DOI: 10.1063/1.1712403. Convective Contribution to Total Conductivity in Fixed-Charge Ionic Systems

Convective Contribution to Total Conductivity in Fixed-Charge Ionic Systems

10.1063/1.1712403

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A theory is presented for the contribution of convective (electro-osmotic) flow to the total electric current in fixed-charge ionic systems. Although the approximations used are severe, no assumption is made as to the geometrical structure of the system; in particular, the existence of capillary pores is not assumed. The result shows that convective flow contributes to the retardation effect of the fixed charges on the mobility of the counterions; moreover, the contribution is such as to suggest the possibility of measuring, in isolation from other factors, the dependence of the counterion self-diffusion coefficient on interactions with the fixed charges.

Bibliography

Manning, G. S. (1967). Convective Contribution to Total Conductivity in Fixed-Charge Ionic Systems. The Journal of Chemical Physics, 47(9), 3377â3381.

Authors 1

Gerald S. Manning (first)

References 12 Referenced 4

10.1021/cr60237a001 / Chem. Rev. (1965)
10.1039/df9562100009 / Discussions Faraday Soc. (1956)
{'key': '2023062100283714300_r2a', 'first-page': '60', 'volume': '62', 'year': '1957', 'journal-title': 'Acta Soc. Med. Upsalien.'} / Acta Soc. Med. Upsalien. (1957)
10.1021/ja01162a082 / J. Am. Chem. Soc. (1950)
10.1063/1.1733791 / J. Chem. Phys. (1963)
10.1063/1.1841040 / J. Chem. Phys. (1967)
10.1039/tf9575301262 / Trans. Faraday Soc. (1957)
10.1051/jcp/1958550263 / J. Chim. Phys. (1958)
10.1063/1.1840663 / J. Chem. Phys. (1967)
10.1039/tf9595501221 / Trans. Faraday Soc. (1959)
10.1103/RevModPhys.15.1 / Rev. Mod. Phys. (1943)
{'key': '2023062100283714300_r11'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:57 a.m.)
Deposited	2 years, 2 months ago (June 21, 2023, 6 a.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 12:26 a.m.)
Issued	57 years, 9 months ago (Nov. 1, 1967)
Published	57 years, 9 months ago (Nov. 1, 1967)
Published Online	21 years, 3 months ago (May 3, 2004)
Published Print	57 years, 9 months ago (Nov. 1, 1967)

Funders 0

None

BibTeX

@article{Manning_1967, title={Convective Contribution to Total Conductivity in Fixed-Charge Ionic Systems}, volume={47}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1712403}, DOI={10.1063/1.1712403}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Manning, Gerald S.}, year={1967}, month=nov, pages={3377–3381} }

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