DOI: 10.1063/1.1680972. Adsorption of CO on a Ni(111) surface

10.1063/1.1680972

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Carbon monoxide adsorbed on Ni(111) forms around θ = 1/3 an ordered √3 × √3/R 30c structure whose unit cell is continuously compressed upon further increasing the coverage until at saturation (θ=0.53 corresponding to 1 × 1015 molecules/cm2) a densely packed layer is reached. The work function increases by 1.31 eV. At θ=1/3 the adsorption energy decreases from its value of 26.5 kcal/mole by 3 kcal/mole. CO adsorption causes the appearance of two peaks at 6 and 14 eV in the electron energy loss spectra, which are ascribed to excitations of electrons from chemisorption levels. The sticking coefficient remains nearly constant up to medium coverages which can be described by a ``precursor'' state model. The results show close similarities with those reported for other nickel surfaces.

Bibliography

Christmann, K., Schober, O., & Ertl, G. (1974). Adsorption of CO on a Ni(111) surface. The Journal of Chemical Physics, 60(12), 4719â4724.

Authors 3

K. Christmann (first)
O. Schober (additional)
G. Ertl (additional)

References 28 Referenced 327

10.1063/1.1677602 / J. Chem. Phys. (1972)
10.1063/1.1673028 / J. Chem. Phys. (1970)
10.1116/1.1317970 / J. Vac. Sci. Technol. (1973)
10.1063/1.1679668 / J. Chem. Phys. (1973)
{'key': '2024020911432567100_r5'}
10.1080/14786436008235838 / Phil. Mag. (1960)
10.1016/0039-6028(69)90071-5 / Surface Sci. (1969)
10.1016/0039-6028(73)90215-X / Surface Sci. (1973)
10.1016/0039-6028(73)90051-4 / Surface Sci. (1973)
{'key': '2024020911432567100_r10', 'volume': '43', 'year': '1974', 'journal-title': 'Surface Sci.'} / Surface Sci. (1974)
{'key': '2024020911432567100_r11', 'first-page': '1906', 'volume': '252', 'year': '1970', 'journal-title': 'Z. Naturforsch.'} / Z. Naturforsch. (1970)
{'key': '2024020911432567100_r11a'}
{'key': '2024020911432567100_r12'}
10.1515/zna-1972-0306 / Z. Naturforsch. A (1972)
10.1016/0039-6028(73)90246-X / Surface Sci. (1973)
10.1063/1.1671876 / J. Chem. Phys. (1969)
10.1016/S0360-0564(08)60341-7 / Adv. Catal. Relat. Subj. (1963)
10.1016/0039-6028(74)90228-3 / Surface Sci. (1974)
{'key': '2024020911432567100_r18', 'first-page': '737', 'volume': '58', 'year': '1946', 'journal-title': 'Proc. R. Soc. A'} / Proc. R. Soc. A (1946)
10.1063/1.1740200 / J. Chem. Phys. (1954)
10.1063/1.1677603 / J. Chem. Phys. (1972)
10.1021/j100792a006 / J. Phys. Chem. (1964)
10.1103/PhysRevLett.27.1520 / Phys. Rev. Lett. (1971)
{'key': '2024020911432567100_r22'}
10.1016/0022-3697(57)90054-9 / J. Phys. Chem. Solids (1957)
10.1016/0022-3697(58)90132-X / J. Phys. Chem. Solids (1958)
10.1016/0039-6028(72)90232-4 / Surface Sci. (1972)
{'key': '2024020911432567100_r25'}

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 4:10 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 7:37 a.m.)
Indexed	2 weeks, 2 days ago (Aug. 20, 2025, 9:09 a.m.)
Issued	51 years, 2 months ago (June 15, 1974)
Published	51 years, 2 months ago (June 15, 1974)
Published Print	51 years, 2 months ago (June 15, 1974)

