DOI: 10.1063/1.1678394. Laser Induced Combination Band Fluorescence in Ethylene Gas

Laser Induced Combination Band Fluorescence in Ethylene Gas

10.1063/1.1678394

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Laser induced vibrational fluorescence decay measurements have been made for the (v7+v8) and (v6+v10) combination bands of C2H4 gas. The rate of vibration-translation/rotation energy transfer in ethylene was found to be 7.23± 0.3 msec−1·torr−1. This result is in agreement with one sound absorption study but disagrees with several ultrasonic dispersion studies. The rate constants for deactivation of C2H4 during collisions with CH4 and C2H6 were also determined as 8.0 msec−1·torr−1 and 92.0 msec−1·torr−1, respectively. The efficiency of ethane as a collision partner is almost certainly an indication of near resonant vibrational energy transfer between the C2H4 and C2H6 molecules. The dependence of the 5-μ and 3-μ fluorescence intensity on laser power suggests that excitation of the fluorescing states is achieved through a combination of multiphoton absorption and collision processes.

Bibliography

Yuan, R. C. L., & Flynn, G. W. (1972). Laser Induced Combination Band Fluorescence in Ethylene Gas. The Journal of Chemical Physics, 57(3), 1316â1321.

Authors 2

Raymond C. L. Yuan (first)
George W. Flynn (additional)

References 33 Referenced 53

10.1103/PhysRevLett.17.233 / Phys. Rev. Letters (1966)
10.1063/1.1840527 / J. Chem. Phys. (1967)
10.1063/1.1670247 / J. Chem. Phys. (1968)
10.1063/1.1670489 / J. Chem. Phys. (1968)
10.1063/1.1670199 / J. Chem. Phys. (1968)
10.1063/1.1674541 / J. Chem. Phys. (1970)
{'key': '2024020909174004200_r7'}
10.1063/1.1668665 / J. Chem. Phys. (1968)
10.1063/1.1672328 / J. Chem. Phys. (1969)
10.1063/1.1672793 / J. Chem. Phys. (1970)
{'key': '2024020909174004200_r11'}
10.1063/1.1677155 / J. Chem. Phys. (1972)
{'key': '2024020909174004200_r13', 'first-page': '1411', 'volume': '16', 'year': '1971', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1971)
{'key': '2024020909174004200_r14', 'first-page': '1411', 'volume': '16', 'year': '1971', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1971)
{'key': '2024020909174004200_r15', 'first-page': '1412', 'volume': '16', 'year': '1971', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1971)
{'key': '2024020909174004200_r16'}
{'key': '2024020909174004200_r17'}
{'key': '2024020909174004200_r18'}
{'key': '2024020909174004200_r19'}
10.1039/tf9656101053 / Trans. Faraday Soc. (1965)
{'key': '2024020909174004200_r21', 'first-page': '212', 'volume': '244A', 'year': '1958', 'journal-title': 'Proc. Roy. Soc.'} / Proc. Roy. Soc. (1958)
{'key': '2024020909174004200_r22', 'first-page': '289', 'volume': '264A', 'year': '1961', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1961)
{'key': '2024020909174004200_r23', 'first-page': '445', 'volume': '248A', 'year': '1958', 'journal-title': 'Proc. Roy Soc. (London)'} / Proc. Roy Soc. (London) (1958)
10.1088/0370-1328/78/6/351 / Proc. Phys. Soc. (1961)
{'key': '2024020909174004200_r25'}
{'key': '2024020909174004200_r26'}
10.1063/1.1731218 / J. Chem. Phys. (1960)
10.1063/1.1725478 / J. Chem. Phys. (1964)
10.1063/1.1653974 / Appl. Phys. Letters (1972)
10.1103/PhysRevLett.19.1273 / Phys. Rev. Letters (1967)
10.1063/1.1840437 / J. Chem. Phys. (1967)
10.1063/1.1671145 / J. Chem. Phys. (1969)
10.1016/0009-2614(71)80588-2 / Chem. Phys. Letters (1971)

