DOI: 10.1063/1.1679435. Temperature dependence of electron attachment at low energies for polyatomic molecules

Temperature dependence of electron attachment at low energies for polyatomic molecules

10.1063/1.1679435

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The cross sections for production of negative ions by attachment of low-energy (&lt;0.2 eV) electrons to selected polyatomic (SF6, CCl4, CFCl3, CH2Br2, CH3I, CHCl3, CF3Br, CH3Br) molecules have been determined as a function of target gas temperature in the range from 300 to 1200°K. For the case of SF6 it is found that the total cross section for negative ion production is independent of gas temperature, although it is known from the experiments of Chen and Chantry that the relative abundances of different species of negative ions produced from SF6 are strongly temperature dependent. In contrast to SF6, the total cross sections for negative ion production in some halogenated hydrocarbons are found to be strongly temperature dependent. It is found that the total cross section for negative ion production in many polyatomic molecules tends towards an absolute maximum as the gas temperature is increased.

Bibliography

Spence, D., & Schulz, G. J. (1973). Temperature dependence of electron attachment at low energies for polyatomic molecules. The Journal of Chemical Physics, 58(5), 1800â1803.

Authors 2

D. Spence (first)
G. J. Schulz (additional)

References 38 Referenced 153

{'key': '2024020910112646000_r1', 'first-page': '389', 'volume': '65', 'year': '1961', 'journal-title': 'J. Res. Nat. Bur. Stand. (U.S.)'} / J. Res. Nat. Bur. Stand. (U.S.) (1961)
10.1021/j100796a036 / J. Phys. Chem. (1963)
{'key': '2024020910112646000_r3', 'first-page': '76', 'volume': '221', 'year': '1971', 'journal-title': 'Sci. Am.'} / Sci. Am. (1971)
10.1063/1.1698559 / J. Chem. Phys. (1953)
10.1063/1.1743019 / J. Chem. Phys. (1956)
10.1063/1.1744534 / J. Chem. Phys. (1958)
10.1063/1.1701051 / J. Chem. Phys. (1961)
10.1088/0370-1328/83/4/314 / Proc. Phys. Soc. (1964)
10.1063/1.1726998 / J. Chem. Phys. (1966)
10.1063/1.1727547 / J. Chem. Phys. (1966)
10.1021/j100865a017 / J. Phys. Chem. (1967)
10.1063/1.1672261 / J. Chem. Phys. (1969)
10.1016/0020-7381(69)85003-5 / Int. J. Mass Spectrom. Ion Phys. (1969)
{'key': '2024020910112646000_r14', 'first-page': '418', 'volume': '15', 'year': '1970', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1970)
10.1063/1.1674280 / J. Chem. Phys. (1970)
10.1063/1.1674440 / J. Chem. Phys. (1970)
10.1016/0020-7055(71)90029-5 / Int. J. Rad. Phys. Chem. (1971)
10.1063/1.1674631 / J. Chem. Phys. (1971)
{'key': '2024020910112646000_r19', 'first-page': '406', 'volume': '17', 'year': '1971', 'journal-title': 'Bull. Amer. Phys. Soc.'} / Bull. Amer. Phys. Soc. (1971)
{'key': '2024020910112646000_r20'}
10.1016/0020-7381(71)83009-7 / Int. J. Mass. Spectrom. Ion Physics (1971)
10.1016/0010-2180(68)90068-0 / Combust. Flame (1968)
10.1103/PhysRev.188.280 / Phys. Rev. (1969)
10.1063/1.1715198 / Rev. Sci. Instrum. (1955)
{'key': '2024020910112646000_r25', 'first-page': '1134', 'volume': '31', 'year': '1960', 'journal-title': 'J. Appl. Phys.'} / J. Appl. Phys. (1960)
{'key': '2024020910112646000_r26'}
{'key': '2024020910112646000_r27'}
{'key': '2024020910112646000_r28'}
{'key': '2024020910112646000_r29'}
10.1063/1.1670274 / J. Chem. Phys. (1968)
{'key': '2024020910112646000_r31'}
{'key': '2024020910112646000_r32'}
{'key': '2024020910112646000_r33'}
10.1063/1.1776916 / J. Chem. Phys. (1963)
10.1103/PhysRevLett.28.333 / Phys. Rev. Lett. (1972)
10.1103/PhysRev.183.157 / Phys. Rev. (1969)
{'key': '2024020910112646000_r37', 'first-page': '14', 'volume': '150', 'year': '1960', 'journal-title': 'Phys. Rev.'} / Phys. Rev. (1960)
10.1063/1.1672521 / J. Chem. Phys. (1969)