Funders 0

None

BibTeX

@article{Christmann_1974, title={Adsorption of CO on a Ni(111) surface}, volume={60}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1680972}, DOI={10.1063/1.1680972}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Christmann, K. and Schober, O. and Ertl, G.}, year={1974}, month=jun, pages={4719–4724} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        20
      ]
    ],
    "date-time": "2025-08-20T13:09:23Z",
    "timestamp": 1755695363949
  },
  "reference-count": 28,
  "publisher": "AIP Publishing",
  "issue": "12",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1974,
        6,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Carbon monoxide adsorbed on Ni(111) forms around \u03b8 = 1/3 an ordered \u221a3 \u00d7 \u221a3/R 30c structure whose unit cell is continuously compressed upon further increasing the coverage until at saturation (\u03b8=0.53 corresponding to 1 \u00d7 1015 molecules/cm2) a densely packed layer is reached. The work function increases by 1.31 eV. At \u03b8=1/3 the adsorption energy decreases from its value of 26.5 kcal/mole by 3 kcal/mole. CO adsorption causes the appearance of two peaks at 6 and 14 eV in the electron energy loss spectra, which are ascribed to excitations of electrons from chemisorption levels. The sticking coefficient remains nearly constant up to medium coverages which can be described by a ``precursor'' state model. The results show close similarities with those reported for other nickel surfaces.</jats:p>",
  "DOI": "10.1063/1.1680972",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        2,
        6
      ]
    ],
    "date-time": "2004-02-06T21:10:00Z",
    "timestamp": 1076101800000
  },
  "page": "4719-4724",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 327,
  "title": "Adsorption of CO on a Ni(111) surface",
  "prefix": "10.1063",
  "volume": "60",
  "author": [
    {
      "given": "K.",
      "family": "Christmann",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Physikalisch-Chemisches Institut der Universit\u00e4t, Munich, Germany"
        }
      ]
    },
    {
      "given": "O.",
      "family": "Schober",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Physikalisch-Chemisches Institut der Universit\u00e4t, Munich, Germany"
        }
      ]
    },
    {
      "given": "G.",
      "family": "Ertl",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Physikalisch-Chemisches Institut der Universit\u00e4t, Munich, Germany"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020911432567100_r1",
      "doi-asserted-by": "crossref",
      "first-page": "2736",
      "DOI": "10.1063/1.1677602",
      "volume": "56",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020911432567100_r2",
      "doi-asserted-by": "crossref",
      "first-page": "589",
      "DOI": "10.1063/1.1673028",
      "volume": "52",
      "year": "1970",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020911432567100_r3",
      "doi-asserted-by": "crossref",
      "first-page": "26",
      "DOI": "10.1116/1.1317970",
      "volume": "10",
      "year": "1973",
      "journal-title": "J. Vac. Sci. Technol."
    },
    {
      "key": "2024020911432567100_r4",
      "doi-asserted-by": "crossref",
      "first-page": "3401",
      "DOI": "10.1063/1.1679668",
      "volume": "58",
      "year": "1973",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020911432567100_r5"
    },
    {
      "key": "2024020911432567100_r6",
      "doi-asserted-by": "crossref",
      "first-page": "222",
      "DOI": "10.1080/14786436008235838",
      "volume": "5",
      "year": "1960",
      "journal-title": "Phil. Mag."
    },
    {
      "key": "2024020911432567100_r7",
      "doi-asserted-by": "crossref",
      "first-page": "137",
      "DOI": "10.1016/0039-6028(69)90071-5",
      "volume": "15",
      "year": "1969",
      "journal-title": "Surface Sci."
    },
    {
      "key": "2024020911432567100_r8",
      "doi-asserted-by": "crossref",
      "first-page": "211",
      "DOI": "10.1016/0039-6028(73)90215-X",
      "volume": "35",
      "year": "1973",
      "journal-title": "Surface Sci."
    },
    {
      "key": "2024020911432567100_r9",
      "doi-asserted-by": "crossref",
      "first-page": "61",
      "DOI": "10.1016/0039-6028(73)90051-4",
      "volume": "40",
      "year": "1973",
