DOI: 10.1063/1.1696403. On the Calculation of Potential Curves by the Rydberg—Klein—Rees Method. I. Experimental Limitations, Extrapolation Procedures, and Applications to the Third-Group Hydrides

On the Calculation of Potential Curves by the Rydberg—Klein—Rees Method. I. Experimental Limitations, Extrapolation Procedures, and Applications to the Third-Group Hydrides

10.1063/1.1696403

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Uncertainties in potential curves determined by the Rydberg—Klein—Rees (RKR) method which result from approximations inherent in current applications of the method and from experimental errors are discussed. The use of the RKR method to extrapolate potential curves beyond the region known spectroscopically is discussed, with calculations on the X 1Σg+ state of H2 presented as examples. Application is made to the X 1Σ+ and a 3II states of GaH, InH, and TlH, with particular emphasis on the correlation of states from the lower MO configurations with the states of the separated atoms.

Bibliography

Ginter, M. L., & Battino, R. (1965). On the Calculation of Potential Curves by the RydbergâKleinâRees Method. I. Experimental Limitations, Extrapolation Procedures, and Applications to the Third-Group Hydrides. The Journal of Chemical Physics, 42(9), 3222â3229.

Authors 2

Marshall L. Ginter (first)
Rubin Battino (additional)

References 38 Referenced 42

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 10, 2005, 10:16 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:48 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 10:05 p.m.)
Issued	60 years, 4 months ago (May 1, 1965)
Published	60 years, 4 months ago (May 1, 1965)
Published Print	60 years, 4 months ago (May 1, 1965)

Funders 0

None

BibTeX

@article{Ginter_1965, title={On the Calculation of Potential Curves by the Rydberg—Klein—Rees Method. I. Experimental Limitations, Extrapolation Procedures, and Applications to the Third-Group Hydrides}, volume={42}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1696403}, DOI={10.1063/1.1696403}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ginter, Marshall L. and Battino, Rubin}, year={1965}, month=may, pages={3222–3229} }

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