DOI: 10.1063/1.1674311. Corrections to the Fuoss–Onsager Theory of Electrolytes

Corrections to the Fuoss–Onsager Theory of Electrolytes

10.1063/1.1674311

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Mathematical corrections are made to the theory of Fuoss and Onsager for the conductivity of ionic solutions to first order in the concentration. The theory is extended to cover the case of asymmetric binary electrolytes; it is found that in this case the results are strongly affected by deviations of the equilibrium ion pair distribution function from that predicted by the Debye–Hückel theory. The results of the conductivity theory are compared to corresponding results of the equilibrium theory.

Bibliography

Murphy, T. J., & Cohen, E. G. D. (1970). Corrections to the FuossâOnsager Theory of Electrolytes. The Journal of Chemical Physics, 53(6), 2173â2186.

Authors 2

T. J. Murphy (first)
E. G. D. Cohen (additional)

References 20 Referenced 19

10.1073/pnas.41.5.274 / Proc. Natl. Acad. Sci. (U.S.) (1955)
10.1021/j150551a038 / J. Phys. Chem. (1957)
10.1021/j100815a040 / J. Phys. Chem. (1962)
10.1021/j100797a020 / J. Phys. Chem. (1963)
10.1021/j100783a001 / J. Phys. Chem. (1964)
10.1021/j100892a017 / J. Phys. Chem. (1965)
10.1021/j100815a040 / J. Phys. Chem. (1962)
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{'key': '2024020906533590400_r6', 'first-page': '647', 'volume': '13', 'year': '1968', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1968)
{'key': '2024020906533590400_r7'}
{'key': '2024020906533590400_r8', 'first-page': '173', 'volume': '26', 'year': '1954', 'journal-title': 'Zh. Eksp. Teor. Fiz.'} / Zh. Eksp. Teor. Fiz. (1954)
{'key': '2024020906533590400_r9', 'first-page': '600', 'volume': '13', 'year': '1968', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1968)
10.1063/1.1692681 / Phys. Fluids (1969)
10.1021/j150574a045 / J. Phys. Chem. (1959)
10.1063/1.1747506 / J. Chem. Phys. (1950)
10.1149/1.3498072 / Trans. Electrochem. Soc. (1934)
10.1021/ja01164a099 / J. Am. Chem. Soc. (1950)
10.1021/ja01320a018 / J. Am. Chem. Soc. (1934)
10.1021/ja01318a021 / J. Am. Chem. Soc. (1934)
{'key': '2024020906533590400_r16'}

Dates

Type	When
Created	21 years, 6 months ago (Feb. 6, 2004, 3:15 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 2:27 a.m.)
Indexed	4 months, 3 weeks ago (April 5, 2025, 1:50 a.m.)
Issued	54 years, 11 months ago (Sept. 15, 1970)
Published	54 years, 11 months ago (Sept. 15, 1970)
Published Print	54 years, 11 months ago (Sept. 15, 1970)

Funders 0

None

BibTeX

@article{Murphy_1970, title={Corrections to the Fuoss–Onsager Theory of Electrolytes}, volume={53}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1674311}, DOI={10.1063/1.1674311}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Murphy, T. J. and Cohen, E. G. D.}, year={1970}, month=sep, pages={2173–2186} }

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