DOI: 10.1063/1.1709103. Intercluster Links—A Mechanism for Flow-Induced Crystallization of Polymer Melts

Intercluster Links—A Mechanism for Flow-Induced Crystallization of Polymer Melts

10.1063/1.1709103

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

An experimental study and review of the literature on the oriented crystallization of high polymers was made to develop an understanding of how ``row-nucleated'' or shishkebab microstructures and the fibrillar links between lamellar crystals may be formed. A new mechanism is proposed for the formation of the fiber nuclei in flowing melts, based on the mechanical alignment and extension of molecules that are entangled with, and extend between, two or more rotating clusters in the melt. Similar alignment of molecules can occur when entangled clusters are pulled to different lamellar crystals during crystallization, producing intercrystallic links.

Bibliography

Williamson, R. B., & Busse, W. F. (1967). Intercluster LinksâA Mechanism for Flow-Induced Crystallization of Polymer Melts. Journal of Applied Physics, 38(11), 4187â4196.

Authors 2

R. B. Williamson (first)
W. F. Busse (additional)

References 15 Referenced 36

{'key': '2024020210015703100_r1'}
10.1002/pol.1955.120157904 / J. Polymer Sci. (1955)
{'key': '2024020210015703100_r3', 'first-page': '1', 'volume': '4', 'year': '1964', 'journal-title': 'S.P.E. Trans.'} / S.P.E. Trans. (1964)
10.1007/BF01507982 / Kolloid Z. (1965)
{'key': '2024020210015703100_r5', 'first-page': '41', 'volume': 'B1', 'year': '1967', 'journal-title': 'J. Macromol. Sci. (Phys.)'} / J. Macromol. Sci. (Phys.) (1967)
10.1126/science.150.3699.1026 / Science (1965)
{'key': '2024020210015703100_r7', 'first-page': '267', 'volume': 'A4', 'year': '1966', 'journal-title': 'J. Polymer Sci.'} / J. Polymer Sci. (1966)
10.1063/1.1707970 / J. Appl. Phys. (1966)
10.1002/pol.1967.110050204 / Polymer Letters (1967)
{'key': '2024020210015703100_r10'}
{'key': '2024020210015703100_r11'}
{'key': '2024020210015703100_r12'}
{'key': '2024020210015703100_r13', 'first-page': '189', 'volume': 'B1', 'year': '1963', 'journal-title': 'J. Polymer Sci.'} / J. Polymer Sci. (1963)
{'key': '2024020210015703100_r14', 'first-page': '235', 'volume': 'B1', 'year': '1967', 'journal-title': 'J. Macromol. Sci. (Phys.)'} / J. Macromol. Sci. (Phys.) (1967)
10.1002/pol.1966.110040917 / J. Polymer Sci. (1966)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 15, 2005, 10:15 a.m.)
Deposited	1 year, 6 months ago (Feb. 2, 2024, 5:50 a.m.)
Indexed	3 months ago (May 21, 2025, 5:46 p.m.)
Issued	57 years, 10 months ago (Oct. 1, 1967)
Published	57 years, 10 months ago (Oct. 1, 1967)
Published Print	57 years, 10 months ago (Oct. 1, 1967)

