DOI: 10.1063/1.1680718. Clustering in supercooled water

10.1063/1.1680718

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The specific heats and densities of supercooled water and heavy water have been measured from the respective melting points to the respective homogeneous nucleation temperatures. The calorimetric measurements indicate structural contributions to the differences between the specific heats of the liquids and the corresponding crystals. These ``structural specific heats'' are exponential functions of the supercooling. The results are interpreted in terms of Frenkel's heterophase fluctuation theory. It is concluded that, during supercooling, water molecules tend to form icelike clusters incorporating six or more monomers.

Bibliography

Rasmussen, D. H., & MacKenzie, A. P. (1973). Clustering in supercooled water. The Journal of Chemical Physics, 59(9), 5003â5013.

Authors 2

D. H. Rasmussen (first)
A. P. MacKenzie (additional)

References 39 Referenced 157

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 9, 2004, 4:10 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 7:14 a.m.)
Indexed	1 month, 2 weeks ago (July 8, 2025, 7:06 a.m.)
Issued	51 years, 9 months ago (Nov. 1, 1973)
Published	51 years, 9 months ago (Nov. 1, 1973)
Published Print	51 years, 9 months ago (Nov. 1, 1973)

Funders 0

None

BibTeX

@article{Rasmussen_1973, title={Clustering in supercooled water}, volume={59}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1680718}, DOI={10.1063/1.1680718}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rasmussen, D. H. and MacKenzie, A. P.}, year={1973}, month=nov, pages={5003–5013} }

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