DOI: 10.1063/1.1723791. Statistical Mechanics of Cross-Linked Polymer Networks I. Rubberlike Elasticity

Statistical Mechanics of Cross-Linked Polymer Networks I. Rubberlike Elasticity

10.1063/1.1723791

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A model is proposed for the structure of a cross-linked network, such as exists in a vulcanized rubber, which is amenable to statistical treatment. Expressions are derived for the structural entropy of the network, and for the entropy change on deformation. The latter is in agreement with the relationship derived by Wall and others by a different treatment.

Bibliography

Flory, P. J., & Rehner, J. (1943). Statistical Mechanics of Cross-Linked Polymer Networks I. Rubberlike Elasticity. The Journal of Chemical Physics, 11(11), 512â520.

Authors 2

Paul J. Flory (first)
John Rehner (additional)

References 26 Referenced 2,069

{'key': '2024020812350471800_r1'}
10.1002/hlca.19350180176 / Helv. Chim. Acta (1935)
{'key': '2024020812350471800_r2a', 'first-page': '273', 'volume': '33', 'year': '1930', 'journal-title': 'Proc. Akad. Wetensch. Amst.'} / Proc. Akad. Wetensch. Amst. (1930)
{'key': '2024020812350471800_r2b', 'first-page': '285', 'volume': 'A182', 'year': '1938', 'journal-title': 'Zeits. f. Physik. Chemie'} / Zeits. f. Physik. Chemie (1938)
10.1021/j150422a005 / J. Phys. Chem. (1942)
10.1039/tf9423800293 / Trans. Faraday Soc. (1942)
10.1007/BF01431917 / Kolloid Zeits. (1932)
{'key': '2024020812350471800_r5', 'first-page': '63', 'volume': '65', 'year': '1934', 'journal-title': 'Monats.'} / Monats. (1934)
10.1007/BF01451681 / Kolloid Zeits. (1934)
10.1103/PhysRev.39.746 / Phys. Rev. (1932)
10.1007/BF01451143 / Kolloid Zeits. (1936)
10.1063/1.1723753 / J. Chem. Phys. (1942)
10.1039/tf9433900036 / Trans. Faraday Soc. (1943)
10.1063/1.1723785 / J. Chem. Phys. (1943)
10.1021/ie50377a017 / Ind. Eng. Chem. (1941)
10.1021/ie50395a025 / Ind. Eng. Chem. (1942)
10.1063/1.1723792 / J. Chem. Phys. (1943)
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{'key': '2024020812350471800_r14'}
{'key': '2024020812350471800_r15'}
{'key': '2024020812350471800_r16', 'first-page': '1283', 'volume': '36', 'year': '1940', 'journal-title': 'Ind. Eng. Chem.'} / Ind. Eng. Chem. (1940)
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10.1021/ie50322a007 / Ind. Eng. Chem. (1936)
{'key': '2024020812350471800_r19', 'first-page': '205', 'volume': 'A163', 'year': '1937', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1937)
10.1021/ja01856a061 / J. Am. Chem. Soc. (1941)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 4:58 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:35 a.m.)
Indexed	43 minutes ago (Sept. 2, 2025, 10:50 p.m.)
Issued	81 years, 10 months ago (Nov. 1, 1943)
Published	81 years, 10 months ago (Nov. 1, 1943)
Published Print	81 years, 10 months ago (Nov. 1, 1943)

Funders 0

None

BibTeX

@article{Flory_1943, title={Statistical Mechanics of Cross-Linked Polymer Networks I. Rubberlike Elasticity}, volume={11}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1723791}, DOI={10.1063/1.1723791}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Flory, Paul J. and Rehner, John}, year={1943}, month=nov, pages={512–520} }

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