Liquids. Deuteron Quadrupole Relaxation in Liquid Deuterium Oxide and Perdeuterobenzene. The Journal of Chemical Physics, 40(8), 2341â2348.

Authors 1

D. E. Woessner (first)

References 56 Referenced 95

{'key': '2024020822270237400_r1'}
10.1103/PhysRev.73.679 / Phys. Rev. (1948)
{'key': '2024020822270237400_r3'}
{'key': '2024020822270237400_r4'}
{'key': '2024020822270237400_r5', 'first-page': '522', 'volume': '8a', 'year': '1953', 'journal-title': 'Z. Naturforsch.'} / Z. Naturforsch. (1953)
10.1063/1.1731140 / J. Chem. Phys. (1960)
10.1063/1.1701002 / J. Chem. Phys. (1961)
{'key': '2024020822270237400_r8', 'first-page': '452', 'volume': '9', 'year': '1960', 'journal-title': 'Bull. Ampere'} / Bull. Ampere (1960)
10.1051/jphysrad:01934005010049700 / J. Phys. Radium (1934)
10.1063/1.1701390 / J. Chem. Phys. (1962)
10.1063/1.1733159 / J. Chem. Phys. (1962)
{'key': '2024020822270237400_r12', 'first-page': '353', 'volume': '15', 'year': '1962', 'journal-title': 'Soviet Phys.-JETP'} / Soviet Phys.-JETP (1962)
{'key': '2024020822270237400_r12a', 'first-page': '503', 'volume': '42', 'year': '1962', 'journal-title': 'Zh. Eksperim. i Teor. Fiz.'} / Zh. Eksperim. i Teor. Fiz. (1962)
{'key': '2024020822270237400_r13', 'first-page': '363', 'volume': '6', 'year': '1961', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1961)
{'key': '2024020822270237400_r14', 'first-page': '815', 'volume': '16', 'year': '1963', 'journal-title': 'Soviet Phys.-JETP'} / Soviet Phys.-JETP (1963)
{'key': '2024020822270237400_r14a', 'first-page': '1154', 'volume': '43', 'year': '1962', 'journal-title': 'Zh. Eksperim. i Teor. Fiz.'} / Zh. Eksperim. i Teor. Fiz. (1962)
10.1103/PhysRevLett.6.349 / Phys. Rev. Letters (1961)
10.1063/1.1733516 / J. Chem. Phys. (1963)
10.1063/1.1733517 / J. Chem. Phys. (1963)
10.1063/1.1733518 / J. Chem. Phys. (1963)
10.1063/1.1733817 / J. Chem. Phys. (1963)
{'key': '2024020822270237400_r20', 'first-page': '532', 'volume': '8a', 'year': '1953', 'journal-title': 'Z. Naturforsch.'} / Z. Naturforsch. (1953)
{'key': '2024020822270237400_r21', 'first-page': '145', 'volume': 'B60', 'year': '1948', 'journal-title': 'Proc. Phys. Soc. (London)'} / Proc. Phys. Soc. (London) (1948)
10.1063/1.1743585 / J. Chem. Phys. (1957)
{'key': '2024020822270237400_r23', 'first-page': '537', 'volume': 'A218', 'year': '1953', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1953)
10.1016/S0081-1947(08)60105-8 / Solid State Phys. (1957)
10.1080/00268975800100201 / Mol. Phys. (1958)
{'key': '2024020822270237400_r26'}
{'key': '2024020822270237400_r27', 'first-page': '945', 'volume': '92', 'year': '1953', 'journal-title': 'Phys. Rev.'} / Phys. Rev. (1953)
10.1063/1.1730170 / J. Chem. Phys. (1959)
{'key': '2024020822270237400_r29'}
{'key': '2024020822270237400_r30'}
{'key': '2024020822270237400_r31', 'first-page': '398', 'volume': 'A216', 'year': '1953', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1953)
10.1063/1.1716004 / Rev. Sci. Instr. (1958)
10.6028/jres.023.008 / J. Res. Natl. Bur. Std. (U.S.) (1939)
10.1103/PhysRev.52.662 / Phys. Rev. (1937)
10.1103/PhysRev.111.1201 / Phys. Rev. (1958)
10.1071/PH600168 / Australian J. Phys. (1960)
10.1063/1.1732766 / J. Chem. Phys. (1962)
10.1063/1.1700780 / J. Chem. Phys. (1952)
10.1063/1.1700951 / J. Chem. Phys. (1960)
{'key': '2024020822270237400_r39'}
10.1021/ja01570a003 / J. Am. Chem. Soc. (1957)
{'key': '2024020822270237400_r41', 'first-page': '101', 'volume': 'A240', 'year': '1957', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1957)
10.1063/1.1698980 / J. Chem. Phys. (1953)
10.1063/1.1731414 / J. Chem. Phys. (1960)
10.1021/j150515a012 / J. Phys. Chem. (1954)
{'key': '2024020822270237400_r45', 'first-page': '365', 'volume': '10', 'year': '1961', 'journal-title': 'Bull. Ampere'} / Bull. Ampere (1961)
{'key': '2024020822270237400_r46', 'first-page': '509', 'volume': '49', 'year': '1961', 'journal-title': 'Am. Scientist'} / Am. Scientist (1961)
10.1063/1.1731936 / J. Chem. Phys. (1961)
{'key': '2024020822270237400_r48', 'first-page': '149', 'volume': 'B67', 'year': '1954', 'journal-title': 'Proc. Phys. Soc. (London)'} / Proc. Phys. Soc. (London) (1954)
10.1063/1.1730651 / J. Chem. Phys. (1959)
10.1002/bbpc.19630670311 / Z. Elektrochem. (1963)
10.1103/PhysRev.126.1054 / Phys. Rev. (1962)
10.1103/PhysRev.128.650 / Phys. Rev. (1962)
10.1063/1.1733499 / J. Chem. Phys. (1963)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 11:03 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 5:27 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 10:20 p.m.)
Issued	61 years, 4 months ago (April 15, 1964)
Published	61 years, 4 months ago (April 15, 1964)
Published Print	61 years, 4 months ago (April 15, 1964)

