DOI: 10.1063/1.1712089. Intrinsic Viscosity of a Once-Broken Rod

Intrinsic Viscosity of a Once-Broken Rod

10.1063/1.1712089

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The intrinsic viscosity theory of Kirkwood, Riseman, and Auer is applied to a molecular model of two long rods of equal length connected by a flexible joint. In the nondraining limit, the intrinsic viscosity of a solution of such molecules is predicted to be 15% lower than that for rigid rods of the same molecular weight, in good agreement with experimental results of Teramoto, Yamashita, and Fujita. This reduction in intrinsic viscosity is smaller than would be expected from the radius of gyration.

Bibliography

Yu, H., & Stockmayer, W. H. (1967). Intrinsic Viscosity of a Once-Broken Rod. The Journal of Chemical Physics, 47(4), 1369â1373.

Authors 2

Hyuk Yu (first)
Walter H. Stockmayer (additional)

References 25 Referenced 38

10.1021/ja01586a021 / J. Am. Chem. Soc. (1956)
{'key': '2024020902260539900_r1a'}
{'key': '2024020902260539900_r1b'}
10.1063/1.1840953 / J. Chem. Phys. (1967)
{'key': '2024020902260539900_r3', 'first-page': '679', 'volume': '68', 'year': '1949', 'journal-title': 'Rec. Trav. Chim.'} / Rec. Trav. Chim. (1949)
{'key': '2024020902260539900_r4'}
10.1063/1.1748194 / J. Chem. Phys. (1951)
{'key': '2024020902260539900_r6', 'first-page': '44', 'volume': '6', 'year': '1956', 'journal-title': 'Bull. Kobayashi Inst. Phys. Res.'} / Bull. Kobayashi Inst. Phys. Res. (1956)
10.1063/1.1744610 / J. Chem. Phys. (1958)
{'key': '2024020902260539900_r8', 'first-page': '1858', 'volume': '45', 'year': '1966', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1966)
{'key': '2024020902260539900_r9'}
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10.1063/1.1724075 / J. Chem. Phys. (1946)
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{'key': '2024020902260539900_r18'}
{'key': '2024020902260539900_r19'}
10.1021/ja01062a003 / J. Am. Chem. Soc. (1964)
10.1021/ja01586a021 / J. Am. Chem. Soc. (1956)
10.1016/S0022-2836(63)80095-9 / J. Mol. Biol. (1963)
10.1002/bip.1966.360040708 / Biopolymers (1966)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:57 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:27 p.m.)
Indexed	1 year, 4 months ago (April 26, 2024, 9:44 a.m.)
Issued	58 years ago (Aug. 15, 1967)
Published	58 years ago (Aug. 15, 1967)
Published Print	58 years ago (Aug. 15, 1967)

Funders 0

None

BibTeX

@article{Yu_1967, title={Intrinsic Viscosity of a Once-Broken Rod}, volume={47}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1712089}, DOI={10.1063/1.1712089}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Yu, Hyuk and Stockmayer, Walter H.}, year={1967}, month=aug, pages={1369–1373} }

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