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 4:02 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:18 a.m.)
Indexed	1 year, 1 month ago (Aug. 2, 2024, 2:35 a.m.)
Issued	53 years, 1 month ago (Aug. 1, 1972)
Published	53 years, 1 month ago (Aug. 1, 1972)
Published Print	53 years, 1 month ago (Aug. 1, 1972)

Funders 0

None

BibTeX

@article{Yuan_1972, title={Laser Induced Combination Band Fluorescence in Ethylene Gas}, volume={57}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1678394}, DOI={10.1063/1.1678394}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Yuan, Raymond C. L. and Flynn, George W.}, year={1972}, month=aug, pages={1316–1321} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        8,
        2
      ]
    ],
    "date-time": "2024-08-02T06:35:47Z",
    "timestamp": 1722580547699
  },
  "reference-count": 33,
  "publisher": "AIP Publishing",
  "issue": "3",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1972,
        8,
        1
      ]
    ]
  },
  "abstract": "<jats:p>Laser induced vibrational fluorescence decay measurements have been made for the (v7+v8) and (v6+v10) combination bands of C2H4 gas. The rate of vibration-translation/rotation energy transfer in ethylene was found to be 7.23\u00b1 0.3\u2009msec\u22121\u00b7torr\u22121. This result is in agreement with one sound absorption study but disagrees with several ultrasonic dispersion studies. The rate constants for deactivation of C2H4 during collisions with CH4 and C2H6 were also determined as 8.0\u2009msec\u22121\u00b7torr\u22121 and 92.0\u2009msec\u22121\u00b7torr\u22121, respectively. The efficiency of ethane as a collision partner is almost certainly an indication of near resonant vibrational energy transfer between the C2H4 and C2H6 molecules. The dependence of the 5-\u03bc and 3-\u03bc fluorescence intensity on laser power suggests that excitation of the fluorescing states is achieved through a combination of multiphoton absorption and collision processes.</jats:p>",
  "DOI": "10.1063/1.1678394",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        2,
        6
      ]
    ],
    "date-time": "2004-02-06T21:02:35Z",
    "timestamp": 1076101355000
  },
  "page": "1316-1321",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 53,
  "title": "Laser Induced Combination Band Fluorescence in Ethylene Gas",
  "prefix": "10.1063",
  "volume": "57",
  "author": [
    {
      "given": "Raymond C. L.",
      "family": "Yuan",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, Columbia University, New York, New York 10027"
        }
      ]
    },
    {
      "given": "George W.",
      "family": "Flynn",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, Columbia University, New York, New York 10027"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020909174004200_r1",
      "doi-asserted-by": "crossref",
      "first-page": "233",
      "DOI": "10.1103/PhysRevLett.17.233",
      "volume": "17",
      "year": "1966",
      "journal-title": "Phys. Rev. Letters"
    },
    {
      "key": "2024020909174004200_r2",
      "doi-asserted-by": "crossref",
      "first-page": "4222",
      "DOI": "10.1063/1.1840527",
      "volume": "46",
      "year": "1967",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r3",
      "doi-asserted-by": "crossref",
      "first-page": "1432",
      "DOI": "10.1063/1.1670247",
      "volume": "49",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r4",
      "doi-asserted-by": "crossref",
      "first-page": "2816",
      "DOI": "10.1063/1.1670489",
      "volume": "49",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r5",
      "doi-asserted-by": "crossref",
      "first-page": "1111",
      "DOI": "10.1063/1.1670199",
      "volume": "49",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r6",
      "doi-asserted-by": "crossref",
      "first-page": "3621",
      "DOI": "10.1063/1.1674541",
      "volume": "53",
      "year": "1970",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r7"
    },
    {
      "key": "2024020909174004200_r8",
      "doi-asserted-by": "crossref",
      "first-page": "5730",
      "DOI": "10.1063/1.1668665",
      "volume": "48",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r9",
      "doi-asserted-by": "crossref",
      "first-page": "2275",
      "DOI": "10.1063/1.1672328",
      "volume": "51",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r10",
      "doi-asserted-by": "crossref",
