DOI: 10.1063/1.1699158. The Vibrational Spectra of Pyridine and Pyridine-<i>d</i>5

The Vibrational Spectra of Pyridine and Pyridine-d5

10.1063/1.1699158

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Pyridine-d5 has been prepared by exchange between pyridine vapor and heavy water in the presence of a palladium catalyst. Infrared and Raman spectra are reported for pyridine and pyridine-d5 over the spectral range 300–4000 cm−1. Interpretation of the spectra with the help of the product rule and by analogy with the fundamental frequencies of benzene and benzene-d6 leads to complete sets of frequencies for the 27 vibrational degrees of freedom of pyridine and of pyridine-d5. The frequency assignment for pyridine does not differ greatly from previous ones, but is believed to be more reliable because of the additional spectroscopic data.

Bibliography

Corrsin, L., Fax, B. J., & Lord, R. C. (1953). The Vibrational Spectra of Pyridine and Pyridine-d5. The Journal of Chemical Physics, 21(7), 1170â1176.

Authors 3

Lester Corrsin (first)
B. J. Fax (additional)
R. C. Lord (additional)

References 20 Referenced 259

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{'key': '2024020815052617700_r2'}
10.1063/1.1724133 / J. Chem. Phys. (1946)
{'key': '2024020815052617700_r4'}
{'key': '2024020815052617700_r5'}
10.1063/1.1747954 / J. Chem. Phys. (1951)
{'key': '2024020815052617700_r6', 'first-page': '124', 'volume': 'B53', 'year': '1943', 'journal-title': 'Z. Physik. Chem.'} / Z. Physik. Chem. (1943)
10.1364/JOSA.42.000149 / J. Opt. Soc. Am. (1952)
10.1063/1.1723943 / J. Chem. Phys. (1944)
10.1063/1.1723850 / J. Chem. Phys. (1943)
10.1039/df9500900026 / Disc. Faraday Soc. (1950)
{'key': '2024020815052617700_r11'}
10.1103/PhysRev.45.706 / Phys. Rev. (1934)
{'key': '2024020815052617700_r13'}
10.1103/RevModPhys.19.87 / Revs. Modern Phys. (1947)
10.1021/ja01876a038 / J. Am. Chem. Soc. (1939)
{'key': '2024020815052617700_r16'}
{'key': '2024020815052617700_r17'}
10.1063/1.1747149 / J. Chem. Phys. (1949)
{'key': '2024020815052617700_r19'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 7:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 10:23 a.m.)
Indexed	3 months ago (May 27, 2025, 3:47 a.m.)
Issued	72 years, 2 months ago (July 1, 1953)
Published	72 years, 2 months ago (July 1, 1953)
Published Print	72 years, 2 months ago (July 1, 1953)

Funders 0

None

BibTeX

@article{Corrsin_1953, title={The Vibrational Spectra of Pyridine and Pyridine-d5}, volume={21}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1699158}, DOI={10.1063/1.1699158}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Corrsin, Lester and Fax, B. J. and Lord, R. C.}, year={1953}, month=jul, pages={1170–1176} }

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