DOI: 10.1063/1.1675360. Pulse Radiolysis Studies. XX. Kinetics of Some Addition Reactions of Gaseous Hydrogen Atoms by Fast Lyman-<i>α</i> Absorption Spectrophotometry

Pulse Radiolysis Studies. XX. Kinetics of Some Addition Reactions of Gaseous Hydrogen Atoms by Fast Lyman-α Absorption Spectrophotometry

10.1063/1.1675360

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The pulse radiolysis technique combined with fast Lyman-α absorption spectrophotometry, has been used to study the kinetics of several addition reactions of gaseous hydrogen atoms. The following absolute rate constants, at 298°K, have been obtained: H+O2+Ar=HO2+Ar, (5.9 ± 0.7) × 109M−2·sec−1, H+CO+H2=HCO+H2, (4.0 ± 0.6) × 107M−2·sec−1, H+CO+Ar=HCO+Ar, (2.6 ± 0.4) × 107M−2·sec−1, H+NO+H2=HNO+H2, (1.4 ± 0.2) × 1010M−2·sec−1. These results, and our earlier value for k1 with H2 as third body, give values of k1H2 / k1Ar = 2.9 and k2H2 / k2Ar = 1.5 for the relative third-body efficiencies of hydrogen and argon. The high-pressure limiting rate constant for H-atom addition to ethylene, obtained directly in the high-pressure region, was found to be H+C2H4=C2H5*, (5.5 ± 0.5) × 108M−1·sec−1, with both H2 and Ar as third body.

Bibliography

Hikida, T., Eyre, J. A., & Dorfman, L. M. (1971). Pulse Radiolysis Studies. XX. Kinetics of Some Addition Reactions of Gaseous Hydrogen Atoms by Fast Lyman-Î± Absorption Spectrophotometry. The Journal of Chemical Physics, 54(8), 3422â3428.

Authors 3

T. Hikida (first)
J. A. Eyre (additional)
Leon M. Dorfman (additional)

References 20 Referenced 60

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{'key': '2024020907384238900_r10', 'first-page': '520', 'volume': 'A297', 'year': '1967', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1967)
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Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 3:15 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 3:20 a.m.)
Indexed	1 year, 3 months ago (May 31, 2024, 5:10 p.m.)
Issued	54 years, 4 months ago (April 15, 1971)
Published	54 years, 4 months ago (April 15, 1971)
Published Print	54 years, 4 months ago (April 15, 1971)

Funders 0

None

BibTeX

@article{Hikida_1971, title={Pulse Radiolysis Studies. XX. Kinetics of Some Addition Reactions of Gaseous Hydrogen Atoms by Fast Lyman-α Absorption Spectrophotometry}, volume={54}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1675360}, DOI={10.1063/1.1675360}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hikida, T. and Eyre, J. A. and Dorfman, Leon M.}, year={1971}, month=apr, pages={3422–3428} }

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