DOI: 10.1063/1.1676684. Determination of Rate Constants for Reactions of O Atoms with C2H2, C2D2, C2H4, and C3H6 Using a Pulsed Vacuum-uv Photolysis

Determination of Rate Constants for Reactions of O Atoms with C2H2, C2D2, C2H4, and C3H6 Using a Pulsed Vacuum-uv Photolysis—Chemiluminescent Method

10.1063/1.1676684

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Absolute rate constants for the primary reactions of O atoms with C2H2, C2D2, C2H4, and C3H6 were determined using vacuum-uv flash photolysis of NO to produce the O atoms. Decays of O atoms were monitored by NO2* chemiluminescent emission with initial O-atom concentrations in the range 1–5×1010 atoms cm−3. The rate constants obtained at 300°K are (in units of cubic centimeters molecule−1· second−1): k=1.31×10−13 (+5; −10%), for O+C2H2 and O+C2D2; k=6.3×10−13 (+5; −15%), for O+C2H4; k=3.6×10−12 (+5; −10%), for O+C3H6. The parameters involved in the assignment of the error limits are discussed in detail.

Bibliography

Stuhl, F., & Niki, H. (1971). Determination of Rate Constants for Reactions of O Atoms with C2H2, C2D2, C2H4, and C3H6 Using a Pulsed Vacuum-uv PhotolysisâChemiluminescent Method. The Journal of Chemical Physics, 55(8), 3954â3957.

Authors 2

F. Stuhl (first)
H. Niki (additional)

References 21 Referenced 39

{'key': '2024020908085414900_r1'}
10.1016/0009-2614(70)80286-X / Chem. Phys. Letters (1970)
{'key': '2024020908085414900_r3', 'first-page': '404', 'volume': 'A269', 'year': '1962', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1962)
10.1063/1.1725958 / J. Chem. Phys. (1964)
10.1039/tf9686401275 / Trans. Faraday Soc. (1968)
10.1063/1.1725154 / J. Chem. Phys. (1964)
{'key': '2024020908085414900_r7', 'first-page': '1895', 'volume': '22', 'year': '1955', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1955)
10.1063/1.1732610 / J. Chem. Phys. (1962)
{'key': '2024020908085414900_r9'}
{'key': '2024020908085414900_r10'}
10.1063/1.1696776 / J. Chem. Phys. (1965)
10.1021/j100889a507 / J. Phys. Chem. (1965)
10.1039/tf9676300630 / Trans. Faraday Soc. (1967)
10.1524/zpch.1967.55.1_2.072 / Z. Physik. Chem. (Frankfurt) (1967)
10.1021/j100725a001 / J. Phys. Chem. (1969)
10.1524/zpch.1969.63.1_4.193 / Z. Physik. Chem. (Frankfurt) (1969)
{'key': '2024020908085414900_r17', 'first-page': '2268', 'volume': '50', 'year': '1970', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1970)
10.1021/j100878a042 / J. Phys. Chem. (1966)
{'key': '2024020908085414900_r19', 'first-page': '277', 'volume': '1968', 'year': '1969', 'journal-title': 'Symp. Combust. 12th, Univ. Poitiers, France'} / Symp. Combust. 12th, Univ. Poitiers, France (1969)
{'key': '2024020908085414900_r20', 'first-page': '288', 'volume': '1968', 'year': '1969', 'journal-title': 'Symp. Combust. 12th, Univ. Poitiers, France'} / Symp. Combust. 12th, Univ. Poitiers, France (1969)
10.1063/1.1731334 / J. Chem. Phys. (1960)

Dates

Type	When
Created	21 years, 6 months ago (Feb. 4, 2004, 5:07 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 3:59 a.m.)
Indexed	11 months, 4 weeks ago (Aug. 31, 2024, 5:28 a.m.)
Issued	53 years, 10 months ago (Oct. 15, 1971)
Published	53 years, 10 months ago (Oct. 15, 1971)
Published Print	53 years, 10 months ago (Oct. 15, 1971)

