DOI: 10.1063/1.1696798. Mass-Spectrometric Study of Gaseous Oxides and Suboxides of Scandium, Yttrium, and Lanthanum

Mass-Spectrometric Study of Gaseous Oxides and Suboxides of Scandium, Yttrium, and Lanthanum

10.1063/1.1696798

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The dissociation energy of the molecule ScO was determined: D0°(ScO) = 160.9±3.5 kcal/mole. The dissociation energies of the molecules YO and LaO, D0°(YO) = 168.6±2.8 and D0°(LaO) = 191.0±2.5 kcal/mole, are discussed. The molecules Sc2O, Y2O, Y2O2, La2O, and La2O2 were identified. Their atomization energies are: D0°(Sc2O) = 245±11, D0°(Y2O) = 258±8, D0°(Y2O2) = 445±12, D0°(La2O) = 266±8, D0°(La2O2) = 468±11 kcal/mole.

Bibliography

Smoes, S., Drowart, J., & Verhaegen, G. (1965). Mass-Spectrometric Study of Gaseous Oxides and Suboxides of Scandium, Yttrium, and Lanthanum. The Journal of Chemical Physics, 43(2), 732â736.

Authors 3

S. Smoes (first)
J. Drowart (additional)
G. Verhaegen (additional)

References 33 Referenced 32

10.1063/1.1724876 / J. Chem. Phys. (1964)
{'key': '2024020900042755800_r2'}
10.1063/1.1742611 / J. Chem. Phys. (1956)
10.1021/j100826a029 / J. Phys. Chem. (1961)
{'key': '2024020900042755800_r5'}
10.1063/1.1725221 / J. Chem. Phys. (1964)
10.1021/j150553a032 / J. Phys. Chem. (1957)
10.1051/jcp/1958550721 / J. Chim. Phys. (1958)
{'key': '2024020900042755800_r9', 'first-page': '1781', 'volume': '33', 'year': '1960', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1960)
{'key': '2024020900042755800_r10'}
{'key': '2024020900042755800_r11'}
{'key': '2024020900042755800_r12', 'volume': '18', 'year': '1956', 'journal-title': 'Advan. Chem. Ser.'} / Advan. Chem. Ser. (1956)
{'key': '2024020900042755800_r13', 'first-page': '41', 'volume': '22', 'year': '1962', 'journal-title': 'Arkiv Fysik'} / Arkiv Fysik (1962)
{'key': '2024020900042755800_r14', 'first-page': '1', 'volume': '19', 'year': '1961', 'journal-title': 'Arkiv Fysik'} / Arkiv Fysik (1961)
{'key': '2024020900042755800_r15'}
{'key': '2024020900042755800_r16'}
10.1063/1.1725905 / J. Chem. Phys. (1964)
10.1063/1.1731952 / J. Chem. Phys. (1961)
{'key': '2024020900042755800_r19'}
10.1021/j150550a027 / J. Phys. Chem. (1957)
10.1021/j150579a028 / J. Phys. Chem. (1959)
{'key': '2024020900042755800_r22'}
10.1063/1.1732529 / J. Chem. Phys. (1962)
10.1063/1.1726358 / J. Chem. Phys. (1964)
{'key': '2024020900042755800_r25', 'first-page': '214', 'volume': '9', 'year': '1964', 'journal-title': 'Ukr. Fiz. Zh.'} / Ukr. Fiz. Zh. (1964)
10.1063/1.1731516 / J. Chem. Phys. (1960)
{'key': '2024020900042755800_r27'}
{'key': '2024020900042755800_r28', 'first-page': '3594', 'volume': '75', 'year': '1963', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1963)
{'key': '2024020900042755800_r29'}
{'key': '2024020900042755800_r30'}
{'key': '2024020900042755800_r31', 'first-page': '1920', 'volume': '10', 'year': '1964', 'journal-title': 'Trans. Faraday Soc.'} / Trans. Faraday Soc. (1964)
10.1016/0032-0633(61)90219-7 / Planetary Space Sci. (1961)
10.1063/1.1730923 / J. Chem. Phys. (1960)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 3:01 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:04 p.m.)
Indexed	1 month, 4 weeks ago (July 3, 2025, 12:03 p.m.)
Issued	60 years, 1 month ago (July 15, 1965)
Published	60 years, 1 month ago (July 15, 1965)
Published Print	60 years, 1 month ago (July 15, 1965)

Funders 0

None

BibTeX

@article{Smoes_1965, title={Mass-Spectrometric Study of Gaseous Oxides and Suboxides of Scandium, Yttrium, and Lanthanum}, volume={43}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1696798}, DOI={10.1063/1.1696798}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Smoes, S. and Drowart, J. and Verhaegen, G.}, year={1965}, month=jul, pages={732–736} }

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  "abstract": "<jats:p>The dissociation energy of the molecule ScO was determined: D0\u00b0(ScO) = 160.9\u00b13.5 kcal/mole. The dissociation energies of the molecules YO and LaO, D0\u00b0(YO) = 168.6\u00b12.8 and D0\u00b0(LaO) = 191.0\u00b12.5 kcal/mole, are discussed. The molecules Sc2O, Y2O, Y2O2, La2O, and La2O2 were identified. Their atomization energies are: D0\u00b0(Sc2O) = 245\u00b111, D0\u00b0(Y2O) = 258\u00b18, D0\u00b0(Y2O2) = 445\u00b112, D0\u00b0(La2O) = 266\u00b18, D0\u00b0(La2O2) = 468\u00b111 kcal/mole.</jats:p>",
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