      "journal-title": "Surface Sci."
    },
    {
      "key": "2024020911432567100_r10",
      "volume": "43",
      "year": "1974",
      "journal-title": "Surface Sci."
    },
    {
      "key": "2024020911432567100_r11",
      "first-page": "1906",
      "volume": "252",
      "year": "1970",
      "journal-title": "Z. Naturforsch."
    },
    {
      "key": "2024020911432567100_r11a"
    },
    {
      "key": "2024020911432567100_r12"
    },
    {
      "key": "2024020911432567100_r13",
      "doi-asserted-by": "crossref",
      "first-page": "408",
      "DOI": "10.1515/zna-1972-0306",
      "volume": "27",
      "year": "1972",
      "journal-title": "Z. Naturforsch. A"
    },
    {
      "key": "2024020911432567100_r14",
      "doi-asserted-by": "crossref",
      "first-page": "53",
      "DOI": "10.1016/0039-6028(73)90246-X",
      "volume": "36",
      "year": "1973",
      "journal-title": "Surface Sci."
    },
    {
      "key": "2024020911432567100_r15",
      "doi-asserted-by": "crossref",
      "first-page": "4852",
      "DOI": "10.1063/1.1671876",
      "volume": "51",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020911432567100_r16",
      "doi-asserted-by": "crossref",
      "first-page": "255",
      "DOI": "10.1016/S0360-0564(08)60341-7",
      "volume": "14",
      "year": "1963",
      "journal-title": "Adv. Catal. Relat. Subj."
    },
    {
      "key": "2024020911432567100_r17",
      "doi-asserted-by": "crossref",
      "first-page": "197",
      "DOI": "10.1016/0039-6028(74)90228-3",
      "volume": "43",
      "year": "1974",
      "journal-title": "Surface Sci."
    },
    {
      "key": "2024020911432567100_r18",
      "first-page": "737",
      "volume": "58",
      "year": "1946",
      "journal-title": "Proc. R. Soc. A"
    },
    {
      "key": "2024020911432567100_r18a",
      "doi-asserted-by": "crossref",
      "first-page": "843",
      "DOI": "10.1063/1.1740200",
      "volume": "22",
      "year": "1954",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020911432567100_r19",
      "doi-asserted-by": "crossref",
      "first-page": "2748",
      "DOI": "10.1063/1.1677603",
      "volume": "56",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020911432567100_r20",
      "doi-asserted-by": "crossref",
      "first-page": "2772",
      "DOI": "10.1021/j100792a006",
      "volume": "68",
      "year": "1964",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020911432567100_r21",
      "doi-asserted-by": "crossref",
      "first-page": "1520",
      "DOI": "10.1103/PhysRevLett.27.1520",
      "volume": "27",
      "year": "1971",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020911432567100_r22"
    },
    {
      "key": "2024020911432567100_r23",
      "doi-asserted-by": "crossref",
      "first-page": "95",
      "DOI": "10.1016/0022-3697(57)90054-9",
      "volume": "3",
      "year": "1957",
      "journal-title": "J. Phys. Chem. Solids"
    },
    {
      "key": "2024020911432567100_r23a",
      "doi-asserted-by": "crossref",
      "first-page": "78",
      "DOI": "10.1016/0022-3697(58)90132-X",
      "volume": "5",
      "year": "1958",
      "journal-title": "J. Phys. Chem. Solids"
    },
    {
      "key": "2024020911432567100_r24",
      "doi-asserted-by": "crossref",
      "first-page": "454",
      "DOI": "10.1016/0039-6028(72)90232-4",
      "volume": "29",
      "year": "1972",
      "journal-title": "Surface Sci."
    },
    {
      "key": "2024020911432567100_r25"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/60/12/4719/18890875/4719_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/60/12/4719/18890875/4719_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T12:37:02Z",
    "timestamp": 1707482222000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/60/12/4719/771550/Adsorption-of-CO-on-a-Ni-111-surface"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1974,
        6,
        15
      ]
    ]
  },
  "references-count": 28,
  "journal-issue": {
    "issue": "12",
    "published-print": {
      "date-parts": [
        [
          1974,
          6,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1680972",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1974,
        6,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1974,
        6,
        15
      ]
    ]
  }
}