DOI: 10.1063/1.1701284. Second Virial Coefficients of Argon, Krypton, and Argon-Krypton Mixtures at Low Temperatures

Second Virial Coefficients of Argon, Krypton, and Argon-Krypton Mixtures at Low Temperatures

10.1063/1.1701284

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Second virial coefficients of argon between 80–125°K, and krypton (105–140°K), have been measured. The experimental values are 5–15% larger in magnitude than those calculated from 12–6 or exp—6 potential functions by the substitution of parameters assigned to describe high-temperature virial coefficients. Second virial coefficients calculated from the potential-distance relationship proposed by Guggenheim and McGlashan are within 1% of the experimental values for argon, but are about 4% smaller in magnitude than the measured krypton coefficients. Argon-krypton mixed virial coefficients have been determined between 105–125°K. These experimental results are best expressed by a 12–6 potential energy parameter combining rule ε12=2ε1ε2/ε1+ε2.

Bibliography

Fender, B. E. F., & Halsey, G. D. (1962). Second Virial Coefficients of Argon, Krypton, and Argon-Krypton Mixtures at Low Temperatures. The Journal of Chemical Physics, 36(7), 1881â1888.

Authors 2

B. E. F. Fender (first)
G. D. Halsey (additional)

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:19 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:31 p.m.)
Indexed	1 month, 4 weeks ago (June 24, 2025, 3:47 a.m.)
Issued	63 years, 4 months ago (April 1, 1962)
Published	63 years, 4 months ago (April 1, 1962)
Published Print	63 years, 4 months ago (April 1, 1962)

Funders 0

None

BibTeX

@article{Fender_1962, title={Second Virial Coefficients of Argon, Krypton, and Argon-Krypton Mixtures at Low Temperatures}, volume={36}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1701284}, DOI={10.1063/1.1701284}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Fender, B. E. F. and Halsey, G. D.}, year={1962}, month=apr, pages={1881–1888} }

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  "abstract": "<jats:p>Second virial coefficients of argon between 80\u2013125\u00b0K, and krypton (105\u2013140\u00b0K), have been measured. The experimental values are 5\u201315% larger in magnitude than those calculated from 12\u20136 or exp\u20146 potential functions by the substitution of parameters assigned to describe high-temperature virial coefficients. Second virial coefficients calculated from the potential-distance relationship proposed by Guggenheim and McGlashan are within 1% of the experimental values for argon, but are about 4% smaller in magnitude than the measured krypton coefficients.</jats:p>\n               <jats:p>Argon-krypton mixed virial coefficients have been determined between 105\u2013125\u00b0K. These experimental results are best expressed by a 12\u20136 potential energy parameter combining rule \u03b512=2\u03b51\u03b52/\u03b51+\u03b52.</jats:p>",
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