Dates

Type	When
Created	21 years, 6 months ago (Feb. 4, 2004, 5:30 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 6:11 a.m.)
Indexed	3 months, 1 week ago (May 19, 2025, 8:30 a.m.)
Issued	52 years, 5 months ago (March 1, 1973)
Published	52 years, 5 months ago (March 1, 1973)
Published Print	52 years, 5 months ago (March 1, 1973)

Funders 0

None

BibTeX

@article{Spence_1973, title={Temperature dependence of electron attachment at low energies for polyatomic molecules}, volume={58}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1679435}, DOI={10.1063/1.1679435}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Spence, D. and Schulz, G. J.}, year={1973}, month=mar, pages={1800–1803} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        5,
        19
      ]
    ],
    "date-time": "2025-05-19T12:30:20Z",
    "timestamp": 1747657820325
  },
  "reference-count": 38,
  "publisher": "AIP Publishing",
  "issue": "5",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1973,
        3,
        1
      ]
    ]
  },
  "abstract": "<jats:p>The cross sections for production of negative ions by attachment of low-energy (&amp;lt;0.2 eV) electrons to selected polyatomic (SF6, CCl4, CFCl3, CH2Br2, CH3I, CHCl3, CF3Br, CH3Br) molecules have been determined as a function of target gas temperature in the range from 300 to 1200\u00b0K. For the case of SF6 it is found that the total cross section for negative ion production is independent of gas temperature, although it is known from the experiments of Chen and Chantry that the relative abundances of different species of negative ions produced from SF6 are strongly temperature dependent. In contrast to SF6, the total cross sections for negative ion production in some halogenated hydrocarbons are found to be strongly temperature dependent. It is found that the total cross section for negative ion production in many polyatomic molecules tends towards an absolute maximum as the gas temperature is increased.</jats:p>",
  "DOI": "10.1063/1.1679435",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        2,
        4
      ]
    ],
    "date-time": "2004-02-04T22:30:48Z",
    "timestamp": 1075933848000
  },
  "page": "1800-1803",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 153,
  "title": "Temperature dependence of electron attachment at low energies for polyatomic molecules",
  "prefix": "10.1063",
  "volume": "58",
  "author": [
    {
      "given": "D.",
      "family": "Spence",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Engineering and Applied Science, Mason Laboratory, Yale University, New Haven, Connecticut 06520"
        }
      ]
    },
    {
      "given": "G. J.",
      "family": "Schulz",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Engineering and Applied Science, Mason Laboratory, Yale University, New Haven, Connecticut 06520"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020910112646000_r1",
      "first-page": "389",
      "volume": "65",
      "year": "1961",
      "journal-title": "J. Res. Nat. Bur. Stand. (U.S.)"
    },
    {
      "key": "2024020910112646000_r2",
      "doi-asserted-by": "crossref",
      "first-page": "360",
      "DOI": "10.1021/j100796a036",
      "volume": "67",
      "year": "1963",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020910112646000_r3",
      "first-page": "76",
      "volume": "221",
      "year": "1971",
      "journal-title": "Sci. Am."
    },
    {
      "key": "2024020910112646000_r4",
      "doi-asserted-by": "crossref",
      "first-page": "119",
      "DOI": "10.1063/1.1698559",
      "volume": "21",
      "year": "1953",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r5",
      "doi-asserted-by": "crossref",
      "first-page": "642",
      "DOI": "10.1063/1.1743019",
      "volume": "25",
      "year": "1956",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r6",
      "doi-asserted-by": "crossref",
      "first-page": "517",
      "DOI": "10.1063/1.1744534",
      "volume": "29",
      "year": "1958",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r7",
      "doi-asserted-by": "crossref",
      "first-page": "1595",
      "DOI": "10.1063/1.1701051",
      "volume": "34",
      "year": "1961",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r8",
      "doi-asserted-by": "crossref",
      "first-page": "611",
      "DOI": "10.1088/0370-1328/83/4/314",
      "volume": "83",
      "year": "1964",
      "journal-title": "Proc. Phys. Soc."
    },
    {
      "key": "2024020910112646000_r9",
      "doi-asserted-by": "crossref",
      "first-page": "2192",
      "DOI": "10.1063/1.1726998",
      "volume": "44",
      "year": "1966",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r10",
      "doi-asserted-by": "crossref",
      "first-page": "4634",
      "DOI": "10.1063/1.1727547",
      "volume": "45",
      "year": "1966",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r11",
      "doi-asserted-by": "crossref",
      "first-page": "1652",
      "DOI": "10.1021/j100865a017",
      "volume": "71",
      "year": "1967",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020910112646000_r12",
