DOI: 10.1063/1.1712176. Measurement of the Depolarization Ratio for the <i>A</i>1 Raman Line of Carbon Tetrachloride in Binary Mixtures

Measurement of the Depolarization Ratio for the A1 Raman Line of Carbon Tetrachloride in Binary Mixtures

10.1063/1.1712176

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A study of the depolarization ratio of the totally symmetric Raman line of carbon tetrachloride in a series of solutions has been made using a He–Ne laser for the source of incident light. A value for ρs (the depolarization ratio measured with linearly polarized incident light) of 0.0039±0.0002 was found for pure CCl4. The solution results provide experimental evidence that interaction between the molecules in the liquid is a major cause of the deviation from the zero depolarization ratio predicted from symmetry arguments. This conclusion is supported by a consideration of other possible causes of the deviation.

Bibliography

Murphy, W. F., Evans, M. V., & Bender, P. (1967). Measurement of the Depolarization Ratio for the A1 Raman Line of Carbon Tetrachloride in Binary Mixtures. The Journal of Chemical Physics, 47(5), 1836â1839.

Authors 3

William F. Murphy (first)
Monroe V. Evans (additional)
Paul Bender (additional)

References 17 Referenced 51

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10.1364/JOSA.38.000281 / J. Opt. Soc. Am. (1948)
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{'key': '2023062623322343300_r10', 'first-page': '79', 'volume': '149', 'year': '1932', 'journal-title': 'Compt. Rend.'} / Compt. Rend. (1932)
10.1038/162453a0 / Nature (1948)
10.1016/0371-1951(65)80169-2 / Spectrochim. Acta (1965)
10.1364/JOSA.36.000454 / J. Opt. Soc. Am. (1946)
{'key': '2023062623322343300_r14'}
10.1063/1.1746824 / J. Chem. Phys. (1948)
{'key': '2023062623322343300_r18'}
10.1364/JOSA.46.000435 / J. Opt. Soc. Am. (1956)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:57 a.m.)
Deposited	2 years, 2 months ago (June 26, 2023, 8:52 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:44 a.m.)
Issued	58 years ago (Sept. 1, 1967)
Published	58 years ago (Sept. 1, 1967)
Published Online	21 years, 4 months ago (May 3, 2004)
Published Print	58 years ago (Sept. 1, 1967)

Funders 0

None

BibTeX

@article{Murphy_1967, title={Measurement of the Depolarization Ratio for the A1 Raman Line of Carbon Tetrachloride in Binary Mixtures}, volume={47}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1712176}, DOI={10.1063/1.1712176}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Murphy, William F. and Evans, Monroe V. and Bender, Paul}, year={1967}, month=sep, pages={1836–1839} }

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