Funders 0

None

BibTeX

@article{Williamson_1967, title={Intercluster Links—A Mechanism for Flow-Induced Crystallization of Polymer Melts}, volume={38}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1709103}, DOI={10.1063/1.1709103}, number={11}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Williamson, R. B. and Busse, W. F.}, year={1967}, month=oct, pages={4187–4196} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        5,
        21
      ]
    ],
    "date-time": "2025-05-21T21:46:54Z",
    "timestamp": 1747864014920
  },
  "reference-count": 15,
  "publisher": "AIP Publishing",
  "issue": "11",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1967,
        10,
        1
      ]
    ]
  },
  "abstract": "<jats:p>An experimental study and review of the literature on the oriented crystallization of high polymers was made to develop an understanding of how ``row-nucleated'' or shishkebab microstructures and the fibrillar links between lamellar crystals may be formed. A new mechanism is proposed for the formation of the fiber nuclei in flowing melts, based on the mechanical alignment and extension of molecules that are entangled with, and extend between, two or more rotating clusters in the melt. Similar alignment of molecules can occur when entangled clusters are pulled to different lamellar crystals during crystallization, producing intercrystallic links.</jats:p>",
  "DOI": "10.1063/1.1709103",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        15
      ]
    ],
    "date-time": "2005-01-15T15:15:01Z",
    "timestamp": 1105802101000
  },
  "page": "4187-4196",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 36,
  "title": "Intercluster Links\u2014A Mechanism for Flow-Induced Crystallization of Polymer Melts",
  "prefix": "10.1063",
  "volume": "38",
  "author": [
    {
      "given": "R. B.",
      "family": "Williamson",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Civil Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts"
        }
      ]
    },
    {
      "given": "W. F.",
      "family": "Busse",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "803 Greenwood Road, Wilmington, Delaware"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020210015703100_r1"
    },
    {
      "key": "2024020210015703100_r2",
      "doi-asserted-by": "crossref",
      "first-page": "31",
      "DOI": "10.1002/pol.1955.120157904",
      "volume": "15",
      "year": "1955",
      "journal-title": "J. Polymer Sci."
    },
    {
      "key": "2024020210015703100_r3",
      "first-page": "1",
      "volume": "4",
      "year": "1964",
      "journal-title": "S.P.E. Trans."
    },
    {
      "key": "2024020210015703100_r4",
      "doi-asserted-by": "crossref",
      "first-page": "160",
      "DOI": "10.1007/BF01507982",
      "volume": "205",
      "year": "1965",
      "journal-title": "Kolloid Z."
    },
    {
      "key": "2024020210015703100_r5",
      "first-page": "41",
      "volume": "B1",
      "year": "1967",
      "journal-title": "J. Macromol. Sci. (Phys.)"
    },
    {
      "key": "2024020210015703100_r6",
      "doi-asserted-by": "crossref",
      "first-page": "1026",
      "DOI": "10.1126/science.150.3699.1026",
      "volume": "150",
      "year": "1965",
      "journal-title": "Science"
    },
    {
      "key": "2024020210015703100_r7",
      "first-page": "267",
      "volume": "A4",
      "year": "1966",
      "journal-title": "J. Polymer Sci."
    },
    {
      "key": "2024020210015703100_r8",
      "doi-asserted-by": "crossref",
      "first-page": "4027",
      "DOI": "10.1063/1.1707970",
      "volume": "37",
      "year": "1966",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020210015703100_r9",
      "doi-asserted-by": "crossref",
      "first-page": "147",
      "DOI": "10.1002/pol.1967.110050204",
      "volume": "5",
      "year": "1967",
      "journal-title": "Polymer Letters"
    },
    {
      "key": "2024020210015703100_r10"
    },
    {
      "key": "2024020210015703100_r11"
    },
    {
      "key": "2024020210015703100_r12"
    },
    {
      "key": "2024020210015703100_r13",
      "first-page": "189",
      "volume": "B1",
      "year": "1963",
      "journal-title": "J. Polymer Sci."
    },
    {
      "key": "2024020210015703100_r14",
      "first-page": "235",
      "volume": "B1",
      "year": "1967",
      "journal-title": "J. Macromol. Sci. (Phys.)"
    },
    {
      "key": "2024020210015703100_r15",
      "doi-asserted-by": "crossref",
      "first-page": "668",
      "DOI": "10.1002/pol.1966.110040917",
      "volume": "4",
      "year": "1966",
      "journal-title": "J. Polymer Sci."
    }
  ],
  "container-title": "Journal of Applied Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jap/article-pdf/38/11/4187/18343236/4187_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jap/article-pdf/38/11/4187/18343236/4187_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        2
      ]
    ],
    "date-time": "2024-02-02T10:50:08Z",
    "timestamp": 1706871008000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jap/article/38/11/4187/4191/Intercluster-Links-A-Mechanism-for-Flow-Induced"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1967,
        10,
        1
      ]
    ]
  },
  "references-count": 15,
  "journal-issue": {
    "issue": "11",
    "published-print": {
      "date-parts": [
        [
          1967,
          10,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1709103",
  "relation": {},
  "ISSN": [
    "0021-8979",
    "1089-7550"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1967,
        10
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1967,
        10,
        1
      ]
    ]
  }
}