DOI: 10.1063/1.1678198. Self-Diffusion in Liquid Water to −31°C

10.1063/1.1678198

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The self-diffusion coefficient of water is reported to −31°C, where the activation energy reaches 11 kcal/mole compared with 4.5 kcal/mole at 25°C. The similarity of the temperature dependence of the fraction of broken hydrogen bonds, as inferred from Raman and infrared data, and the diffusion coefficient over the entire liquid range forms the basis of empirical support of the dominant role of hydrogen bonding in the fundamental diffusion mechanism.

Bibliography

Gillen, K. T., Douglass, D. C., & Hoch, M. J. R. (1972). Self-Diffusion in Liquid Water to â31Â°C. The Journal of Chemical Physics, 57(12), 5117â5119.

Authors 3

Kenneth T. Gillen (first)
D. C. Douglass (additional)
M. J. R. Hoch (additional)

References 17 Referenced 272

10.1021/j100682a019 / J. Phys. Chem. (1971)
{'key': '2024020909575776500_r2', 'first-page': '1410', 'volume': '21a', 'year': '1966', 'journal-title': 'Z. Naturforsch.'} / Z. Naturforsch. (1966)
{'key': '2024020909575776500_r3'}
10.1063/1.1776922 / J. Chem. Phys. (1963)
10.1139/p68-560 / Can. J. Phys. (1968)
10.1021/j150567a020 / J. Phys. Chem. (1958)
{'key': '2024020909575776500_r7', 'first-page': '193', 'volume': 'B68', 'year': '1955', 'journal-title': 'Proc. Phys. Soc. (London)'} / Proc. Phys. Soc. (London) (1955)
10.1063/1.1695690 / J. Chem. Phys. (1965)
10.1002/bbpc.19710750303 / Ber. Bunsenges. Physik. Chem. (1971)
10.1063/1.1676386 / J. Chem. Phys. (1971)
10.1016/0031-9163(65)90321-5 / Phys. Letters (1965)
10.1063/1.1676831 / J. Chem. Phys. (1972)
{'key': '2024020909575776500_r13'}
{'key': '2024020909575776500_r14'}
10.1021/j100715a002 / J. Phys. Chem. (1970)
10.1063/1.1725371 / J. Chem. Phys. (1964)
{'key': '2024020909575776500_r17', 'first-page': '523', 'volume': '18', 'year': '1959', 'journal-title': 'Acta Phys. Polon.'} / Acta Phys. Polon. (1959)

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 4:02 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:57 a.m.)
Indexed	4 weeks, 1 day ago (July 25, 2025, 5:55 a.m.)
Issued	52 years, 8 months ago (Dec. 15, 1972)
Published	52 years, 8 months ago (Dec. 15, 1972)
Published Print	52 years, 8 months ago (Dec. 15, 1972)

Funders 0

None

BibTeX

@article{Gillen_1972, title={Self-Diffusion in Liquid Water to −31°C}, volume={57}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1678198}, DOI={10.1063/1.1678198}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Gillen, Kenneth T. and Douglass, D. C. and Hoch, M. J. R.}, year={1972}, month=dec, pages={5117–5119} }

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