DOI: 10.1063/1.1700508. The Measurement of Bond Moments and Derivatives in HCN and DCN from Infrared Intensities

The Measurement of Bond Moments and Derivatives in HCN and DCN from Infrared Intensities

10.1063/1.1700508

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The absolute infrared absorption intensities of the fundamental vibrations of HCN and DCN have been measured, using the pressure broadening technique. These measurements yield the bond moments μC–H=±1.13d, μC≡N=±1.80d and show that if C is positive in the C≡N dipole, H is positive in the C–H dipole. The change in moment with internuclear distance is found to be ∂μ/∂rC–H=±1.05d/A, ∂μ/∂rC≡N=∓0.66d/A. Two of the three anomalous peaks in the band ν1 of HCN are shown to arise from the dimer of HCN.

Bibliography

Hyde, G. E., & Hornig, D. F. (1952). The Measurement of Bond Moments and Derivatives in HCN and DCN from Infrared Intensities. The Journal of Chemical Physics, 20(4), 647â652.

Authors 2

G. E. Hyde (first)
D. F. Hornig (additional)

References 19 Referenced 123

10.1063/1.1747823 / J. Chem. Phys. (1950)
10.1063/1.1746461 / J. Chem. Phys. (1947)
10.1063/1.1747469 / J. Chem. Phys. (1950)
10.1063/1.1748401 / J. Chem. Phys. (1951)
10.1063/1.1746366 / J. Chem. Phys. (1947)
10.1103/PhysRev.57.710 / Phys. Rev. (1940)
10.1103/PhysRev.69.628 / Phys. Rev. (1946)
10.1063/1.1724067 / J. Chem. Phys. (1946)
10.1364/JOSA.40.000497 / J. Opt. Soc. Am. (1950)
{'key': '2024020814315646100_r10', 'first-page': '1213', 'volume': '19', 'year': '1951', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1951)
10.1021/ja01323a015 / J. Am. Chem. Soc. (1934)
10.1021/ja01265a017 / J. Am. Chem. Soc. (1939)
10.1063/1.1747132 / J. Chem. Phys. (1949)
10.1103/PhysRev.42.777 / Phys. Rev. (1932)
{'key': '2024020814315646100_r15', 'first-page': '858', 'volume': '194', 'year': '1932', 'journal-title': 'Compt. Rend.'} / Compt. Rend. (1932)
10.1063/1.1747107 / J. Chem. Phys. (1949)
10.1063/1.1748158 / J. Chem. Phys. (1951)
10.1039/TF9423800433 / Trans. Faraday Soc. (1942)
10.1039/tf9383401209 / Trans. Faraday Soc. (1938)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 8:19 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:32 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:43 p.m.)
Issued	73 years, 4 months ago (April 1, 1952)
Published	73 years, 4 months ago (April 1, 1952)
Published Print	73 years, 4 months ago (April 1, 1952)

