DOI: 10.1063/1.1676438. Experimental Study of the Equation of State of Liquid Krypton

Experimental Study of the Equation of State of Liquid Krypton

10.1063/1.1676438

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The gas expansion method has been used to measure the density of liquid krypton at 11 temperatures from 120 to 220°K and at pressures up to 3680 atm. The results have been fitted to the Strobridge equation, which has been used to estimate, at regular intervals of pressure and temperature, the following properties: density, isothermal compressibility, thermal expansion coefficient, thermal pressure coefficient, configurational internal energy, and entropy relative to the saturated liquid. The equation of state results, together with estimated values of the third virial coefficient and published values of vapor pressure, second virial coefficient, and sound velocity in the liquid phase, have been used to estimate the following properties of the saturated liquid: enthalpy of vaporization, configurational internal energy, isothermal compressibility, thermal expansion coefficient, thermal pressure coefficient, adiabatic compressibility, and specific heats. The linear dependence of configurational internal energy on density, over a wide range of pressures and temperatures, suggests a relatively simple form for a hard sphere equation of state for monatomic liquids. The evaluation of constants for such an equation is briefly discussed.

Bibliography

Streett, W. B., & Staveley, L. A. K. (1971). Experimental Study of the Equation of State of Liquid Krypton. The Journal of Chemical Physics, 55(5), 2495â2506.

Authors 2

W. B. Streett (first)
L. A. K. Staveley (additional)

References 27 Referenced 105

10.1016/0031-8914(66)90032-2 / Physica (1966)
10.1016/0021-9614(70)90080-7 / J. Chem. Thermodynamics (1970)
10.1016/S0031-8914(37)80179-2 / Physica (1937)
10.1016/0021-9614(70)90081-9 / J. Chem. Thermodynamics (1970)
10.1016/0021-9614(69)90072-X / J. Chem. Thermodynamics (1969)
{'key': '2024020908084467700_r6', 'first-page': '363', 'volume': '13', 'year': '1968', 'journal-title': 'Advan. Cryog. Eng.'} / Advan. Cryog. Eng. (1968)
10.1063/1.1671380 / J. Chem. Phys. (1969)
{'key': '2024020908084467700_r8'}
10.1039/TF9676301320 / Trans. Faraday Soc. (1967)
{'key': '2024020908084467700_r10'}
10.1016/0031-8914(69)90148-7 / Physica (1969)
{'key': '2024020908084467700_r12', 'volume': '129', 'year': '1962', 'journal-title': 'Natl. Bur. Std. (U.S.), Tech. Note'} / Natl. Bur. Std. (U.S.), Tech. Note (1962)
10.1016/S0011-2275(67)80069-9 / Cryogenics (1967)
{'key': '2024020908084467700_r14', 'first-page': '642', 'volume': '33', 'year': '1938', 'journal-title': 'Ann. Phys.'} / Ann. Phys. (1938)
10.1088/0370-1328/78/6/347 / Proc. Phys. Soc. (London) (1961)
{'key': '2024020908084467700_r16', 'first-page': '63', 'volume': '28', 'year': '1952', 'journal-title': 'Physica'} / Physica (1952)
10.1016/0031-8914(67)90193-0 / Physica (1967)
{'key': '2024020908084467700_r18'}
{'key': '2024020908084467700_r19', 'first-page': '898', 'volume': '13', 'year': '1967', 'journal-title': 'Am. Inst. Chem. Eng. J.'} / Am. Inst. Chem. Eng. J. (1967)
{'key': '2024020908084467700_r20'}
10.1139/v67-335 / Can. J. Chem. (1967)
10.1002/aic.690010203 / Am. Inst. Chem. Eng. J. (1955)
10.1039/qr9702400416 / Quart. Rev. Chem. Soc. (1970)
10.1063/1.1703300 / J. Chem. Phys. (1967)
10.1039/tf9706602453 / Trans. Faraday Soc. (1970)
{'key': '2024020908084467700_r26', 'first-page': '2745', 'volume': '44', 'year': '1970', 'journal-title': 'Zhur. Phys. Khim. (USSR)'} / Zhur. Phys. Khim. (USSR) (1970)
10.1016/0011-2275(70)90103-7 / Cryogenics (1970)

Dates

Type	When
Created	21 years, 7 months ago (Feb. 4, 2004, 5:07 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 3:59 a.m.)
Indexed	1 year, 6 months ago (Feb. 12, 2024, 10:41 p.m.)
Issued	54 years ago (Sept. 1, 1971)
Published	54 years ago (Sept. 1, 1971)
Published Print	54 years ago (Sept. 1, 1971)

