DOI: 10.1063/1.1709778. Surface Self-Diffusion of Nickel and Platinum

Surface Self-Diffusion of Nickel and Platinum

10.1063/1.1709778

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The surface rearrangement of nickel and platinum due to (1) an electric field (build-up) and (2) surface tension (annealing) as the net driving force, has been studied by field-electron emission microscopy over the temperature range 510°–750°K for Ni and 550°–850°K for Pt. An Arrhenius-type relationship between temperature and time was found in both cases, so that an activation energy could be associated with each process. It is assumed that this is an average activation energy for surface diffusion. The results of the field build-up experiments gave an activation energy of Qf=19.1±1.9 kcal/mole for Ni over the negative field range (28–38)×106 V/cm, and Qf=26.3±2.6 kcal/mole for Pt over the negative field range (27–39)×106 V/cm. It was possible to measure the effect of the electric field using a method devised earlier by Bettler and Charbonnier. This gave calculated zero-field activation energies of 20.6±2.1 kcal/mole for Ni and 29.7±3.0 kcal/mole for Pt. The results of the annealing experiments (no electric field) gave an activation energy of Q0=21.4±2.1 kcal/mole for Ni and 29.5±3.0 kcal/mole for Pt. (The foregoing indicated uncertainties are estimated over-all limits of error.) It is concluded from the agreement between the results of the two different types of measurement that either type of measurement (for fcc metals) may be used to determine the same quantity within a 10% uncertainty.

Bibliography

Melmed, A. J. (1967). Surface Self-Diffusion of Nickel and Platinum. Journal of Applied Physics, 38(4), 1885â1892.

Authors 1

Allan J. Melmed (first)

References 25 Referenced 63

{'key': '2024020209342578100_r1'}
10.1016/0079-6425(63)90011-2 / Progr. Mater. Sci. (1963)
10.1016/S0065-2539(08)60210-3 / Advan. Electron. Electron Phys. (1960)
{'key': '2024020209342578100_r4'}
{'key': '2024020209342578100_r5', 'first-page': '191', 'volume': 'A286', 'year': '1965', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1965)
{'key': '2024020209342578100_r6'}
{'key': '2024020209342578100_r7'}
{'key': '2024020209342578100_r8'}
{'key': '2024020209342578100_r9', 'first-page': '642', 'volume': '126', 'year': '1959', 'journal-title': 'Z. Physik'} / Z. Physik (1959)
{'key': '2024020209342578100_r10', 'first-page': '1147', 'volume': '1', 'year': '1956', 'journal-title': 'Soviet Phys.-Tech. Phys.'} / Soviet Phys.-Tech. Phys. (1956)
10.1103/PhysRev.117.1452 / Phys. Rev. (1960)
10.1103/PhysRev.119.85 / Phys. Rev. (1960)
{'key': '2024020209342578100_r13'}
{'key': '2024020209342578100_r14'}
{'key': '2024020209342578100_r15'}
10.1063/1.1714360 / J. Appl. Phys. (1965)
{'key': '2024020209342578100_r17', 'first-page': '262', 'volume': 'A176', 'year': '1940', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1940)
10.1002/pssb.19640040321 / Phys. Status Solidi (1964)
10.1063/1.1703074 / J. Appl. Phys. (1965)
10.1063/1.1743484 / J. Chem. Phys. (1957)
10.1016/S0065-2539(08)61226-3 / Advan. Electron. Electron Phys. (1956)
{'key': '2024020209342578100_r22', 'first-page': '48', 'volume': '61', 'year': '1957', 'journal-title': 'Z. Elektrochem.'} / Z. Elektrochem. (1957)
10.1016/0001-6160(64)90055-0 / Acta Met. (1964)
10.1016/0001-6160(62)90203-1 / Acta Met. (1962)
10.1016/0001-6160(61)90034-7 / Acta Met. (1961)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 15, 2005, 10:15 a.m.)
Deposited	1 year, 6 months ago (Feb. 2, 2024, 5:33 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6 a.m.)
Issued	58 years, 5 months ago (March 15, 1967)
Published	58 years, 5 months ago (March 15, 1967)
Published Print	58 years, 5 months ago (March 15, 1967)

Funders 0

None

BibTeX

@article{Melmed_1967, title={Surface Self-Diffusion of Nickel and Platinum}, volume={38}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1709778}, DOI={10.1063/1.1709778}, number={4}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Melmed, Allan J.}, year={1967}, month=mar, pages={1885–1892} }

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