Abstract
The quantum mechanics of collisions between diatomic molecules is discussed. Explicit expressions for the angular transition probabilities are obtained. These expressions are in terms of a set of coefficients which are defined by the asymptotic form of the solutions of a set of coupled differential equations in one variable, the separation of the molecules. The coupled differential equations involve integrals of the intermolecular potential function, which may be of any form. A solution of the coupled differential equations by a perturbation method, which is valid in the case of low-energy collisions, in which transitions occur rarely, is discussed.
References
4
Referenced
20
10.1063/1.1700387
/ J. Chem. Phys. (1952)10.1063/1.1699164
/ J. Chem. Phys. (1953)10.1143/ptp/8.5.497
/ Progr. Theoret. Phys. (Japan) (1952){'key': '2024020815203511000_r4'}
Dates
Type | When |
---|---|
Created | 20 years, 7 months ago (Jan. 5, 2005, 7:34 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 11:39 a.m.) |
Indexed | 1 year, 6 months ago (Feb. 9, 2024, 3:03 p.m.) |
Issued | 71 years, 9 months ago (Nov. 1, 1953) |
Published | 71 years, 9 months ago (Nov. 1, 1953) |
Published Print | 71 years, 9 months ago (Nov. 1, 1953) |
@article{Curtiss_1953, title={The Quantum Mechanics of Collisions between Diatomic Molecules}, volume={21}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1698740}, DOI={10.1063/1.1698740}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Curtiss, C. F.}, year={1953}, month=nov, pages={2045–2050} }