Abstract
By rapid cooling from the melt, an amorphous phase has been obtained in palladium—silicon alloys containing 15 to 23 at.% Si. This phase is stable at room temperature and crystallization cannot be detected after one month at 250°C. With rates of heating greater than 20°C/min, rapid crystallization takes place at 400°C, with a heat release of approximately 1000 cal/mole. The electrical resistivity of an alloy containing 17 at.% Si at room temperature is 2.6 times that of the equilibrium alloy. The resistivity decreases linearly with decreasing temperature and is about 95% of the room-temperature value at 2°K. Various factors involved in the retention of amorphous phases in rapidly quenched liquid alloys are discussed.
References
13
Referenced
170
{'key': '2024020208220229400_r1', 'first-page': '869', 'volume': '187', 'year': '1960', 'journal-title': 'Nature'}
/ Nature (1960)10.1063/1.1753718
/ Appl. Phys. Letters (1963){'key': '2024020208220229400_r3', 'first-page': '362', 'volume': '227', 'year': '1963', 'journal-title': 'Trans. Metal AIME'}
/ Trans. Metal AIME (1963)10.1063/1.1718403
/ J. Sci. Instr. (1963){'key': '2024020208220229400_r5'}
10.1063/1.1931150
/ J. Appl. Phys. (1962){'key': '2024020208220229400_r7'}
10.1080/14786436208212676
/ Phil. Mag. (1962){'key': '2024020208220229400_r9'}
{'key': '2024020208220229400_r10', 'first-page': '131', 'volume': '189', 'year': '1961', 'journal-title': 'Nature'}
/ Nature (1961){'key': '2024020208220229400_r11', 'first-page': '422', 'volume': '221', 'year': '1961', 'journal-title': 'Trans. Metal. Soc. AIME'}
/ Trans. Metal. Soc. AIME (1961){'key': '2024020208220229400_r12', 'first-page': '1028', 'volume': '146', 'year': '1908', 'journal-title': 'Compt. Rend.'}
/ Compt. Rend. (1908){'key': '2024020208220229400_r13', 'first-page': '242', 'volume': '191', 'year': '1951', 'journal-title': 'Trans. AIME J. Metals'}
/ Trans. AIME J. Metals (1951)
Dates
Type | When |
---|---|
Created | 20 years, 4 months ago (April 22, 2005, 12:39 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 2, 2024, 4:46 a.m.) |
Indexed | 1 month, 3 weeks ago (June 26, 2025, 12:08 p.m.) |
Issued | 60 years, 1 month ago (July 1, 1965) |
Published | 60 years, 1 month ago (July 1, 1965) |
Published Print | 60 years, 1 month ago (July 1, 1965) |
@article{Duwez_1965, title={Amorphous Phase in Palladium—Silicon Alloys}, volume={36}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1714461}, DOI={10.1063/1.1714461}, number={7}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Duwez, Pol and Willens, R. H. and Crewdson, R. C.}, year={1965}, month=jul, pages={2267–2269} }