Funders 0

None

BibTeX

@article{Woessner_1964, title={Molecular Reorientation in Liquids. Deuteron Quadrupole Relaxation in Liquid Deuterium Oxide and Perdeuterobenzene}, volume={40}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1725512}, DOI={10.1063/1.1725512}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Woessner, D. E.}, year={1964}, month=apr, pages={2341–2348} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T03:20:25Z",
    "timestamp": 1707535225769
  },
  "reference-count": 56,
  "publisher": "AIP Publishing",
  "issue": "8",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1964,
        4,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Temperature-dependence measurements have been made on the deuteron spin\u2014lattice relaxation times for liquid deuterium oxide and perdeuterobenzene. The quadrupole spin\u2014lattice relaxation is expressed in terms of motional models previously developed for magnetic dipole\u2014dipole relaxation. The deuterium oxide data are discussed in terms of microwave, dielectric relaxation, and hydrogen-bonding phenomena. The T1 values follow rather closely a proportionality to absolute temperature divided by viscosity. The effective quadrupole coupling constant is only \u2154 to \u00be of the value derived from microwave data. For perdeuterobenzene, the 1.86-kcal/mole activation energy rules out a dominance of the rotational-inertia effect proposed recently by Steele. The temperature dependence is much lower than that of the absolute temperature divided by viscosity. Possible reasons for this are discussed. By use of proton-relaxation data, a quadrupole coupling constant value of 138 kc/sec is estimated, assuming axial symmetry of the electric-field gradient about the C\u2014D bond.</jats:p>",
  "DOI": "10.1063/1.1725512",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        6
      ]
    ],
    "date-time": "2005-01-06T04:03:42Z",
    "timestamp": 1104984222000
  },
  "page": "2341-2348",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 95,
  "title": "Molecular Reorientation in Liquids. Deuteron Quadrupole Relaxation in Liquid Deuterium Oxide and Perdeuterobenzene",
  "prefix": "10.1063",
  "volume": "40",
  "author": [
    {
      "given": "D. E.",
      "family": "Woessner",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Socony Mobil Oil Company, Inc., Field Research Laboratory, Dallas, Texas 75221"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020822270237400_r1"
    },
    {
      "key": "2024020822270237400_r2",
      "doi-asserted-by": "crossref",
      "first-page": "679",
      "DOI": "10.1103/PhysRev.73.679",
      "volume": "73",
      "year": "1948",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020822270237400_r3"
    },
    {
      "key": "2024020822270237400_r4"
    },
    {
      "key": "2024020822270237400_r5",
      "first-page": "522",
      "volume": "8a",
      "year": "1953",
      "journal-title": "Z. Naturforsch."
    },
    {
      "key": "2024020822270237400_r6",
      "doi-asserted-by": "crossref",
      "first-page": "86",
      "DOI": "10.1063/1.1731140",
      "volume": "33",
      "year": "1960",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r7",
      "doi-asserted-by": "crossref",
      "first-page": "651",
      "DOI": "10.1063/1.1701002",
      "volume": "34",
      "year": "1961",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r8",
      "first-page": "452",
      "volume": "9",
      "year": "1960",
      "journal-title": "Bull. Ampere"
    },
    {
      "key": "2024020822270237400_r9",
      "doi-asserted-by": "crossref",
      "first-page": "497",
      "DOI": "10.1051/jphysrad:01934005010049700",
      "volume": "5",
      "year": "1934",
      "journal-title": "J. Phys. Radium"
    },
    {
      "key": "2024020822270237400_r10",
      "doi-asserted-by": "crossref",
      "first-page": "647",
      "DOI": "10.1063/1.1701390",
      "volume": "37",
      "year": "1962",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r11",
      "doi-asserted-by": "crossref",
      "first-page": "765",
      "DOI": "10.1063/1.1733159",
      "volume": "37",
      "year": "1962",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r12",
      "first-page": "353",
      "volume": "15",
      "year": "1962",
      "journal-title": "Soviet Phys.-JETP"
    },
    {
      "key": "2024020822270237400_r12a",
      "first-page": "503",
