DOI: 10.1063/1.1680504. Symmetry assignments of the lowest CT excited states of ruthenium (II) complexes via a proposed electronic coupling model

Symmetry assignments of the lowest CT excited states of ruthenium (II) complexes via a proposed electronic coupling model

10.1063/1.1680504

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Temperature dependence measurements of the decay times of the observed charge-transfer luminescence of three ruthenium (II) complexes indicate a manifold of decaying excited levels in thermal equilibrium. Relative energies and decay constants for each level have been derived from the data for the tris(2, 2′-bipyridine)ruthenium(II) and tris(4, 4′-diphenyl-2, 2′-bipyridine)ruthenium(II) cations and for cis-dicyanobis(2, 2′-bipyridine) ruthenium(II). An electronic coupling model has been proposed that satisfactorily rationalizes the experimental results and allows the levels to be symmetry labeled.

Bibliography

Harrigan, R. W., & Crosby, G. A. (1973). Symmetry assignments of the lowest CT excited states of ruthenium (II) complexes via a proposed electronic coupling model. The Journal of Chemical Physics, 59(7), 3468â3476.

Authors 2

R. W. Harrigan (first)
G. A. Crosby (additional)

References 19 Referenced 123

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10.1016/0022-2852(68)90144-6 / J. Mol. Spectrosc. (1968)
10.1021/ja00741a003 / J. Am. Chem. Soc. (1971)
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10.1021/ja00742a016 / J. Am. Chem. Soc. (1971)
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10.1021/ja00763a007 / J. Am. Chem. Soc. (1972)
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{'key': '2024020910543628100_r11'}
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{'key': '2024020910543628100_r17'}
{'key': '2024020910543628100_r18'}

Dates

Type	When
Created	21 years, 6 months ago (Feb. 9, 2004, 4:10 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 6:53 a.m.)
Indexed	2 weeks, 5 days ago (Aug. 5, 2025, 8:13 a.m.)
Issued	51 years, 10 months ago (Oct. 1, 1973)
Published	51 years, 10 months ago (Oct. 1, 1973)
Published Print	51 years, 10 months ago (Oct. 1, 1973)

Funders 0

None

BibTeX

@article{Harrigan_1973, title={Symmetry assignments of the lowest CT excited states of ruthenium (II) complexes via a proposed electronic coupling model}, volume={59}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1680504}, DOI={10.1063/1.1680504}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Harrigan, R. W. and Crosby, G. A.}, year={1973}, month=oct, pages={3468–3476} }

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