DOI: 10.1063/1.1680605. Molecular electron affinities from collisional ionization of cesium. II. SF6 and TeF6

Molecular electron affinities from collisional ionization of cesium. II. SF6 and TeF6

10.1063/1.1680605

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The relative cross sections for the production of mass selected negative ions resulting from collisions of Cs with SF6 and TeF6 have been studied as a function of the incident cesium atom energy from 0 to 40 eV. Electron affinities (E.A.) for SF6 and TeF6 are derived from accurate measurements of the threshold for ion-pair production with the results E.A. (SF6)=0.54−0.17+0.1 eV and E.A. (TeF6)=3.34−0.17+0.1 eV. Dissociative ionization studies resulted in E.A.(SF5) ≥ 2.8 ± 0.2 eV and D(SF6−−F)=1.05± 0.1 eV.

Bibliography

Compton, R. N., & Cooper, C. D. (1973). Molecular electron affinities from collisional ionization of cesium. II. SF6 and TeF6. The Journal of Chemical Physics, 59(8), 4140â4144.

Authors 2

R. N. Compton (first)
C. D. Cooper (additional)

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 9, 2004, 4:10 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 6:59 a.m.)
Indexed	3 months, 1 week ago (May 15, 2025, 1:09 p.m.)
Issued	51 years, 10 months ago (Oct. 15, 1973)
Published	51 years, 10 months ago (Oct. 15, 1973)
Published Print	51 years, 10 months ago (Oct. 15, 1973)

Funders 0

None

BibTeX

@article{Compton_1973, title={Molecular electron affinities from collisional ionization of cesium. II. SF6 and TeF6}, volume={59}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1680605}, DOI={10.1063/1.1680605}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Compton, R. N. and Cooper, C. D.}, year={1973}, month=oct, pages={4140–4144} }

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