DOI: 10.1063/1.1711920. Diffusion Cloud-Chamber Investigation of Homogeneous Nucleation

Diffusion Cloud-Chamber Investigation of Homogeneous Nucleation

10.1063/1.1711920

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The critical supersaturations for the homogeneous nucleation of ethanol, methanol, hexane, and water were experimentally determined in the temperature range 235° to 295°K using a thermal diffusion cloud chamber. The design, construction, and operation of the chamber are described. A computer solution of the heat and mass flux equations determines the variation of pressure and temperature as a function of chamber height. The determination of the experimental critical supersaturation from chamber conditions is described and a comparison made with the values calculated from the Becker-Doering, Volmer, Zeldovich equation. Good agreement (usually within 5%) is obtained for ethanol, methanol, and hexane over a 60°K temperature range. Experimental difficulties limited the water data to a temperature range less than 15°K and agreement to within 15%.

Bibliography

Katz, J. L., & Ostermier, B. J. (1967). Diffusion Cloud-Chamber Investigation of Homogeneous Nucleation. The Journal of Chemical Physics, 47(2), 478â487.

Authors 2

J. L. Katz (first)
B. J. Ostermier (additional)

References 34 Referenced 193

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{'key': '2024020902262019000_r2'}
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:57 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:27 p.m.)
Indexed	1 year, 6 months ago (Feb. 27, 2024, 6:44 a.m.)
Issued	58 years, 1 month ago (July 15, 1967)
Published	58 years, 1 month ago (July 15, 1967)
Published Print	58 years, 1 month ago (July 15, 1967)

Funders 0

None

BibTeX

@article{Katz_1967, title={Diffusion Cloud-Chamber Investigation of Homogeneous Nucleation}, volume={47}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1711920}, DOI={10.1063/1.1711920}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Katz, J. L. and Ostermier, B. J.}, year={1967}, month=jul, pages={478–487} }

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