DOI: 10.1063/1.1696615. Light Scattering of Water, Deuterium Oxide, and Other Pure Liquids

Light Scattering of Water, Deuterium Oxide, and Other Pure Liquids

10.1063/1.1696615

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The Rayleigh ratio and the Cabannes factor for water, deuterium oxide, and a number of other pure liquids were determined at 25°C, at angles of observation ranging from 30° to 150°, at 546 and 436 mμ. It was found that the Rayleigh ratio of water is substantially lower than the values reported in the literature; the values found by us Ru546(90)=0.865 10−6 cm−1, Ru436(90)=2.32 10−6 cm−1 for H2O, and Ru436(90)=0.843×10−6 cm−1, Ru436(90)=2.30 10−6 cm−1 for D2O are in excellent agreement with the predictions of the Einstein density-fluctuation theory, modified by the Cabannes anisotropy factor. The temperature dependence of the Rayleigh ratios for H2O and D2O is also satisfactorily predicted by the variation of the bulk parameters appearing in the Einstein—Cabannes equations. In contradistinction to such liquids as benzene, the Rayleigh ratios of H2O and D2O have a minimum, at about 22° and 28°C, respectively. No significant new information on the structure of water as a function of temperature can be derived from light-scattering experiments.

Bibliography

Cohen, G., & Eisenberg, H. (1965). Light Scattering of Water, Deuterium Oxide, and Other Pure Liquids. The Journal of Chemical Physics, 43(11), 3881â3887.

Authors 2

Gerald Cohen (first)
Henryk Eisenberg (additional)

References 24 Referenced 54

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{'key': '2024020900284216500_r9'}
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{'key': '2024020900284216500_r14'}
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 3:01 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:28 p.m.)
Indexed	1 year, 2 months ago (June 14, 2024, 7:46 p.m.)
Issued	59 years, 8 months ago (Dec. 1, 1965)
Published	59 years, 8 months ago (Dec. 1, 1965)
Published Print	59 years, 8 months ago (Dec. 1, 1965)

Funders 0

None

BibTeX

@article{Cohen_1965, title={Light Scattering of Water, Deuterium Oxide, and Other Pure Liquids}, volume={43}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1696615}, DOI={10.1063/1.1696615}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Cohen, Gerald and Eisenberg, Henryk}, year={1965}, month=dec, pages={3881–3887} }

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