Funders 0

None

BibTeX

@article{Streett_1971, title={Experimental Study of the Equation of State of Liquid Krypton}, volume={55}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1676438}, DOI={10.1063/1.1676438}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Streett, W. B. and Staveley, L. A. K.}, year={1971}, month=sep, pages={2495–2506} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        13
      ]
    ],
    "date-time": "2024-02-13T03:41:00Z",
    "timestamp": 1707795660845
  },
  "reference-count": 27,
  "publisher": "AIP Publishing",
  "issue": "5",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1971,
        9,
        1
      ]
    ]
  },
  "abstract": "<jats:p>The gas expansion method has been used to measure the density of liquid krypton at 11 temperatures from 120 to 220\u00b0K and at pressures up to 3680 atm. The results have been fitted to the Strobridge equation, which has been used to estimate, at regular intervals of pressure and temperature, the following properties: density, isothermal compressibility, thermal expansion coefficient, thermal pressure coefficient, configurational internal energy, and entropy relative to the saturated liquid. The equation of state results, together with estimated values of the third virial coefficient and published values of vapor pressure, second virial coefficient, and sound velocity in the liquid phase, have been used to estimate the following properties of the saturated liquid: enthalpy of vaporization, configurational internal energy, isothermal compressibility, thermal expansion coefficient, thermal pressure coefficient, adiabatic compressibility, and specific heats. The linear dependence of configurational internal energy on density, over a wide range of pressures and temperatures, suggests a relatively simple form for a hard sphere equation of state for monatomic liquids. The evaluation of constants for such an equation is briefly discussed.</jats:p>",
  "DOI": "10.1063/1.1676438",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        2,
        4
      ]
    ],
    "date-time": "2004-02-04T22:07:14Z",
    "timestamp": 1075932434000
  },
  "page": "2495-2506",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 105,
  "title": "Experimental Study of the Equation of State of Liquid Krypton",
  "prefix": "10.1063",
  "volume": "55",
  "author": [
    {
      "given": "W. B.",
      "family": "Streett",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Science Research Laboratory, U. S. Military Academy, West Point, New York 10996"
        }
      ]
    },
    {
      "given": "L. A. K.",
      "family": "Staveley",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Inorganic Chemistry Laboratory, The University of Oxford, Oxford, England"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020908084467700_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1503",
      "DOI": "10.1016/0031-8914(66)90032-2",
      "volume": "32",
      "year": "1966",
      "journal-title": "Physica"
    },
    {
      "key": "2024020908084467700_r2",
      "doi-asserted-by": "crossref",
      "first-page": "171",
      "DOI": "10.1016/0021-9614(70)90080-7",
      "volume": "2",
      "year": "1970",
      "journal-title": "J. Chem. Thermodynamics"
    },
    {
      "key": "2024020908084467700_r3",
      "doi-asserted-by": "crossref",
      "first-page": "1200",
      "DOI": "10.1016/S0031-8914(37)80179-2",
      "volume": "4",
      "year": "1937",
      "journal-title": "Physica"
    },
    {
      "key": "2024020908084467700_r4",
      "doi-asserted-by": "crossref",
      "first-page": "179",
      "DOI": "10.1016/0021-9614(70)90081-9",
      "volume": "2",
      "year": "1970",
      "journal-title": "J. Chem. Thermodynamics"
    },
    {
      "key": "2024020908084467700_r5",
      "doi-asserted-by": "crossref",
      "first-page": "413",
      "DOI": "10.1016/0021-9614(69)90072-X",
      "volume": "1",
      "year": "1969",
      "journal-title": "J. Chem. Thermodynamics"
    },
    {
      "key": "2024020908084467700_r6",
      "first-page": "363",
      "volume": "13",
      "year": "1968",
      "journal-title": "Advan. Cryog. Eng."
    },
    {
      "key": "2024020908084467700_r7",
      "doi-asserted-by": "crossref",
      "first-page": "2302",
      "DOI": "10.1063/1.1671380",
      "volume": "50",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908084467700_r8"
    },
    {
      "key": "2024020908084467700_r9",
      "doi-asserted-by": "crossref",
      "first-page": "1320",
      "DOI": "10.1039/TF9676301320",
      "volume": "63",
