DOI: 10.1063/1.1677513. Hydrodynamic Theory of the Angular Velocity Autocorrelation Function

Hydrodynamic Theory of the Angular Velocity Autocorrelation Function

10.1063/1.1677513

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The angular velocity correlation function is computed using a frequency dependent version of Stokes' Law. The drag torque on a sphere rotating nonuniformly about one of its diagonals is used to compute the relaxation of the angular velocity. It is shown that the asymptotic time dependence of this function goes as t−5/2. Consequences of this persistence in the orientational relaxation of molecules is discussed.

Bibliography

Berne, B. J. (1972). Hydrodynamic Theory of the Angular Velocity Autocorrelation Function. The Journal of Chemical Physics, 56(5), 2164â2168.

Authors 1

Bruce J. Berne (first)

References 11 Referenced 48

{'key': '2024020909011664500_r1', 'first-page': '3569', 'volume': '54', 'year': '1970', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1970)
{'key': '2024020909011664500_r1a'}
{'key': '2024020909011664500_r2', 'first-page': '1462', 'volume': '3', 'year': '1970', 'journal-title': 'Phys. Rev. A'} / Phys. Rev. A (1970)
10.1103/PhysRevA.1.18 / Phys. Rev. A (1970)
{'key': '2024020909011664500_r4', 'first-page': '2906', 'volume': '2', 'year': '1970', 'journal-title': 'Phys. Rev. A'} / Phys. Rev. A (1970)
10.1103/PhysRevA.3.1394 / Phys. Rev. A (1971)
{'key': '2024020909011664500_r6'}
{'key': '2024020909011664500_r7', 'first-page': '235', 'volume': '29', 'year': '1966', 'journal-title': 'Rept. Progr. Phys.'} / Rept. Progr. Phys. (1966)
{'key': '2024020909011664500_r8', 'first-page': '1462', 'volume': '2', 'year': '1970', 'journal-title': 'Phys. Rev. A'} / Phys. Rev. A (1970)
10.1063/1.1672951 / J. Chem. Phys. (1970)
{'key': '2024020909011664500_r10'}

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 3:25 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 4:59 a.m.)
Indexed	5 days, 22 hours ago (Aug. 27, 2025, 11:32 a.m.)
Issued	53 years, 6 months ago (March 1, 1972)
Published	53 years, 6 months ago (March 1, 1972)
Published Print	53 years, 6 months ago (March 1, 1972)

Funders 0

None

BibTeX

@article{Berne_1972, title={Hydrodynamic Theory of the Angular Velocity Autocorrelation Function}, volume={56}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1677513}, DOI={10.1063/1.1677513}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Berne, Bruce J.}, year={1972}, month=mar, pages={2164–2168} }

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