DOI: 10.1063/1.1678963. Self-diffusion in liquid ammonia and deuteroammonia

Self-diffusion in liquid ammonia and deuteroammonia

10.1063/1.1678963

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Coefficients of self-diffusion have been measured by the spin-echo technique for neat NH3 and ND3 from 200 to 298°K. The data are well represented by D=(4.5± 0.2)× 10−3exp [−(2.07± 0.02)/RT] for NH3 and by D=(6.0± 0.3)× 10−3exp [−(2.31± 0.02)/RT] for ND3. The difference in activation energy for self-diffusion between NH3 and ND3 is shown to be consistent with the viscosity measurements of Hutchison and O'Reilly. These results are interpreted by means of a quasilattice model for self-diffusion in the liquid state. Values of the work required to create a molecular vacancy are evaluated from liquid density, isothermal compressibility and the scaled particle theory. The quasilattice model yields pre-exponential factors for self-diffusion that are in reasonable agreement with experiment.

Bibliography

OâReilly, D. E., Peterson, E. M., & Scheie, C. E. (1973). Self-diffusion in liquid ammonia and deuteroammonia. The Journal of Chemical Physics, 58(10), 4072â4075.

Authors 3

D. E. O'Reilly (first)
E. M. Peterson (additional)
C. E. Scheie (additional)

References 17 Referenced 56

10.1063/1.1731559 / J. Chem. Phys. (1961)
10.1063/1.1673662 / J. Chem. Phys. (1970)
10.1063/1.1678036 / J. Chem. Phys. (1972)
10.1103/PhysRev.94.630 / Phys. Rev. (1954)
10.1063/1.1716828 / Rev. Sci. Instrum. (1960)
10.1016/0031-9163(65)90016-8 / Phys. Lett. (1965)
10.1063/1.1676386 / J. Chem. Phys. (1971)
{'key': '2024020910262085500_r8'}
10.1107/S0365110X59002420 / Acta Crystallogr. (1959)
10.1063/1.1676509 / J. Chem. Phys. (1971)
10.1063/1.1677567 / J. Chem. Phys. (1972)
{'key': '2024020910262085500_r11', 'first-page': '269', 'volume': '24', 'year': '1963', 'journal-title': 'Acta Phys. Pol.'} / Acta Phys. Pol. (1963)
10.1021/je60037a019 / J. Chem. Eng. Data (1968)
10.1063/1.1700883 / J. Chem. Phys. (1960)
10.1063/1.1677074 / J. Chem. Phys. (1972)
10.1063/1.1678334 / J. Chem. Phys. (1972)
10.1016/0009-2614(67)85079-6 / Chem. Phys. Lett. (1967)

Dates

Type	When
Created	21 years, 6 months ago (Feb. 4, 2004, 5:30 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 6:25 a.m.)
Indexed	7 months, 4 weeks ago (Dec. 30, 2024, 1:09 p.m.)
Issued	52 years, 3 months ago (May 15, 1973)
Published	52 years, 3 months ago (May 15, 1973)
Published Print	52 years, 3 months ago (May 15, 1973)

Funders 0

None

BibTeX

@article{O_Reilly_1973, title={Self-diffusion in liquid ammonia and deuteroammonia}, volume={58}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1678963}, DOI={10.1063/1.1678963}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={O’Reilly, D. E. and Peterson, E. M. and Scheie, C. E.}, year={1973}, month=may, pages={4072–4075} }

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