DOI: 10.1063/1.1696187. Group Moment Interpretation of the Infrared Intensities of Crystalline <i>n</i>-Paraffins

Group Moment Interpretation of the Infrared Intensities of Crystalline n-Paraffins

10.1063/1.1696187

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The infrared intensities of bands in the spectra (3000–700 cm−1) of the crystalline n-paraffins n-C4H10 through n-C8H18 have been measured and interpreted using a group moment model. In this model intensities are expressed in terms of dipole moment derivatives with respect to group coordinates, i.e., coordinates describing the motions of CH3 and CH2 groups. In spite of a severe limitation in the accuracy of the measured intensities caused by preferred orientation in the polycrystalline films, a good correlation between calculated and observed intensities has been obtained.

Bibliography

Snyder, R. G. (1965). Group Moment Interpretation of the Infrared Intensities of Crystalline n-Paraffins. The Journal of Chemical Physics, 42(5), 1744â1763.

Authors 1

R. G. Snyder (first)

References 23 Referenced 95

10.1016/0371-1951(63)80096-X / Spectrochim. Acta (1963)
10.1016/0371-1951(65)80115-1 / Spectrochim. Acta (1965)
10.1021/j150533a004 / J. Phys. Chem. (1955)
{'key': '2024020823395072700_r4'}
{'key': '2024020823395072700_r5'}
{'key': '2024020823395072700_r6'}
10.1016/0022-2852(62)90024-3 / J. Mol. Spectry. (1962)
10.1103/PhysRev.47.552 / Phys. Rev. (1935)
10.1063/1.1731434 / J. Chem. Phys. (1960)
10.1063/1.1731636 / J. Chem. Phys. (1961)
10.3891/acta.chem.scand.15-1747 / Acta Chem. Scand. (1961)
10.3891/acta.chem.scand.15-1747 / Acta Chem. Scand. (1961)
{'key': '2024020823395072700_r11b'}
10.1364/JOSA.50.000036 / J. Opt. Soc. Am. (1960)
10.1063/1.1733278 / J. Chem. Phys. (1962)
10.1021/ja01121a018 / J. Am. Chem. Soc. (1952)
10.1016/0371-1951(63)80095-8 / Spectrochim. Acta (1963)
10.1016/0022-2852(62)90039-5 / J. Mol. Spectry. (1962)
{'key': '2024020823395072700_r17'}
{'key': '2024020823395072700_r18'}
10.1016/0022-2852(60)90112-0 / J. Mol. Spectry. (1960)
{'key': '2024020823395072700_r20', 'first-page': '402', 'volume': '53', 'year': '1957', 'journal-title': 'Trans. Faraday Soc.'} / Trans. Faraday Soc. (1957)
{'key': '2024020823395072700_r21'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 10, 2005, 10:16 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:40 p.m.)
Indexed	1 year, 4 months ago (April 5, 2024, 6:16 p.m.)
Issued	60 years, 5 months ago (March 1, 1965)
Published	60 years, 5 months ago (March 1, 1965)
Published Print	60 years, 5 months ago (March 1, 1965)

Funders 0

None

BibTeX

@article{Snyder_1965, title={Group Moment Interpretation of the Infrared Intensities of Crystalline n-Paraffins}, volume={42}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1696187}, DOI={10.1063/1.1696187}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Snyder, R. G.}, year={1965}, month=mar, pages={1744–1763} }

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