      "doi-asserted-by": "crossref",
      "first-page": "1791",
      "DOI": "10.1063/1.1672261",
      "volume": "51",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r13",
      "doi-asserted-by": "crossref",
      "first-page": "197",
      "DOI": "10.1016/0020-7381(69)85003-5",
      "volume": "3",
      "year": "1969",
      "journal-title": "Int. J. Mass Spectrom. Ion Phys."
    },
    {
      "key": "2024020910112646000_r14",
      "first-page": "418",
      "volume": "15",
      "year": "1970",
      "journal-title": "Bull. Am. Phys. Soc."
    },
    {
      "key": "2024020910112646000_r15",
      "doi-asserted-by": "crossref",
      "first-page": "2000",
      "DOI": "10.1063/1.1674280",
      "volume": "53",
      "year": "1970",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r16",
      "doi-asserted-by": "crossref",
      "first-page": "2999",
      "DOI": "10.1063/1.1674440",
      "volume": "53",
      "year": "1970",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r17",
      "doi-asserted-by": "crossref",
      "first-page": "273",
      "DOI": "10.1016/0020-7055(71)90029-5",
      "volume": "3",
      "year": "1971",
      "journal-title": "Int. J. Rad. Phys. Chem."
    },
    {
      "key": "2024020910112646000_r18",
      "doi-asserted-by": "crossref",
      "first-page": "438",
      "DOI": "10.1063/1.1674631",
      "volume": "54",
      "year": "1971",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r19",
      "first-page": "406",
      "volume": "17",
      "year": "1971",
      "journal-title": "Bull. Amer. Phys. Soc."
    },
    {
      "key": "2024020910112646000_r20"
    },
    {
      "key": "2024020910112646000_r21",
      "doi-asserted-by": "crossref",
      "first-page": "117",
      "DOI": "10.1016/0020-7381(71)83009-7",
      "volume": "6",
      "year": "1971",
      "journal-title": "Int. J. Mass. Spectrom. Ion Physics"
    },
    {
      "key": "2024020910112646000_r22",
      "doi-asserted-by": "crossref",
      "first-page": "513",
      "DOI": "10.1016/0010-2180(68)90068-0",
      "volume": "12",
      "year": "1968",
      "journal-title": "Combust. Flame"
    },
    {
      "key": "2024020910112646000_r23",
      "doi-asserted-by": "crossref",
      "first-page": "280",
      "DOI": "10.1103/PhysRev.188.280",
      "volume": "188",
      "year": "1969",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020910112646000_r24",
      "doi-asserted-by": "crossref",
      "first-page": "1101",
      "DOI": "10.1063/1.1715198",
      "volume": "26",
      "year": "1955",
      "journal-title": "Rev. Sci. Instrum."
    },
    {
      "key": "2024020910112646000_r25",
      "first-page": "1134",
      "volume": "31",
      "year": "1960",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020910112646000_r26"
    },
    {
      "key": "2024020910112646000_r27"
    },
    {
      "key": "2024020910112646000_r28"
    },
    {
      "key": "2024020910112646000_r29"
    },
    {
      "key": "2024020910112646000_r30",
      "doi-asserted-by": "crossref",
      "first-page": "1526",
      "DOI": "10.1063/1.1670274",
      "volume": "49",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r31"
    },
    {
      "key": "2024020910112646000_r32"
    },
    {
      "key": "2024020910112646000_r33"
    },
    {
      "key": "2024020910112646000_r34",
      "doi-asserted-by": "crossref",
      "first-page": "1540",
      "DOI": "10.1063/1.1776916",
      "volume": "38",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020910112646000_r35",
      "doi-asserted-by": "crossref",
      "first-page": "333",
      "DOI": "10.1103/PhysRevLett.28.333",
      "volume": "28",
      "year": "1972",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020910112646000_r36",
      "doi-asserted-by": "crossref",
      "first-page": "157",
      "DOI": "10.1103/PhysRev.183.157",
      "volume": "183",
      "year": "1969",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020910112646000_r37",
      "first-page": "14",
      "volume": "150",
      "year": "1960",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020910112646000_r38",
      "doi-asserted-by": "crossref",
      "first-page": "3369",
      "DOI": "10.1063/1.1672521",
      "volume": "51",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/58/5/1800/18884133/1800_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/58/5/1800/18884133/1800_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T11:11:38Z",
    "timestamp": 1707477098000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/58/5/1800/213526/Temperature-dependence-of-electron-attachment-at"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1973,
        3,
        1
      ]
    ]
  },
  "references-count": 38,
  "journal-issue": {
    "issue": "5",
    "published-print": {
      "date-parts": [
        [
          1973,
          3,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1679435",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1973,
        3,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1973,
        3,
        1
      ]
    ]
  }
}