Funders 0

None

BibTeX

@article{Hyde_1952, title={The Measurement of Bond Moments and Derivatives in HCN and DCN from Infrared Intensities}, volume={20}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1700508}, DOI={10.1063/1.1700508}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hyde, G. E. and Hornig, D. F.}, year={1952}, month=apr, pages={647–652} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T23:43:58Z",
    "timestamp": 1707608638360
  },
  "reference-count": 19,
  "publisher": "AIP Publishing",
  "issue": "4",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1952,
        4,
        1
      ]
    ]
  },
  "abstract": "<jats:p>The absolute infrared absorption intensities of the fundamental vibrations of HCN and DCN have been measured, using the pressure broadening technique. These measurements yield the bond moments \u03bcC\u2013H=\u00b11.13d, \u03bcC\u2261N=\u00b11.80d and show that if C is positive in the C\u2261N dipole, H is positive in the C\u2013H dipole. The change in moment with internuclear distance is found to be \u2202\u03bc/\u2202rC\u2013H=\u00b11.05d/A, \u2202\u03bc/\u2202rC\u2261N=\u22130.66d/A. Two of the three anomalous peaks in the band \u03bd1 of HCN are shown to arise from the dimer of HCN.</jats:p>",
  "DOI": "10.1063/1.1700508",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        9
      ]
    ],
    "date-time": "2005-01-09T13:19:47Z",
    "timestamp": 1105276787000
  },
  "page": "647-652",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 123,
  "title": "The Measurement of Bond Moments and Derivatives in HCN and DCN from Infrared Intensities",
  "prefix": "10.1063",
  "volume": "20",
  "author": [
    {
      "given": "G. E.",
      "family": "Hyde",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Metcalf Chemical Laboratories, Brown University, Providence, Rhode Island"
        }
      ]
    },
    {
      "given": "D. F.",
      "family": "Hornig",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Metcalf Chemical Laboratories, Brown University, Providence, Rhode Island"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020814315646100_r1",
      "doi-asserted-by": "crossref",
      "first-page": "983",
      "DOI": "10.1063/1.1747823",
      "volume": "18",
      "year": "1950",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r2",
      "doi-asserted-by": "crossref",
      "first-page": "157",
      "DOI": "10.1063/1.1746461",
      "volume": "15",
      "year": "1947",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r3",
      "doi-asserted-by": "crossref",
      "first-page": "1316",
      "DOI": "10.1063/1.1747469",
      "volume": "18",
      "year": "1950",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r4",
      "doi-asserted-by": "crossref",
      "first-page": "881",
      "DOI": "10.1063/1.1748401",
      "volume": "19",
      "year": "1951",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r5",
      "doi-asserted-by": "crossref",
      "first-page": "868",
      "DOI": "10.1063/1.1746366",
      "volume": "15",
      "year": "1947",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r6",
      "doi-asserted-by": "crossref",
      "first-page": "710",
      "DOI": "10.1103/PhysRev.57.710",
      "volume": "57",
      "year": "1940",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020814315646100_r7",
      "doi-asserted-by": "crossref",
      "first-page": "628",
      "DOI": "10.1103/PhysRev.69.628",
      "volume": "69",
      "year": "1946",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020814315646100_r8",
      "doi-asserted-by": "crossref",
      "first-page": "578",
      "DOI": "10.1063/1.1724067",
      "volume": "14",
      "year": "1946",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r9",
      "doi-asserted-by": "crossref",
      "first-page": "497",
      "DOI": "10.1364/JOSA.40.000497",
      "volume": "40",
      "year": "1950",
      "journal-title": "J. Opt. Soc. Am."
    },
    {
      "key": "2024020814315646100_r10",
      "first-page": "1213",
      "volume": "19",
      "year": "1951",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r11",
      "doi-asserted-by": "crossref",
      "first-page": "1697",
      "DOI": "10.1021/ja01323a015",
      "volume": "56",
      "year": "1934",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020814315646100_r12",
      "doi-asserted-by": "crossref",
      "first-page": "2626",
      "DOI": "10.1021/ja01265a017",
      "volume": "61",
      "year": "1939",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020814315646100_r13",
      "doi-asserted-by": "crossref",
      "first-page": "1163",
      "DOI": "10.1063/1.1747132",
      "volume": "17",
      "year": "1949",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r14",
      "doi-asserted-by": "crossref",
      "first-page": "777",
      "DOI": "10.1103/PhysRev.42.777",
      "volume": "42",
      "year": "1932",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020814315646100_r15",
      "first-page": "858",
      "volume": "194",
      "year": "1932",
      "journal-title": "Compt. Rend."
    },
    {
      "key": "2024020814315646100_r16",
      "doi-asserted-by": "crossref",
      "first-page": "1022",
      "DOI": "10.1063/1.1747107",
      "volume": "17",
      "year": "1949",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r17",
      "doi-asserted-by": "crossref",
      "first-page": "193",
      "DOI": "10.1063/1.1748158",
      "volume": "19",
      "year": "1951",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814315646100_r18",
      "doi-asserted-by": "crossref",
      "first-page": "433",
      "DOI": "10.1039/TF9423800433",
      "volume": "38",
      "year": "1942",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020814315646100_r19",
      "doi-asserted-by": "crossref",
      "first-page": "1209",
      "DOI": "10.1039/tf9383401209",
      "volume": "34",
      "year": "1938",
      "journal-title": "Trans. Faraday Soc."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/20/4/647/18800853/647_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/20/4/647/18800853/647_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T14:32:17Z",
    "timestamp": 1707402737000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/20/4/647/73630/The-Measurement-of-Bond-Moments-and-Derivatives-in"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1952,
        4,
        1
      ]
    ]
  },
  "references-count": 19,
  "journal-issue": {
    "issue": "4",
    "published-print": {
      "date-parts": [
        [
          1952,
          4,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1700508",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1952,
        4
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1952,
        4,
        1
      ]
    ]
  }
}