DOI: 10.1063/1.1699045. The Molecular Structure, Dipole Moment, and <i>g</i> Factor of Ozone from Its Microwave Spectrum

The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum

10.1063/1.1699045

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Four low-J rotational transitions of 0316 have been measured in the region from 42 to 118 kmc. The rotational spectroscopic constants found are A = 106,530.0±1.1 Mc, B = 13,349.06±0.06 Mc, C = 11,834.3±1.1 Mc. The oxygen nuclei form an isosceles triangle with an apex angle of 116°49′±30′, and the two equal internuclear distances are 1.278±0.003A. From the Stark splitting of the 20,2→11,1 transition the dipole moment is 0.53±0.02 debye. Zeeman splittings of this transition show that ozone is not significantly paramagnetic.

Authors 4

R. Trambarulo (first)
S. N. Ghosh (additional)
C. A. Burrus (additional)
W. Gordy (additional)

References 19 Referenced 114

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{'key': '2024020814575444900_r6', 'first-page': '741', 'volume': '16', 'year': '1948', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1948)
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 7:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:58 a.m.)
Indexed	3 months, 2 weeks ago (May 11, 2025, 8:25 p.m.)
Issued	72 years, 3 months ago (May 1, 1953)
Published	72 years, 3 months ago (May 1, 1953)
Published Print	72 years, 3 months ago (May 1, 1953)

Funders 0

None

BibTeX

@article{Trambarulo_1953, title={The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum}, volume={21}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1699045}, DOI={10.1063/1.1699045}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Trambarulo, R. and Ghosh, S. N. and Burrus, C. A. and Gordy, W.}, year={1953}, month=may, pages={851–855} }

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