Abstract
Single crystal EPR spectra of tris(octamethylpyrophosphoramide) copper (II) perchlorate have been obtained at 90 °K. The results are correlated with x-ray structural data and evidence is presented in support of a model in which three g tensors are related by the trigonal axis of the unit cell. The model is consistent with the dynamic-static Jahn-Teller theory proposed by Abragam and Pryce which assumes the presence of three mutually perpendicular tetragonal distortions of equal energy.
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Dates
Type | When |
---|---|
Created | 21 years, 6 months ago (Feb. 9, 2004, 4:10 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 7:10 a.m.) |
Indexed | 1 year, 6 months ago (Feb. 9, 2024, 7:43 a.m.) |
Issued | 51 years, 8 months ago (Dec. 15, 1973) |
Published | 51 years, 8 months ago (Dec. 15, 1973) |
Published Print | 51 years, 8 months ago (Dec. 15, 1973) |
@article{Koch_1973, title={Single crystal electron paramagnetic resonance study of tris (octamethylpyrophosphoramide) copper (II) perchlorate}, volume={59}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1680010}, DOI={10.1063/1.1680010}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Koch, Richard C. and Joesten, Melvin D. and Venable, John H.}, year={1973}, month=dec, pages={6312–6320} }