      "year": "1967",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020908084467700_r10"
    },
    {
      "key": "2024020908084467700_r11",
      "doi-asserted-by": "crossref",
      "first-page": "555",
      "DOI": "10.1016/0031-8914(69)90148-7",
      "volume": "44",
      "year": "1969",
      "journal-title": "Physica"
    },
    {
      "key": "2024020908084467700_r12",
      "volume": "129",
      "year": "1962",
      "journal-title": "Natl. Bur. Std. (U.S.), Tech. Note"
    },
    {
      "key": "2024020908084467700_r13",
      "doi-asserted-by": "crossref",
      "first-page": "200",
      "DOI": "10.1016/S0011-2275(67)80069-9",
      "volume": "7",
      "year": "1967",
      "journal-title": "Cryogenics"
    },
    {
      "key": "2024020908084467700_r14",
      "first-page": "642",
      "volume": "33",
      "year": "1938",
      "journal-title": "Ann. Phys."
    },
    {
      "key": "2024020908084467700_r15",
      "doi-asserted-by": "crossref",
      "first-page": "1462",
      "DOI": "10.1088/0370-1328/78/6/347",
      "volume": "78",
      "year": "1961",
      "journal-title": "Proc. Phys. Soc. (London)"
    },
    {
      "key": "2024020908084467700_r16",
      "first-page": "63",
      "volume": "28",
      "year": "1952",
      "journal-title": "Physica"
    },
    {
      "key": "2024020908084467700_r17",
      "doi-asserted-by": "crossref",
      "first-page": "369",
      "DOI": "10.1016/0031-8914(67)90193-0",
      "volume": "37",
      "year": "1967",
      "journal-title": "Physica"
    },
    {
      "key": "2024020908084467700_r18"
    },
    {
      "key": "2024020908084467700_r19",
      "first-page": "898",
      "volume": "13",
      "year": "1967",
      "journal-title": "Am. Inst. Chem. Eng. J."
    },
    {
      "key": "2024020908084467700_r20"
    },
    {
      "key": "2024020908084467700_r21",
      "doi-asserted-by": "crossref",
      "first-page": "2079",
      "DOI": "10.1139/v67-335",
      "volume": "45",
      "year": "1967",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020908084467700_r22",
      "doi-asserted-by": "crossref",
      "first-page": "142",
      "DOI": "10.1002/aic.690010203",
      "volume": "1",
      "year": "1955",
      "journal-title": "Am. Inst. Chem. Eng. J."
    },
    {
      "key": "2024020908084467700_r23",
      "doi-asserted-by": "crossref",
      "first-page": "416",
      "DOI": "10.1039/qr9702400416",
      "volume": "24",
      "year": "1970",
      "journal-title": "Quart. Rev. Chem. Soc."
    },
    {
      "key": "2024020908084467700_r24",
      "doi-asserted-by": "crossref",
      "first-page": "2248",
      "DOI": "10.1063/1.1703300",
      "volume": "47",
      "year": "1967",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020908084467700_r25",
      "doi-asserted-by": "crossref",
      "first-page": "2453",
      "DOI": "10.1039/tf9706602453",
      "volume": "66",
      "year": "1970",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020908084467700_r26",
      "first-page": "2745",
      "volume": "44",
      "year": "1970",
      "journal-title": "Zhur. Phys. Khim. (USSR)"
    },
    {
      "key": "2024020908084467700_r27",
      "doi-asserted-by": "crossref",
      "first-page": "210",
      "DOI": "10.1016/0011-2275(70)90103-7",
      "volume": "10",
      "year": "1970",
      "journal-title": "Cryogenics"
    }
  ],
  "updated-by": [
    {
      "updated": {
        "date-parts": [
          [
            1975,
            1,
            15
          ]
        ],
        "date-time": "1975-01-15T00:00:00Z",
        "timestamp": 158976000000
      },
      "DOI": "10.1063/1.431012",
      "type": "correction",
      "source": "publisher",
      "label": "Correction"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/55/5/2495/18875411/2495_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/55/5/2495/18875411/2495_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T08:59:19Z",
    "timestamp": 1707469159000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/55/5/2495/87822/Experimental-Study-of-the-Equation-of-State-of"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1971,
        9,
        1
      ]
    ]
  },
  "references-count": 27,
  "journal-issue": {
    "issue": "5",
    "published-print": {
      "date-parts": [
        [
          1971,
          9,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1676438",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1971,
        9,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1971,
        9,
        1
      ]
    ]
  }
}