DOI: 10.1063/1.1676962. Absolute Rate Constants for the Reaction of Atomic Oxygen with Ethylene over the Temperature Range 232

Absolute Rate Constants for the Reaction of Atomic Oxygen with Ethylene over the Temperature Range 232–500°K

10.1063/1.1676962

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Rate constants for the reaction of atomic oxygen with ethylene were measured over a temperature range of 232–500°K using the flash photolysis-resonance fluorescence technique. The rate constant at room temperature was also determined using a flash photolysis-kinetic absorption spectroscopy system and a discharge-flow system coupled to a mass spectrometer. Within the experimental errors of the three techniques, good agreement was found for the rate constant at 298°K. The bimolecular rate constant was also found invariant to changes in both total pressure and reactant concentration. Over the temperature range of the experiments, the rate data could be fitted by a simple Arrhenius expression of the form, k=5.42± 0.30× 10−12 exp[(−1130± 32 cal mole−1)/RT]cm3molecule−1· sec−1.

Bibliography

Davis, D. D., Huie, R. E., Herron, J. T., Kurylo, M. J., & Braun, W. (1972). Absolute Rate Constants for the Reaction of Atomic Oxygen with Ethylene over the Temperature Range 232â500Â°K. The Journal of Chemical Physics, 56(10), 4868â4876.

Authors 5

Douglas D. Davis (first)
Robert E. Huie (additional)
John T. Herron (additional)
Michael J. Kurylo (additional)
Walter Braun (additional)

References 27 Referenced 65

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{'key': '2024020909094079400_r5', 'first-page': '1095', 'volume': '149', 'year': '1963', 'journal-title': 'Dokl. Akad Nauk SSSR'} / Dokl. Akad Nauk SSSR (1963)
{'key': '2024020909094079400_r6'}
{'key': '2024020909094079400_r7', 'first-page': '157', 'volume': '1962', 'year': '1963', 'journal-title': 'Symp. Combust. 9th, Cornell Univ. Ithaca, N.Y.'} / Symp. Combust. 9th, Cornell Univ. Ithaca, N.Y. (1963)
{'key': '2024020909094079400_r8', 'first-page': '62', 'volume': '5', 'year': '1967', 'journal-title': 'J. Fac. Eng. Univ. Tokyo Ser. A'} / J. Fac. Eng. Univ. Tokyo Ser. A (1967)
{'key': '2024020909094079400_r9'}
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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 3:25 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:11 a.m.)
Indexed	11 months, 4 weeks ago (Aug. 31, 2024, 5:31 a.m.)
Issued	53 years, 3 months ago (May 15, 1972)
Published	53 years, 3 months ago (May 15, 1972)
Published Print	53 years, 3 months ago (May 15, 1972)

Funders 0

None

BibTeX

@article{Davis_1972, title={Absolute Rate Constants for the Reaction of Atomic Oxygen with Ethylene over the Temperature Range 232–500°K}, volume={56}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1676962}, DOI={10.1063/1.1676962}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Davis, Douglas D. and Huie, Robert E. and Herron, John T. and Kurylo, Michael J. and Braun, Walter}, year={1972}, month=may, pages={4868–4876} }

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