DOI: 10.1063/1.1697136. Effect of Pressure on the Dielectric Properties of Ice I

Effect of Pressure on the Dielectric Properties of Ice I

10.1063/1.1697136

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The effect of pressure up to about 2 kbar on the dielectric properties of Ice I at − 23.4° has been measured. The static dielectric constant increases with increasing pressure by about the amount predicted by the Kirkwood theory. The increase in relaxation time yields a volume of activation for the relaxation process of 2.9±0.2 cm3 mole−1 which supports current views that dielectric relaxation occurs by rotation at orientational defects. The volume of activation given by the rapid rise of dc conductivity with increasing pressure is − 11±∼3 cm3 mole−1 which is consistent with the proton-transfer mechanism.

Bibliography

Chan, R. K., Davidson, D. W., & Whalley, E. (1965). Effect of Pressure on the Dielectric Properties of Ice I. The Journal of Chemical Physics, 43(7), 2376â2383.

Authors 3

R. K. Chan (first)
D. W. Davidson (additional)
E. Whalley (additional)

References 44 Referenced 74

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{'key': '2024020900193570800_r2a'}
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 3:01 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:19 p.m.)
Indexed	3 weeks, 2 days ago (Aug. 7, 2025, 4:54 a.m.)
Issued	59 years, 10 months ago (Oct. 1, 1965)
Published	59 years, 10 months ago (Oct. 1, 1965)
Published Print	59 years, 10 months ago (Oct. 1, 1965)

Funders 0

None

BibTeX

@article{Chan_1965, title={Effect of Pressure on the Dielectric Properties of Ice I}, volume={43}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1697136}, DOI={10.1063/1.1697136}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Chan, R. K. and Davidson, D. W. and Whalley, E.}, year={1965}, month=oct, pages={2376–2383} }

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