Abstract
Cleaved germanium surfaces, oxygenated at room temperature, were heated under high vacuum and the restoration of their oxygen-adsorbing capacity was determined. No restoration was observed at 425°C. Above 575°C, however, the oxygen-adsorbing capacity of the surfaces was completely recovered. Discharge of GeO from the surface was associated with this process. The restoration process followed first-order reaction kinetics with an activation energy of 56 kcal/mole. Concurrently with restoration a pronounced decrease in the surface area was observed. The results are discussed in terms of the kinetic and energy requirements of the system.
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Dates
Type | When |
---|---|
Created | 20 years, 4 months ago (April 22, 2005, 12:12 p.m.) |
Deposited | 1 year, 7 months ago (Feb. 1, 2024, 5:34 p.m.) |
Indexed | 1 year, 6 months ago (Feb. 8, 2024, 3:02 p.m.) |
Issued | 67 years, 4 months ago (May 1, 1958) |
Published | 67 years, 4 months ago (May 1, 1958) |
Published Print | 67 years, 4 months ago (May 1, 1958) |
@article{Rosenberg_1958, title={Thermal Restoration of Oxygenated Germanium Surfaces}, volume={29}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1723282}, DOI={10.1063/1.1723282}, number={5}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Rosenberg, A. J. and Robinson, P. H. and Gatos, H. C.}, year={1958}, month=may, pages={771–775} }