      "volume": "42",
      "year": "1962",
      "journal-title": "Zh. Eksperim. i Teor. Fiz."
    },
    {
      "key": "2024020822270237400_r13",
      "first-page": "363",
      "volume": "6",
      "year": "1961",
      "journal-title": "Bull. Am. Phys. Soc."
    },
    {
      "key": "2024020822270237400_r14",
      "first-page": "815",
      "volume": "16",
      "year": "1963",
      "journal-title": "Soviet Phys.-JETP"
    },
    {
      "key": "2024020822270237400_r14a",
      "first-page": "1154",
      "volume": "43",
      "year": "1962",
      "journal-title": "Zh. Eksperim. i Teor. Fiz."
    },
    {
      "key": "2024020822270237400_r15",
      "doi-asserted-by": "crossref",
      "first-page": "349",
      "DOI": "10.1103/PhysRevLett.6.349",
      "volume": "6",
      "year": "1961",
      "journal-title": "Phys. Rev. Letters"
    },
    {
      "key": "2024020822270237400_r16",
      "doi-asserted-by": "crossref",
      "first-page": "2404",
      "DOI": "10.1063/1.1733516",
      "volume": "38",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r17",
      "doi-asserted-by": "crossref",
      "first-page": "2411",
      "DOI": "10.1063/1.1733517",
      "volume": "38",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r18",
      "doi-asserted-by": "crossref",
      "first-page": "2418",
      "DOI": "10.1063/1.1733518",
      "volume": "38",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r19",
      "doi-asserted-by": "crossref",
      "first-page": "1155",
      "DOI": "10.1063/1.1733817",
      "volume": "38",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r20",
      "first-page": "532",
      "volume": "8a",
      "year": "1953",
      "journal-title": "Z. Naturforsch."
    },
    {
      "key": "2024020822270237400_r21",
      "first-page": "145",
      "volume": "B60",
      "year": "1948",
      "journal-title": "Proc. Phys. Soc. (London)"
    },
    {
      "key": "2024020822270237400_r22",
      "doi-asserted-by": "crossref",
      "first-page": "1575",
      "DOI": "10.1063/1.1743585",
      "volume": "26",
      "year": "1957",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r23",
      "first-page": "537",
      "volume": "A218",
      "year": "1953",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020822270237400_r24",
      "doi-asserted-by": "crossref",
      "first-page": "321",
      "DOI": "10.1016/S0081-1947(08)60105-8",
      "volume": "5",
      "year": "1957",
      "journal-title": "Solid State Phys."
    },
    {
      "key": "2024020822270237400_r25",
      "doi-asserted-by": "crossref",
      "first-page": "168",
      "DOI": "10.1080/00268975800100201",
      "volume": "1",
      "year": "1958",
      "journal-title": "Mol. Phys."
    },
    {
      "key": "2024020822270237400_r26"
    },
    {
      "key": "2024020822270237400_r27",
      "first-page": "945",
      "volume": "92",
      "year": "1953",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020822270237400_r28",
      "doi-asserted-by": "crossref",
      "first-page": "1272",
      "DOI": "10.1063/1.1730170",
      "volume": "30",
      "year": "1959",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r29"
    },
    {
      "key": "2024020822270237400_r30"
    },
    {
      "key": "2024020822270237400_r31",
      "first-page": "398",
      "volume": "A216",
      "year": "1953",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020822270237400_r31a",
      "doi-asserted-by": "crossref",
      "first-page": "55",
      "DOI": "10.1063/1.1716004",
      "volume": "29",
      "year": "1958",
      "journal-title": "Rev. Sci. Instr."
    },
    {
      "key": "2024020822270237400_r32",
      "doi-asserted-by": "crossref",
      "first-page": "197",
      "DOI": "10.6028/jres.023.008",
      "volume": "23",
      "year": "1939",
      "journal-title": "J. Res. Natl. Bur. Std. (U.S.)"
    },
    {
      "key": "2024020822270237400_r33",
      "doi-asserted-by": "crossref",
      "first-page": "662",
      "DOI": "10.1103/PhysRev.52.662",
      "volume": "52",
      "year": "1937",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020822270237400_r34",
      "doi-asserted-by": "crossref",
      "first-page": "1201",
      "DOI": "10.1103/PhysRev.111.1201",
      "volume": "111",
      "year": "1958",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020822270237400_r35",
      "doi-asserted-by": "crossref",
