DOI: 10.1063/1.1679527. Vibrational population inversion in hydrogen iodide from H+I2→ HI+I

Vibrational population inversion in hydrogen iodide from H+I2→ HI+I

10.1063/1.1679527

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A classical trajectory analysis for the reaction H+I2→ HI+I at 600°K, using trajectories sampled within the transition region, shows vibrational excitation of the HI product molecules, mainly to the v=3 to v=5 levels. The calculated thermal rate is in approximate agreement with measurements by Sullivan. The product angular distribution is peaked at 110–120° relative to the incident atoms as measured for the reaction of D atoms by McDonald, LeBreton, and Herschbach. The translational energy distribution of the products is also similar to that found by McDonald et al. for the deuterium analog.

Bibliography

Anderson, J. B., & Kung, R. T. V. (1973). Vibrational population inversion in hydrogen iodide from H+I2â HI+I. The Journal of Chemical Physics, 58(6), 2477â2479.

Authors 2

J. B. Anderson (first)
R. T. V. Kung (additional)

References 19 Referenced 17

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{'key': '2024020910065059600_r1b', 'first-page': '613', 'volume': '9', 'year': '1969', 'journal-title': 'Zh. Eksp. Teor. Fiz. Pisma Red.'} / Zh. Eksp. Teor. Fiz. Pisma Red. (1969)
10.1063/1.1744517 / J. Chem. Phys. (1958)
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10.1063/1.1733755 / J. Chem. Phys. (1963)
{'key': '2024020910065059600_r2c', 'first-page': '352', 'volume': '14', 'year': '1965', 'journal-title': 'Phys. Rev. Letters'} / Phys. Rev. Letters (1965)
{'key': '2024020910065059600_r3', 'first-page': '570', 'volume': 'A258', 'year': '1960', 'journal-title': 'Proc. Royal Soc. (London)'} / Proc. Royal Soc. (London) (1960)
10.1039/DF9674400183 / Discuss. Faraday Soc. (1967)
10.1063/1.1754926 / Appl. Phys. Lett. (1967)
{'key': '2024020910065059600_r3c', 'first-page': '419', 'volume': 'QE-3', 'year': '1967', 'journal-title': 'IEEE J. Quantum Electron'} / IEEE J. Quantum Electron (1967)
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{'key': '2024020910065059600_r7'}
{'key': '2024020910065059600_r8'}
{'key': '2024020910065059600_r9'}
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Dates

Type	When
Created	21 years, 6 months ago (Feb. 4, 2004, 5:30 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 6:07 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:07 a.m.)
Issued	52 years, 5 months ago (March 15, 1973)
Published	52 years, 5 months ago (March 15, 1973)
Published Print	52 years, 5 months ago (March 15, 1973)

Funders 0

None

BibTeX

@article{Anderson_1973, title={Vibrational population inversion in hydrogen iodide from H+I2→ HI+I}, volume={58}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1679527}, DOI={10.1063/1.1679527}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Anderson, J. B. and Kung, R. T. V.}, year={1973}, month=mar, pages={2477–2479} }

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