DOI: 10.1063/1.1700895. Vibrational Spectra of OsF6 and PtF6

10.1063/1.1700895

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Infrared absorption spectra of gaseous OsF6 and PtF6 from 6–50μ and the Raman spectrum of liquid OsF6 are reported. These are interpreted in terms of the octahedral point group Oh, and the six fundamental frequencies are determined. Their values and symmetry species are for OsF6 733 (a1g), 632 (eg), 720 (f1u), 268 (f1u), 252 (f2g), and 230 (f2u); for PtF6 655 (a1g), 601 (eg), 705 (f1u), 273 (f1u), 242 (f2g), and 211 (f2u). Thermodynamic functions, including electronic contributions, are calculated for the ideal gaseous state of both compounds. A comparison of the details of the vibrational spectra of eleven hexafluorides reveals certain characteristic features for OsF6 and ReF6. Since only these two molecules have appropriately degenerate electronic ground states these differences are interpreted as evidence of a Jahn-Teller effect.

Bibliography

Weinstock, B., Claassen, H. H., & Malm, J. G. (1960). Vibrational Spectra of OsF6 and PtF6. The Journal of Chemical Physics, 32(1), 181â185.

Authors 3

Bernard Weinstock (first)
Howard H. Claassen (additional)
John G. Malm (additional)

References 27 Referenced 60

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 9:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 2:19 p.m.)
Indexed	11 months, 1 week ago (Sept. 16, 2024, 11:49 a.m.)
Issued	65 years, 7 months ago (Jan. 1, 1960)
Published	65 years, 7 months ago (Jan. 1, 1960)
Published Print	65 years, 7 months ago (Jan. 1, 1960)

Funders 0

None

BibTeX

@article{Weinstock_1960, title={Vibrational Spectra of OsF6 and PtF6}, volume={32}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1700895}, DOI={10.1063/1.1700895}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Weinstock, Bernard and Claassen, Howard H. and Malm, John G.}, year={1960}, month=jan, pages={181–185} }

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