      "first-page": "5421",
      "DOI": "10.1063/1.1672793",
      "volume": "52",
      "year": "1970",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r11"
    },
    {
      "key": "2024020909174004200_r12",
      "doi-asserted-by": "crossref",
      "first-page": "6060",
      "DOI": "10.1063/1.1677155",
      "volume": "56",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r13",
      "first-page": "1411",
      "volume": "16",
      "year": "1971",
      "journal-title": "Bull. Am. Phys. Soc."
    },
    {
      "key": "2024020909174004200_r14",
      "first-page": "1411",
      "volume": "16",
      "year": "1971",
      "journal-title": "Bull. Am. Phys. Soc."
    },
    {
      "key": "2024020909174004200_r15",
      "first-page": "1412",
      "volume": "16",
      "year": "1971",
      "journal-title": "Bull. Am. Phys. Soc."
    },
    {
      "key": "2024020909174004200_r16"
    },
    {
      "key": "2024020909174004200_r17"
    },
    {
      "key": "2024020909174004200_r18"
    },
    {
      "key": "2024020909174004200_r19"
    },
    {
      "key": "2024020909174004200_r20",
      "doi-asserted-by": "crossref",
      "first-page": "1053",
      "DOI": "10.1039/tf9656101053",
      "volume": "61",
      "year": "1965",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020909174004200_r21",
      "first-page": "212",
      "volume": "244A",
      "year": "1958",
      "journal-title": "Proc. Roy. Soc."
    },
    {
      "key": "2024020909174004200_r22",
      "first-page": "289",
      "volume": "264A",
      "year": "1961",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020909174004200_r23",
      "first-page": "445",
      "volume": "248A",
      "year": "1958",
      "journal-title": "Proc. Roy Soc. (London)"
    },
    {
      "key": "2024020909174004200_r24",
      "doi-asserted-by": "crossref",
      "first-page": "1502",
      "DOI": "10.1088/0370-1328/78/6/351",
      "volume": "78",
      "year": "1961",
      "journal-title": "Proc. Phys. Soc."
    },
    {
      "key": "2024020909174004200_r25"
    },
    {
      "key": "2024020909174004200_r26"
    },
    {
      "key": "2024020909174004200_r27",
      "doi-asserted-by": "crossref",
      "first-page": "627",
      "DOI": "10.1063/1.1731218",
      "volume": "33",
      "year": "1960",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r28",
      "doi-asserted-by": "crossref",
      "first-page": "2095",
      "DOI": "10.1063/1.1725478",
      "volume": "40",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r29",
      "doi-asserted-by": "crossref",
      "first-page": "42",
      "DOI": "10.1063/1.1653974",
      "volume": "20",
      "year": "1972",
      "journal-title": "Appl. Phys. Letters"
    },
    {
      "key": "2024020909174004200_r30",
      "doi-asserted-by": "crossref",
      "first-page": "1273",
      "DOI": "10.1103/PhysRevLett.19.1273",
      "volume": "19",
      "year": "1967",
      "journal-title": "Phys. Rev. Letters"
    },
    {
      "key": "2024020909174004200_r31",
      "doi-asserted-by": "crossref",
      "first-page": "98",
      "DOI": "10.1063/1.1840437",
      "volume": "46",
      "year": "1967",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r32",
      "doi-asserted-by": "crossref",
      "first-page": "924",
      "DOI": "10.1063/1.1671145",
      "volume": "50",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020909174004200_r33",
      "doi-asserted-by": "crossref",
      "first-page": "103",
      "DOI": "10.1016/0009-2614(71)80588-2",
      "volume": "8",
      "year": "1971",
      "journal-title": "Chem. Phys. Letters"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/57/3/1316/18880455/1316_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/57/3/1316/18880455/1316_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T10:18:04Z",
    "timestamp": 1707473884000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/57/3/1316/754670/Laser-Induced-Combination-Band-Fluorescence-in"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1972,
        8,
        1
      ]
    ]
  },
  "references-count": 33,
  "journal-issue": {
    "issue": "3",
    "published-print": {
      "date-parts": [
        [
          1972,
          8,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1678394",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1972,
        8,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1972,
        8,
        1
      ]
    ]
  }
}