DOI: 10.1063/1.1697251. Solution Dimerization of the Tetracyanoquinodimethane Ion Radical

Solution Dimerization of the Tetracyanoquinodimethane Ion Radical

10.1063/1.1697251

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The reversible dimerization of the anion radical of 7,7,8,8-tetracyanoquinodimethane in aqueous solution has been studied spectroscopically. Analysis of the spectra yields an equilibrium constant for dimerization (2A−⇆A2=) at 25° of 2.5×103 liter/mole and a heat of dimerization of −10.4 kcal/mole dimer.

Bibliography

Boyd, R. H., & Phillips, W. D. (1965). Solution Dimerization of the Tetracyanoquinodimethane Ion Radical. The Journal of Chemical Physics, 43(9), 2927â2929.

Authors 2

Richard H. Boyd (first)
William D. Phillips (additional)

References 9 Referenced 188

{'key': '2024020900054967800_r1', 'first-page': '30', 'volume': '64', 'year': '1964', 'journal-title': 'Chem. Rev.'} / Chem. Rev. (1964)
10.1039/TF9625802168 / Trans. Faraday Soc. (1962)
10.1039/tf9625801809 / Trans. Faraday Soc. (1962)
10.1063/1.1733536 / J. Chem. Phys. (1963)
10.1021/ja01509a052 / J. Am. Chem. Soc. (1960)
10.1021/j100827a035 / J. Phys. Chem. (1961)
10.1021/ja01857a043 / J. Am. Chem. Soc. (1941)
10.1063/1.1701011 / J. Chem. Phys. (1961)
10.1063/1.1701103 / J. Chem. Phys. (1961)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 3:01 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:05 p.m.)
Indexed	3 months, 3 weeks ago (May 8, 2025, 3:47 a.m.)
Issued	59 years, 10 months ago (Nov. 1, 1965)
Published	59 years, 10 months ago (Nov. 1, 1965)
Published Print	59 years, 10 months ago (Nov. 1, 1965)

Funders 0

None

BibTeX

@article{Boyd_1965, title={Solution Dimerization of the Tetracyanoquinodimethane Ion Radical}, volume={43}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1697251}, DOI={10.1063/1.1697251}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Boyd, Richard H. and Phillips, William D.}, year={1965}, month=nov, pages={2927–2929} }

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