DOI: 10.1063/1.1677130. Absorption Spectrum of Matrix-Isolated Ca Atoms

Absorption Spectrum of Matrix-Isolated Ca Atoms

10.1063/1.1677130

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The absorption spectra of Ca atoms isolated in Ar, Kr, and Xe matrices at 16–20°K were obtained from 3000 to 7000 Å. In Kr and Xe matrices an asymmetric triplet was observed which was assigned to the 1P1←1S0 transition. In concentrated Kr: Ca samples new low-energy peaks appear which are assigned to well-defined metal aggregates, probably Ca2. The results for Ar: Ca could not be correlated with the other matrices, and it is suggested that atomic isolation was not attained in this matrix.

Bibliography

Francis, J. E., & Webber, S. E. (1972). Absorption Spectrum of Matrix-Isolated Ca Atoms. The Journal of Chemical Physics, 56(12), 5879â5886.

Authors 2

J. E. Francis (first)
S. E. Webber (additional)

References 27 Referenced 43

10.1126/science.168.3933.783 / Science (1970)
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{'key': '2024020909182300800_r2'}
10.1080/00268975900100401 / Mol. Phys. (1959)
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10.1103/RevModPhys.36.748 / Rev. Mod. Phys. (1964)
10.1063/1.1712314 / J. Chem. Phys. (1967)
10.1016/0009-2614(69)80152-1 / Chem. Phys. Letters (1969)
10.1080/00268976000100361 / Mol. Phys. (1960)
10.1063/1.1672732 / J. Chem. Phys. (1970)
10.1063/1.1840705 / J. Chem. Phys. (1967)
10.1063/1.1734088 / J. Chem. Phys. (1963)
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{'key': '2024020909182300800_r22'}
{'key': '2024020909182300800_r23', 'first-page': '153', 'volume': '218', 'year': '1968', 'journal-title': 'Nature'} / Nature (1968)
10.1038/224785a0 / Nature (1969)
{'key': '2024020909182300800_r25'}

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 3:25 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:18 a.m.)
Indexed	1 year, 5 months ago (March 4, 2024, 4:21 p.m.)
Issued	53 years, 2 months ago (June 15, 1972)
Published	53 years, 2 months ago (June 15, 1972)
Published Print	53 years, 2 months ago (June 15, 1972)

Funders 0

None

BibTeX

@article{Francis_1972, title={Absorption Spectrum of Matrix-Isolated Ca Atoms}, volume={56}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1677130}, DOI={10.1063/1.1677130}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Francis, J. E. and Webber, S. E.}, year={1972}, month=jun, pages={5879–5886} }

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