DOI: 10.1063/1.1678453. Quenching of Infrared Chemiluminescence: Rates of Energy Transfer from HF (v ≤ 5) to CO2 and HF, and from DF (v ≤ 3) to CO2 and HF

Quenching of Infrared Chemiluminescence: Rates of Energy Transfer from HF (v ≤ 5) to CO2 and HF, and from DF (v ≤ 3) to CO2 and HF

10.1063/1.1678453

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The intensity of HF (and DF) infrared chemiluminescence from vibrationally excited molecules produced in the chain reaction H + F2 → HF + F; F + H2 → HF + H (and its deuterium analogue) has been studied as a function of the concentration of added CO2 and HF. Using a steady-state analysis rate coefficients have been determined for transfer of vibrational energy from HF (v ≤ 5) and DF (v ≤ 3) to (vibrationally cold) CO2 and HF. The results are discussed in terms of possible mechanisms for energy transfer and the importance of the processes in chemical lasers.

Bibliography

Airey, J. R., & Smith, I. W. M. (1972). Quenching of Infrared Chemiluminescence: Rates of Energy Transfer from HF (v â¤ 5) to CO2 and HF, and from DF (v â¤ 3) to CO2 and HF. The Journal of Chemical Physics, 57(4), 1669â1676.

Authors 2

J. R. Airey (first)
I. W. M. Smith (additional)

References 39 Referenced 80

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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 4:02 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:17 a.m.)
Indexed	1 month, 3 weeks ago (July 4, 2025, 8:06 a.m.)
Issued	53 years ago (Aug. 15, 1972)
Published	53 years ago (Aug. 15, 1972)
Published Print	53 years ago (Aug. 15, 1972)

Funders 0

None

BibTeX

@article{Airey_1972, title={Quenching of Infrared Chemiluminescence: Rates of Energy Transfer from HF (v ≤ 5) to CO2 and HF, and from DF (v ≤ 3) to CO2 and HF}, volume={57}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1678453}, DOI={10.1063/1.1678453}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Airey, J. R. and Smith, I. W. M.}, year={1972}, month=aug, pages={1669–1676} }

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