DOI: 10.1063/1.1678575. Torsion-Vibration-Rotation Interactions in Methanol. IV. Microwave Spectrum of CH3OH in the Excited CO Stretching State

Torsion-Vibration-Rotation Interactions in Methanol. IV. Microwave Spectrum of CH3OH in the Excited CO Stretching State

10.1063/1.1678575

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The K=2← 1 E1 Q branch and the JK=10← 00 A-E doublet have been observed for the first excited CO stretching mode in the microwave spectrum of normal methanol. A value for the excited state barrier to internal rotation of 397.9± 3 cm−1 is required to reproduce the Q-branch origin frequency of 47 929.9 MHz, with reasonable limits on geometry changes assumed. This value is consistent with previous infrared results.

Bibliography

Lees, R. M. (1972). Torsion-Vibration-Rotation Interactions in Methanol. IV. Microwave Spectrum of CH3OH in the Excited CO Stretching State. The Journal of Chemical Physics, 57(6), 2249â2252.

Authors 1

R. M. Lees (first)

References 15 Referenced 48

{'key': '2024020909410058300_r1'}
{'key': '2024020909410058300_r1a'}
10.1063/1.1668221 / J. Chem. Phys. (1968)
10.1063/1.1678323 / J. Chem. Phys. (1972)
10.1051/jphysrad:01960002108-9063400 / J. Phys. Radium (1960)
10.1016/0022-2852(65)90152-9 / J. Mol. Spectry. (1965)
10.1063/1.1668024 / J. Chem. Phys. (1968)
10.1063/1.1698668 / J. Chem. Phys. (1953)
10.1063/1.1739886 / J. Chem. Phys. (1954)
10.1143/JPSJ.11.781 / J. Phys. Soc. Japan (1956)
10.1063/1.1733049 / J. Chem. Phys. (1962)
10.1063/1.1677131 / J. Chem. Phys. (1972)
{'key': '2024020909410058300_r9'}
{'key': '2024020909410058300_r9a'}
10.1002/9780470171851.ch1 / Progr. Phys. Org. Chem. (1968)

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 4:02 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:40 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 3:31 a.m.)
Issued	52 years, 11 months ago (Sept. 15, 1972)
Published	52 years, 11 months ago (Sept. 15, 1972)
Published Print	52 years, 11 months ago (Sept. 15, 1972)

Funders 0

None

BibTeX

@article{Lees_1972, title={Torsion-Vibration-Rotation Interactions in Methanol. IV. Microwave Spectrum of CH3OH in the Excited CO Stretching State}, volume={57}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1678575}, DOI={10.1063/1.1678575}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lees, R. M.}, year={1972}, month=sep, pages={2249–2252} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        11
      ]
    ],
    "date-time": "2024-02-11T08:31:20Z",
    "timestamp": 1707640280795
  },
  "reference-count": 15,
  "publisher": "AIP Publishing",
  "issue": "6",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1972,
        9,
        15
      ]
    ]
  },
  "abstract": "<jats:p>The K=2\u2190 1\u2009E1\u2009Q branch and the JK=10\u2190 00\u2009A-E doublet have been observed for the first excited CO stretching mode in the microwave spectrum of normal methanol. A value for the excited state barrier to internal rotation of 397.9\u00b1 3\u2009cm\u22121 is required to reproduce the Q-branch origin frequency of 47 929.9 MHz, with reasonable limits on geometry changes assumed. This value is consistent with previous infrared results.</jats:p>",
  "DOI": "10.1063/1.1678575",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        2,
        6
      ]
    ],
    "date-time": "2004-02-06T21:02:35Z",
    "timestamp": 1076101355000
  },
  "page": "2249-2252",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 48,
  "title": "Torsion-Vibration-Rotation Interactions in Methanol. IV. Microwave Spectrum of CH3OH in the Excited CO Stretching State",
  "prefix": "10.1063",
  "volume": "57",
  "author": [
    {
      "given": "R. M.",
      "family": "Lees",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Physics, University of New Brunswick, Fredericton, New Brunswick, Canada"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020909410058300_r1"
    },
    {
      "key": "2024020909410058300_r1a"
    },
    {
      "key": "2024020909410058300_r2",
      "doi-asserted-by": "crossref",
      "first-page": "5299",
      "DOI": "10.1063/1.1668221",
      "volume": "48",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909410058300_r3",
      "doi-asserted-by": "crossref",
      "first-page": "824",
      "DOI": "10.1063/1.1678323",
      "volume": "57",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909410058300_r4",
      "doi-asserted-by": "crossref",
      "first-page": "634",
      "DOI": "10.1051/jphysrad:01960002108-9063400",
      "volume": "21",
      "year": "1960",
      "journal-title": "J. Phys. Radium"
    },
    {
      "key": "2024020909410058300_r4a",
      "doi-asserted-by": "crossref",
      "first-page": "378",
      "DOI": "10.1016/0022-2852(65)90152-9",
      "volume": "15",
      "year": "1965",
      "journal-title": "J. Mol. Spectry."
    },
    {
      "key": "2024020909410058300_r5",
      "doi-asserted-by": "crossref",
      "first-page": "4544",
      "DOI": "10.1063/1.1668024",
      "volume": "48",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909410058300_r6",
      "doi-asserted-by": "crossref",
      "first-page": "1804",
      "DOI": "10.1063/1.1698668",
      "volume": "21",
      "year": "1953",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909410058300_r7",
      "doi-asserted-by": "crossref",
      "first-page": "1733",
      "DOI": "10.1063/1.1739886",
      "volume": "22",
      "year": "1954",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909410058300_r7a",
      "doi-asserted-by": "crossref",
      "first-page": "781",
      "DOI": "10.1143/JPSJ.11.781",
      "volume": "11",
      "year": "1956",
      "journal-title": "J. Phys. Soc. Japan"
    },
    {
      "key": "2024020909410058300_r7b",
      "doi-asserted-by": "crossref",
      "first-page": "2516",
      "DOI": "10.1063/1.1733049",
      "volume": "37",
      "year": "1962",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909410058300_r8",
      "doi-asserted-by": "crossref",
      "first-page": "5887",
      "DOI": "10.1063/1.1677131",
      "volume": "56",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909410058300_r9"
    },
    {
      "key": "2024020909410058300_r9a"
    },
    {
      "key": "2024020909410058300_r10",
      "doi-asserted-by": "crossref",
      "first-page": "1",
      "DOI": "10.1002/9780470171851.ch1",
      "volume": "6",
      "year": "1968",
      "journal-title": "Progr. Phys. Org. Chem."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/57/6/2249/18882090/2249_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/57/6/2249/18882090/2249_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T10:40:21Z",
    "timestamp": 1707475221000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/57/6/2249/455680/Torsion-Vibration-Rotation-Interactions-in"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1972,
        9,
        15
      ]
    ]
  },
  "references-count": 15,
  "journal-issue": {
    "issue": "6",
    "published-print": {
      "date-parts": [
        [
          1972,
          9,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1678575",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1972,
        9,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1972,
        9,
        15
      ]
    ]
  }
}