DOI: 10.1063/1.1696159. Radio-Frequency and Microwave Spectra of 6Li127I by the Molecular-Beam Electric-Resonance Method

Radio-Frequency and Microwave Spectra of 6Li127I by the Molecular-Beam Electric-Resonance Method

10.1063/1.1696159

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The radio-frequency and microwave spectra of 6Li127I have been observed by the molecular-beam electric-resonance method of molecular spectroscopy. Spectra of 6Li127I in the first two vibrational states were obtained. From the J=1 radio frequency, Stark spectra values were obtained for the electric dipole moment μ, the iodine nuclear quadrupole interaction eqQI, and the iodine spin-rotation constant cI. The values of these constants are v=0v=1μ (debye)7.4285±0.0017.5120±0.001eqQI (Mc/sec)−198.780 ±0.005−207.453 ±0.010cI (kc/sec)7.7 ±0.47.8 ±0.6. The observation of J=1→J=0 microwave transitions yielded the following rotational constants: B0=15 304.895±0.005 Mc/sec,B1=15 153.316±0.009 Mc/sec.

Bibliography

Breivogel, F. W., Hebert, A. J., & Street, K. (1965). Radio-Frequency and Microwave Spectra of 6Li127I by the Molecular-Beam Electric-Resonance Method. The Journal of Chemical Physics, 42(5), 1555â1558.

Authors 3

F. W. Breivogel (first)
A. J. Hebert (additional)
K. Street (additional)

References 10 Referenced 21

{'key': '2024020823263050200_r1'}
{'key': '2024020823263050200_r2'}
10.1103/PhysRev.96.629 / Phys. Rev. (1954)
10.1103/PhysRev.127.817 / Phys. Rev. (1962)
10.1103/PhysRev.41.721 / Phys. Rev. (1932)
{'key': '2024020823263050200_r6'}
10.1063/1.1726273 / J. Chem. Phys. (1964)
10.1063/1.1725764 / J. Chem. Phys. (1964)
{'key': '2024020823263050200_r9'}
{'key': '2024020823263050200_r10'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 10, 2005, 10:16 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:26 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 11:49 a.m.)
Issued	60 years, 5 months ago (March 1, 1965)
Published	60 years, 5 months ago (March 1, 1965)
Published Print	60 years, 5 months ago (March 1, 1965)

Funders 0

None

BibTeX

@article{Breivogel_1965, title={Radio-Frequency and Microwave Spectra of 6Li127I by the Molecular-Beam Electric-Resonance Method}, volume={42}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1696159}, DOI={10.1063/1.1696159}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Breivogel, F. W. and Hebert, A. J. and Street, K.}, year={1965}, month=mar, pages={1555–1558} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T16:49:43Z",
    "timestamp": 1707583783119
  },
  "reference-count": 10,
  "publisher": "AIP Publishing",
  "issue": "5",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1965,
        3,
        1
      ]
    ]
  },
  "abstract": "<jats:p>The radio-frequency and microwave spectra of 6Li127I have been observed by the molecular-beam electric-resonance method of molecular spectroscopy. Spectra of 6Li127I in the first two vibrational states were obtained. From the J=1 radio frequency, Stark spectra values were obtained for the electric dipole moment \u03bc, the iodine nuclear quadrupole interaction eqQI, and the iodine spin-rotation constant cI. The values of these constants are v=0v=1\u03bc\u2009(debye)7.4285\u00b10.0017.5120\u00b10.001eqQI\u2009(Mc/sec)\u2212198.780\u2009\u00b10.005\u2212207.453\u2009\u00b10.010cI\u2009(kc/sec)7.7\u2009\u2009\u00b10.47.8\u2009\u2009\u00b10.6.</jats:p>\n               <jats:p>The observation of J=1\u2192J=0 microwave transitions yielded the following rotational constants: B0=15 304.895\u00b10.005\u2009Mc/sec,B1=15 153.316\u00b10.009\u2009Mc/sec.</jats:p>",
  "DOI": "10.1063/1.1696159",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        10
      ]
    ],
    "date-time": "2005-01-10T15:16:30Z",
    "timestamp": 1105370190000
  },
  "page": "1555-1558",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 21,
  "title": "Radio-Frequency and Microwave Spectra of 6Li127I by the Molecular-Beam Electric-Resonance Method",
  "prefix": "10.1063",
  "volume": "42",
  "author": [
    {
      "suffix": "Jr.",
      "given": "F. W.",
      "family": "Breivogel",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry and Lawrence Radiation Laboratory, University of California, Berkeley, California"
        }
      ]
    },
    {
      "given": "A. J.",
      "family": "Hebert",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry and Lawrence Radiation Laboratory, University of California, Berkeley, California"
        }
      ]
    },
    {
      "suffix": "Jr.",
      "given": "K.",
      "family": "Street",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry and Lawrence Radiation Laboratory, University of California, Berkeley, California"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020823263050200_r1"
    },
    {
      "key": "2024020823263050200_r2"
    },
    {
      "key": "2024020823263050200_r3",
      "doi-asserted-by": "crossref",
      "first-page": "629",
      "DOI": "10.1103/PhysRev.96.629",
      "volume": "96",
      "year": "1954",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020823263050200_r4",
      "doi-asserted-by": "crossref",
      "first-page": "817",
      "DOI": "10.1103/PhysRev.127.817",
      "volume": "127",
      "year": "1962",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020823263050200_r5",
      "doi-asserted-by": "crossref",
      "first-page": "721",
      "DOI": "10.1103/PhysRev.41.721",
      "volume": "41",
      "year": "1932",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020823263050200_r6"
    },
    {
      "key": "2024020823263050200_r7",
      "doi-asserted-by": "crossref",
      "first-page": "2368",
      "DOI": "10.1063/1.1726273",
      "volume": "41",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823263050200_r8",
      "doi-asserted-by": "crossref",
      "first-page": "3540",
      "DOI": "10.1063/1.1725764",
      "volume": "41",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020823263050200_r9"
    },
    {
      "key": "2024020823263050200_r10"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/42/5/1555/18836815/1555_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/42/5/1555/18836815/1555_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T23:26:42Z",
    "timestamp": 1707434802000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/42/5/1555/78305/Radio-Frequency-and-Microwave-Spectra-of-6Li127I"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1965,
        3,
        1
      ]
    ]
  },
  "references-count": 10,
  "journal-issue": {
    "issue": "5",
    "published-print": {
      "date-parts": [
        [
          1965,
          3,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1696159",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1965,
        3,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1965,
        3,
        1
      ]
    ]
  }
}