DOI: 10.1063/1.1712114. Adsorption of Gases on Chromium Films

10.1063/1.1712114

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The adsorption behavior of O2, H2, CH4, C2H6, and C2H4 has been investigated on clean Cr films at 27° and 100°C. The gases adsorbed in the following order; O2&gt;C2H4&gt;H2&gt;C2H6&gt;CH4. No gaseous decomposition products were observed when CH4 adsorbed on a clean Cr surface, but C2H6 interacted with Cr at 100°C to produce appreciable amounts of gaseous H2. Ethylene was found to undergo extensive self-hydrogenation to C2H6 over Cr films at both 27° and 100°C. The presence of preadsorbed oxygen on Cr films at 100°C inhibited both H2 production from adsorbed C2H6 and the self-hydrogenation of C2H4.

Bibliography

McElligott, P. E., Roberts, R. W., & Engel, T. W. (1967). Adsorption of Gases on Chromium Films. The Journal of Chemical Physics, 47(4), 1537â1543.

Authors 3

P. E. McElligott (first)
R. W. Roberts (additional)
T. W. Engel (additional)

References 23 Referenced 5

10.1039/tf9625801159 / Trans. Faraday Soc. (1962)
{'key': '2024020902315122700_r2'}
10.1021/ja01269a023 / J. Am. Chem. Soc. (1938)
{'key': '2024020902315122700_r4'}
10.1021/j100809a027 / J. Phys. Chem. (1962)
10.1038/1991152a0 / Nature (1963)
10.1021/j100826a017 / J. Phys. Chem. (1961)
{'key': '2024020902315122700_r8'}
10.1116/1.1491725 / J. Vacuum Sci. Technol. (1964)
{'key': '2024020902315122700_r10', 'first-page': '417', 'volume': '1960', 'year': '1961', 'journal-title': 'Natl. Symp. Vacuum Technol. Trans.'} / Natl. Symp. Vacuum Technol. Trans. (1961)
10.1038/194038a0 / Nature (1962)
{'key': '2024020902315122700_r12', 'first-page': '81', 'volume': 'A256', 'year': '1960', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1960)
{'key': '2024020902315122700_r13'}
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{'key': '2024020902315122700_r15'}
10.1039/TF9565201618 / Trans. Faraday Soc. (1956)
10.1039/tf9585401692 / Trans. Faraday Soc. (1958)
10.1088/0508-3443/14/8/308 / Brit. J. Appl. Phys. (1963)
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10.1021/j100791a504 / J. Phys. Chem. (1964)
10.1039/TF9534900867 / Trans. Faraday Soc. (1953)
{'key': '2024020902315122700_r21', 'first-page': '361', 'volume': 'A223', 'year': '1954', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1954)
10.1039/tf9524800160 / Trans. Faraday Soc. (1952)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:57 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:33 p.m.)
Indexed	1 year, 5 months ago (March 1, 2024, 1:46 p.m.)
Issued	58 years ago (Aug. 15, 1967)
Published	58 years ago (Aug. 15, 1967)
Published Print	58 years ago (Aug. 15, 1967)

Funders 0

None

BibTeX

@article{McElligott_1967, title={Adsorption of Gases on Chromium Films}, volume={47}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1712114}, DOI={10.1063/1.1712114}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={McElligott, P. E. and Roberts, R. W. and Engel, T. W.}, year={1967}, month=aug, pages={1537–1543} }

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