Funders 0

None

BibTeX

@article{Stuhl_1971, title={Determination of Rate Constants for Reactions of O Atoms with C2H2, C2D2, C2H4, and C3H6 Using a Pulsed Vacuum-uv Photolysis—Chemiluminescent Method}, volume={55}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1676684}, DOI={10.1063/1.1676684}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Stuhl, F. and Niki, H.}, year={1971}, month=oct, pages={3954–3957} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        8,
        31
      ]
    ],
    "date-time": "2024-08-31T09:28:51Z",
    "timestamp": 1725096531887
  },
  "reference-count": 21,
  "publisher": "AIP Publishing",
  "issue": "8",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1971,
        10,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Absolute rate constants for the primary reactions of O atoms with C2H2, C2D2, C2H4, and C3H6 were determined using vacuum-uv flash photolysis of NO to produce the O atoms. Decays of O atoms were monitored by NO2* chemiluminescent emission with initial O-atom concentrations in the range 1\u20135\u00d71010 atoms cm\u22123. The rate constants obtained at 300\u00b0K are (in units of cubic centimeters molecule\u22121\u00b7 second\u22121): k=1.31\u00d710\u221213\u2009(+5;\u2009\u221210%), for O+C2H2 and O+C2D2; k=6.3\u00d710\u221213\u2009(+5;\u2009\u221215%), for O+C2H4; k=3.6\u00d710\u221212\u2009(+5;\u2009\u221210%), for O+C3H6. The parameters involved in the assignment of the error limits are discussed in detail.</jats:p>",
  "DOI": "10.1063/1.1676684",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        2,
        4
      ]
    ],
    "date-time": "2004-02-04T22:07:14Z",
    "timestamp": 1075932434000
  },
  "page": "3954-3957",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 39,
  "title": "Determination of Rate Constants for Reactions of O Atoms with C2H2, C2D2, C2H4, and C3H6 Using a Pulsed Vacuum-uv Photolysis\u2014Chemiluminescent Method",
  "prefix": "10.1063",
  "volume": "55",
  "author": [
    {
      "given": "F.",
      "family": "Stuhl",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Scientific Research Staff, Ford Motor Company, Dearborn, Michigan 48121"
        }
      ]
    },
    {
      "given": "H.",
      "family": "Niki",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Scientific Research Staff, Ford Motor Company, Dearborn, Michigan 48121"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020908085414900_r1"
    },
    {
      "key": "2024020908085414900_r2",
      "doi-asserted-by": "crossref",
      "first-page": "197",
      "DOI": "10.1016/0009-2614(70)80286-X",
      "volume": "7",
      "year": "1970",
      "journal-title": "Chem. Phys. Letters"
    },
    {
      "key": "2024020908085414900_r3",
      "first-page": "404",
      "volume": "A269",
      "year": "1962",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020908085414900_r4",
      "doi-asserted-by": "crossref",
      "first-page": "764",
      "DOI": "10.1063/1.1725958",
      "volume": "41",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908085414900_r5",
      "doi-asserted-by": "crossref",
      "first-page": "1275",
      "DOI": "10.1039/tf9686401275",
      "volume": "64",
      "year": "1968",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020908085414900_r6",
      "doi-asserted-by": "crossref",
      "first-page": "558",
      "DOI": "10.1063/1.1725154",
      "volume": "40",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908085414900_r7",
      "first-page": "1895",
      "volume": "22",
      "year": "1955",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908085414900_r8",
      "doi-asserted-by": "crossref",
      "first-page": "783",
      "DOI": "10.1063/1.1732610",
      "volume": "36",
      "year": "1962",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908085414900_r9"
    },
    {
      "key": "2024020908085414900_r10"
    },
    {
      "key": "2024020908085414900_r11",
      "doi-asserted-by": "crossref",
      "first-page": "525",
      "DOI": "10.1063/1.1696776",
      "volume": "43",
      "year": "1965",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908085414900_r12",
      "doi-asserted-by": "crossref",
      "first-page": "1749",
      "DOI": "10.1021/j100889a507",
      "volume": "69",
      "year": "1965",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020908085414900_r13",
      "doi-asserted-by": "crossref",
      "first-page": "630",
      "DOI": "10.1039/tf9676300630",
      "volume": "63",
      "year": "1967",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020908085414900_r14",
      "doi-asserted-by": "crossref",
      "first-page": "72",
      "DOI": "10.1524/zpch.1967.55.1_2.072",
      "volume": "55",
      "year": "1967",
      "journal-title": "Z. Physik. Chem. (Frankfurt)"
    },
    {
      "key": "2024020908085414900_r15",
      "doi-asserted-by": "crossref",
      "first-page": "1181",
      "DOI": "10.1021/j100725a001",
      "volume": "73",
      "year": "1969",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020908085414900_r16",
      "doi-asserted-by": "crossref",
      "first-page": "193",
      "DOI": "10.1524/zpch.1969.63.1_4.193",
      "volume": "63",
      "year": "1969",
      "journal-title": "Z. Physik. Chem. (Frankfurt)"
    },
    {
      "key": "2024020908085414900_r17",
      "first-page": "2268",
      "volume": "50",
      "year": "1970",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908085414900_r18",
      "doi-asserted-by": "crossref",
      "first-page": "1950",
      "DOI": "10.1021/j100878a042",
      "volume": "70",
      "year": "1966",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020908085414900_r19",
      "first-page": "277",
      "volume": "1968",
      "year": "1969",
      "journal-title": "Symp. Combust. 12th, Univ. Poitiers, France"
    },
    {
      "key": "2024020908085414900_r20",
      "first-page": "288",
      "volume": "1968",
      "year": "1969",
      "journal-title": "Symp. Combust. 12th, Univ. Poitiers, France"
    },
    {
      "key": "2024020908085414900_r21",
      "doi-asserted-by": "crossref",
      "first-page": "1063",
      "DOI": "10.1063/1.1731334",
      "volume": "33",
      "year": "1960",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/55/8/3954/18875417/3954_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/55/8/3954/18875417/3954_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T08:59:27Z",
    "timestamp": 1707469167000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/55/8/3954/87233/Determination-of-Rate-Constants-for-Reactions-of-O"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1971,
        10,
        15
      ]
    ]
  },
  "references-count": 21,
  "journal-issue": {
    "issue": "8",
    "published-print": {
      "date-parts": [
        [
          1971,
          10,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1676684",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1971,
        10,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1971,
        10,
        15
      ]
    ]
  }
}