      "first-page": "168",
      "DOI": "10.1071/PH600168",
      "volume": "13",
      "year": "1960",
      "journal-title": "Australian J. Phys."
    },
    {
      "key": "2024020822270237400_r36",
      "doi-asserted-by": "crossref",
      "first-page": "1473",
      "DOI": "10.1063/1.1732766",
      "volume": "36",
      "year": "1962",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r37",
      "doi-asserted-by": "crossref",
      "first-page": "1452",
      "DOI": "10.1063/1.1700780",
      "volume": "20",
      "year": "1952",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r38",
      "doi-asserted-by": "crossref",
      "first-page": "85",
      "DOI": "10.1063/1.1700951",
      "volume": "32",
      "year": "1960",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r39"
    },
    {
      "key": "2024020822270237400_r40",
      "doi-asserted-by": "crossref",
      "first-page": "3310",
      "DOI": "10.1021/ja01570a003",
      "volume": "79",
      "year": "1957",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020822270237400_r41",
      "first-page": "101",
      "volume": "A240",
      "year": "1957",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020822270237400_r42",
      "doi-asserted-by": "crossref",
      "first-page": "633",
      "DOI": "10.1063/1.1698980",
      "volume": "21",
      "year": "1953",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r43",
      "doi-asserted-by": "crossref",
      "first-page": "1371",
      "DOI": "10.1063/1.1731414",
      "volume": "33",
      "year": "1960",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r44",
      "doi-asserted-by": "crossref",
      "first-page": "430",
      "DOI": "10.1021/j150515a012",
      "volume": "58",
      "year": "1954",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020822270237400_r45",
      "first-page": "365",
      "volume": "10",
      "year": "1961",
      "journal-title": "Bull. Ampere"
    },
    {
      "key": "2024020822270237400_r46",
      "first-page": "509",
      "volume": "49",
      "year": "1961",
      "journal-title": "Am. Scientist"
    },
    {
      "key": "2024020822270237400_r47",
      "doi-asserted-by": "crossref",
      "first-page": "81",
      "DOI": "10.1063/1.1731936",
      "volume": "35",
      "year": "1961",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r48",
      "first-page": "149",
      "volume": "B67",
      "year": "1954",
      "journal-title": "Proc. Phys. Soc. (London)"
    },
    {
      "key": "2024020822270237400_r49",
      "doi-asserted-by": "crossref",
      "first-page": "1555",
      "DOI": "10.1063/1.1730651",
      "volume": "31",
      "year": "1959",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020822270237400_r50",
      "doi-asserted-by": "crossref",
      "first-page": "328",
      "DOI": "10.1002/bbpc.19630670311",
      "volume": "67",
      "year": "1963",
      "journal-title": "Z. Elektrochem."
    },
    {
      "key": "2024020822270237400_r51",
      "doi-asserted-by": "crossref",
      "first-page": "1054",
      "DOI": "10.1103/PhysRev.126.1054",
      "volume": "126",
      "year": "1962",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020822270237400_r52",
      "doi-asserted-by": "crossref",
      "first-page": "650",
      "DOI": "10.1103/PhysRev.128.650",
      "volume": "128",
      "year": "1962",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020822270237400_r53",
      "doi-asserted-by": "crossref",
      "first-page": "76",
      "DOI": "10.1063/1.1733499",
      "volume": "38",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/40/8/2341/18832689/2341_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/40/8/2341/18832689/2341_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T22:27:23Z",
    "timestamp": 1707431243000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/40/8/2341/209289/Molecular-Reorientation-in-Liquids-Deuteron"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1964,
        4,
        15
      ]
    ]
  },
  "references-count": 56,
  "journal-issue": {
    "issue": "8",
    "published-print": {
      "date-parts": [
        [
          1964,
          4,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1725512",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1964,
        4,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1964,
        4,
        15
      ]
    ]
  }
}