DOI: 10.1063/1.1713188. NMR Observations of Drawn Polymers. IV. Molecular Orientation and Mobility in Drawn Polyethylene and Polyoxymethylene

NMR Observations of Drawn Polymers. IV. Molecular Orientation and Mobility in Drawn Polyethylene and Polyoxymethylene

10.1063/1.1713188

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The linewidth and second moment of oriented samples of drawn PE and POM were measured as a function of temperature. from −196° to 160°C, and of the angle between draw direction and magnetic field H0, mostly at 0°, 45°, and 90°. Much detail in the temperature behavior of these quantities is resolved which cannot be observed with unoriented samples. On the basis of linewidth measurements of drawn PE, an interpretation of the high-temperature narrowing of the broad line observed with PE single crystals and PE crystallized from the melt is given. The anisotropy of the decrease in second moment with rising temperature which is related to anisotropic molecular motion was determined for PE, subtracting the contribution due to lattice expansion from the total decrease measured. The ``mobile fraction'' was determined for the two polymers as a function of temperature. In both cases a reduction of mobile fraction upon drawing is observed.

Bibliography

Olf, H. G., & Peterlin, A. (1964). NMR Observations of Drawn Polymers. IV. Molecular Orientation and Mobility in Drawn Polyethylene and Polyoxymethylene. Journal of Applied Physics, 35(11), 3108â3114.

Authors 2

Heinz G. Olf (first)
Anton Peterlin (additional)

References 27 Referenced 53

10.1016/0032-3861(60)90031-8 / Polymer (1960)
10.1063/1.1735465 / J. Appl. Phys. (1960)
10.1002/macp.1960.020370122 / Makromol. Chem. (1960)
10.1002/pol.1960.1204614717 / J. Polymer Sci. (1960)
10.1007/BF01520589 / Kolloid-Z. (1961)
10.1063/1.1777071 / J. Appl. Phys. (1961)
10.1021/j100810a033 / J. Phys. Chem. (1962)
10.1063/1.1729048 / J. Appl. Phys. (1963)
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{'key': '2024020207531754300_r10', 'first-page': '1175', 'volume': 'A1', 'year': '1963', 'journal-title': 'J. Polymer Sci.'} / J. Polymer Sci. (1963)
{'key': '2024020207531754300_r11'}
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10.1002/macp.1959.020340104 / Makromol. Chem. (1959)
{'key': '2024020207531754300_r17'}
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10.1103/PhysRev.74.1168 / Phys. Rev. (1948)
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Dates

Type	When
Created	20 years, 4 months ago (April 22, 2005, 12:38 p.m.)
Deposited	1 year, 7 months ago (Feb. 2, 2024, 4:16 a.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 8:19 a.m.)
Issued	60 years, 10 months ago (Nov. 1, 1964)
Published	60 years, 10 months ago (Nov. 1, 1964)
Published Print	60 years, 10 months ago (Nov. 1, 1964)

Funders 0

None

BibTeX

@article{Olf_1964, title={NMR Observations of Drawn Polymers. IV. Molecular Orientation and Mobility in Drawn Polyethylene and Polyoxymethylene}, volume={35}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1713188}, DOI={10.1063/1.1713188}, number={11}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Olf, Heinz G. and Peterlin, Anton}, year={1964}, month=nov, pages={3108–3114} }

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