DOI: 10.1063/1.1725245. Polarized Emission and Triplet—Triplet Absorption Spectra of Aromatic Hydrocarbons in Benzophenone Crystals [Penn]

Polarized Emission and Triplet—Triplet Absorption Spectra of Aromatic Hydrocarbons in Benzophenone Crystals

10.1063/1.1725245

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The polarization of the phosphorescence of naphthalene, anthracene, pyrene, and chrysene as guest in the benzophenone lattice have been examined. Considerable out-of-plane intensity has been shown to be present in these transitions. The results have confirmed conclusions from previous experimental observations and have led to certain assignments for the lowest triplet states which are in agreement with theoretical predictions. The triplet—triplet absorption spectra of naphthalene, anthracene, and chrysene have been detected using polarized light and the mixed crystals. All these T—T transitions were polarized in the aromatic molecular planes, in accordance with theory. The phosphorescence of pyrene in benzophenone has been analyzed and tentatively interpreted as triplet—singlet emission of the pyrene dimer.

Bibliography

Hochstrasser, R. M., & Lower, S. K. (1964). Polarized Emission and TripletâTriplet Absorption Spectra of Aromatic Hydrocarbons in Benzophenone Crystals. The Journal of Chemical Physics, 40(4), 1041â1046.

Authors 2

Robin M. Hochstrasser (first)
Stephen K. Lower (additional)

References 25 Referenced 39

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 11:03 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 5:19 p.m.)
Indexed	1 year, 6 months ago (Feb. 27, 2024, 12:22 a.m.)
Issued	61 years, 6 months ago (Feb. 15, 1964)
Published	61 years, 6 months ago (Feb. 15, 1964)
Published Print	61 years, 6 months ago (Feb. 15, 1964)

Funders 0

None

BibTeX

@article{Hochstrasser_1964, title={Polarized Emission and Triplet—Triplet Absorption Spectra of Aromatic Hydrocarbons in Benzophenone Crystals}, volume={40}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1725245}, DOI={10.1063/1.1725245}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hochstrasser, Robin M. and Lower, Stephen K.}, year={1964}, month=feb, pages={1041–1046} }

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