Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

The PVT properties of water and mercury have been measured up to 8000 bar between 30 and 150°C with an accuracy of 0.01% of the volume by electromagnetically detecting the change in length of a column of fluid. Numerical differentiation yields thermal expansion coefficients and compressibilities accurate to 0.5% for water and 1.0% for mercury. The first and second derivatives of entropy with respect to volume for mercury are consonant with a hard sphere model, though (∂2U / ∂2)T requires a softer repulsive potential. Water, because of its structure, only approaches such a simple model above our maximum temperature.

Bibliography

Grindley, T., & Lind, J. E. (1971). PVT Properties of Water and Mercury. The Journal of Chemical Physics, 54(9), 3983–3989.

Authors 2
  1. T. Grindley (first)
  2. John E. Lind (additional)
References 29 Referenced 190
  1. 10.1002/aic.690060129 / A.I.Ch.E. J. (1960)
  2. {'key': '2024020907431678100_r2'}
  3. {'key': '2024020907431678100_r3', 'first-page': '565', 'volume': 'A258', 'year': '1965', 'journal-title': 'Phil. Trans. Roy. Soc. London'} / Phil. Trans. Roy. Soc. London (1965)
  4. 10.1021/je60032a018 / J. Chem. Eng. Data (1967)
  5. 10.1088/0508-3443/15/9/314 / Brit. J. Appl. Phys. (1964)
  6. 10.1126/science.164.3881.860.b / Science (1969)
  7. {'key': '2024020907431678100_r7'}
  8. {'key': '2024020907431678100_r8'}
  9. 10.6028/jres.023.008 / J. Res. Natl. Bur. Std. (1939)
  10. 10.1021/ja01361a020 / J. Am. Chem. Soc. (1931)
  11. {'key': '2024020907431678100_r11', 'first-page': '307', 'volume': '48', 'year': '1913', 'journal-title': 'Proc. Am. Acad. Arts Sci.'} / Proc. Am. Acad. Arts Sci. (1913)
  12. {'key': '2024020907431678100_r12'}
  13. 10.1063/1.1749561 / J. Chem. Phys. (1935)
  14. {'key': '2024020907431678100_r14', 'first-page': '70', 'volume': 'A267', 'year': '1969', 'journal-title': 'Am. J. Sci.'} / Am. J. Sci. (1969)
  15. {'key': '2024020907431678100_r14a'}
  16. 10.6028/jres.059.028 / J. Res. Natl. Bur. Std. (1957)
  17. 10.1121/1.1911201 / J. Acoust. Soc. Am. (1968)
  18. 10.1121/1.1910739 / J. Acoust. Soc. Am. (1968)
  19. 10.1121/1.1910740 / J. Acoust. Soc. Am. (1968)
  20. 10.1080/14786440608564567 / Phil. Mag. (1928)
  21. 10.1088/0508-3443/5/7/303 / British J. Appl. Phys. (1954)
  22. {'key': '2024020907431678100_r20', 'first-page': '668', 'volume': '17', 'year': '1949', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1949)
  23. 10.1063/1.1841095 / J. Chem. Phys. (1967)
  24. 10.1103/PhysRev.173.271 / Phys. Rev. (1968)
  25. 10.1063/1.1840521 / J. Chem. Phys. (1967)
  26. {'key': '2024020907431678100_r24', 'first-page': '83', 'volume': '145', 'year': '1965', 'journal-title': 'Phys. Rev.'} / Phys. Rev. (1965)
  27. 10.6028/jres.046.038 / J. Res. Natl. Bur. Std. (1951)
  28. 10.1063/1.1674033 / J. Chem. Phys. (1970)
  29. {'key': '2024020907431678100_r27'}
Dates
Type When
Created 21 years, 6 months ago (Feb. 6, 2004, 3:15 p.m.)
Deposited 1 year, 6 months ago (Feb. 9, 2024, 3:26 a.m.)
Indexed 1 month ago (July 24, 2025, 7:04 a.m.)
Issued 54 years, 3 months ago (May 1, 1971)
Published 54 years, 3 months ago (May 1, 1971)
Published Print 54 years, 3 months ago (May 1, 1971)
Funders 0

None

@article{Grindley_1971, title={PVT Properties of Water and Mercury}, volume={54}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1675455}, DOI={10.1063/1.1675455}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Grindley, T. and Lind, John E.}, year={1971}, month=may, pages={3983–3989} }