DOI: 10.1063/1.1702720. Kinetics of Melting and Crystallization of Phosphorus Pentoxide

Kinetics of Melting and Crystallization of Phosphorus Pentoxide

10.1063/1.1702720

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The melting and crystallization of tetragonal phosphorus pentoxide has been investigated by the use of a microscopic technique. Superheating of about 50° above the melting temperature was possible. Melting was heterogeneous and began only at free surfaces or grain boundaries but never within a crystal. At a supercool or superheat of 10°, the respective rates were approximately 5 and 10 A/sec. The dependency of melting and crystallization on temperature, time, crystal direction, morphology, and preparation history was studied. Under ideal conditions, the observed rates were in almost quantitative agreement with those calculated from a simple model based primarily on viscosity considerations.

Bibliography

Cormia, R. L., Mackenzie, J. D., & Turnbull, D. (1963). Kinetics of Melting and Crystallization of Phosphorus Pentoxide. Journal of Applied Physics, 34(8), 2239â2244.

Authors 3

R. L. Cormia (first)
J. D. Mackenzie (additional)
D. Turnbull (additional)

References 5 Referenced 83

10.1021/j100827a012 / J. Phys. Chem. (1961)
{'key': '2024020207112986700_r2', 'first-page': '794', 'volume': '65', 'year': '1947', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1947)
{'key': '2024020207112986700_r3'}
{'key': '2024020207112986700_r4'}
{'key': '2024020207112986700_r5', 'first-page': '914', 'volume': '24', 'year': '1956', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1956)

Dates

Type	When
Created	20 years, 4 months ago (April 22, 2005, 12:31 p.m.)
Deposited	1 year, 6 months ago (Feb. 2, 2024, 2:20 a.m.)
Indexed	4 months, 2 weeks ago (April 10, 2025, 6:10 a.m.)
Issued	62 years ago (Aug. 1, 1963)
Published	62 years ago (Aug. 1, 1963)
Published Print	62 years ago (Aug. 1, 1963)

Funders 0

None

BibTeX

@article{Cormia_1963, title={Kinetics of Melting and Crystallization of Phosphorus Pentoxide}, volume={34}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1702720}, DOI={10.1063/1.1702720}, number={8}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Cormia, R. L. and Mackenzie, J. D. and Turnbull, D.}, year={1963}, month=aug, pages={2239–2244} }

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